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Gentiobiose, α- (6-O-β-D-Glucopyranosyl-α-D-glucopyranose) is a rare disaccharide that was find in living systems which use it both structurally and as energy source. Gentiobiose was first isolated from gentian roots and was shown to be involved in signaling pathways of the plant.
beta-Gentiobiose is a naturally occurring disaccharide. It was proved to be potent inhibitors of the lytic activity of NK cells as well as of cytotoxic T lymphocytes activated in mixed lymphocyte cultures.