METHYL PHENYLGLYOXALATE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C9H8O3
Molecular Weight	164.158
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

COC(=O)C(=O)C1=CC=CC=C1

InChI

InChIKey=YLHXLHGIAMFFBU-UHFFFAOYSA-N

InChI=1S/C9H8O3/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6H,1H3

HIDE SMILES / InChI

Molecular Formula	C9H8O3
Molecular Weight	164.158
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
The [2+2]-photocycloaddition of aromatic aldehydes and ketones to 3,4-dihydro-2-pyridones: regioselectivity, diastereoselectivity, and reductive ring opening of the product oxetanes.	2001 Oct 15	11695686
Constraining asymmetric organometallic catalysts within mesoporous supports boosts their enantioselectivity.	2003 Dec 10	14653721
Stereoselective generation of vicinal stereogenic quaternary centers by photocycloaddition of 5-methoxy oxazoles to alpha-keto esters: synthesis of erythro beta-hydroxy dimethyl aspartates.	2004 Apr 21	15064785
Ru-Catalyzed asymmetric hydrogenation of alpha-ketoesters with CeCl3.7H2O as additive.	2005 Nov 24	16288522
Synthesis, properties, and oxidizing ability of areno-annulated 1,3-dimethyl-10-phenylcyclohepta[4,5]pyrrolo[2,3-d]pyrimidine- 2,4(1,3H)-dionylium ions.	2006 Jan 6	16388633
Amine degradation by 4,5-epoxy-2-decenal in model systems.	2006 Mar 22	16536625
Unusual temperature dependence of enantioselectivity in asymmetric reductions by chiral NADH models.	2006 May 11	16671783
N-methyl-(R)-3-(tert-butyl)-sulfinyl-1,4-dihydropyridine: a novel NADH model compound.	2007 Mar 12	17851400
Exploiting nanospace for asymmetric catalysis: confinement of immobilized, single-site chiral catalysts enhances enantioselectivity.	2008 Jun	18505277
[Overview of 40 years' chemical study].	2009 Jan	19122440
Mechanistic insights on the magnesium(II) ion-activated reduction of methyl benzoylformate with chelated NADH peptide beta-lactam models.	2009 Sep 4	19642693
Integration of newly isolated biocatalyst and resin-based in situ product removal technique for the asymmetric synthesis of (R)-methyl mandelate.	2010 Sep	20033429

Patents

Substance Class	Chemical Created by `admin` on `Sat Dec 16 04:55:42 GMT 2023` Edited by `admin` on `Sat Dec 16 04:55:42 GMT 2023`
Record UNII	23F2045STG
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

METHYL PHENYLGLYOXALATE

Systematic Name

English

METHYL .ALPHA.-OXOBENZENEACETATE

Systematic Name

English

GLYCOPYRRONIUM BROMIDE IMPURITY H [EP IMPURITY]

Common Name

English

BENZENEACETIC ACID, .ALPHA.-OXO-, METHYL ESTER

Common Name

English

METHYL 2-OXO-2-PHENYLACETATE

Systematic Name

English

METHYL BENZOYLFORMATE

Official Name

English

METHYL BENZOYLFORMATE [INCI]

Common Name

English

METHOXYCARBONYL PHENYL KETONE

Systematic Name

English

METHYL PHENYL-.ALPHA.-OXOACETATE

Systematic Name

English

METHYL PHENYLGLYOXYLATE

Systematic Name

English

2-OXO-2-PHENYLACETIC ACID METHYL ESTER

Systematic Name

English

NSC-409881

Code

English

BENZOYLFORMIC ACID METHYL ESTER

Systematic Name

English

NSC-171206

Code

English

METHYL PHENYLOXOACETATE

Systematic Name

English

METHYL OXOPHENYLACETATE

Systematic Name

English

METHYL 2-PHENYL-2-OXOACETATE

Systematic Name

English

PHENYLGLYOXYLIC ACID METHYL ESTER

Systematic Name

English

Code System Code Type Description

EPA CompTox

DTXSID9065867