Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C4H10N2Si |
| Molecular Weight | 114.2211 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 1 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
C[Si](C)(C)C=[N+]=[N-]
InChI
InChIKey=ONDSBJMLAHVLMI-UHFFFAOYSA-N
InChI=1S/C4H10N2Si/c1-7(2,3)4-6-5/h4H,1-3H3
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Trimethylsilyldiazomethane as a versatile stitching agent for the introduction of aziridines into functionalized organic molecules. | 2010-11-05 |
|
| Structure-function relationships of the antigenicity of mycolic acids in tuberculosis patients. | 2010-11 |
|
| Trimethylsilyldiazomethane: a safe non-explosive, cost effective and less-toxic reagent for phenol derivatization in GC applications. | 2010-11 |
|
| Leaf senescence signaling: the Ca2+-conducting Arabidopsis cyclic nucleotide gated channel2 acts through nitric oxide to repress senescence programming. | 2010-10 |
|
| Virus-induced gene silencing of plastidial soluble inorganic pyrophosphatase impairs essential leaf anabolic pathways and reduces drought stress tolerance in Nicotiana benthamiana. | 2010-09 |
|
| Difluorobenzocyclooctyne: synthesis, reactivity, and stabilization by beta-cyclodextrin. | 2010-08-25 |
|
| Catalytic and regioselective ring expansion of arylcyclobutanones with trimethylsilyldiazomethane. Ligand-dependent entry to beta-ketosilane or enolsilane adducts. | 2010-08-20 |
|
| Trimethylsilyldiazomethane (TMSD) as a new derivatization reagent for trace analysis of selected non-steroidal anti-inflammatory drugs (NSAIDs) by gas chromatography methods. | 2010-08 |
|
| Methylation of acidic moieties in poly(methyl methacrylate-co-methacrylic acid) copolymers for end-group characterization by tandem mass spectrometry. | 2010-07-30 |
|
| Laser microdissection of conifer stem tissues: isolation and analysis of high quality RNA, terpene synthase enzyme activity and terpenoid metabolites from resin ducts and cambial zone tissue of white spruce (Picea glauca). | 2010-06-12 |
|
| Analytical strategy for the molecular weight determination of random copolymers of poly(methyl methacrylate) and poly(methacrylic acid). | 2010-06 |
|
| Determination of butoxyacetic acid (biomarker of ethylene glycol monobutyl ether exposure) in human urine candidate reference material. | 2010-05 |
|
| Synthesis of marine polycyclic polyethers via endo-selective epoxide-opening cascades. | 2010-03-19 |
|
| General and species-specific transcriptional responses to downy mildew infection in a susceptible (Vitis vinifera) and a resistant (V. riparia) grapevine species. | 2010-02-18 |
|
| Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a methyl analogue with trimethylsilyl diazomethane. | 2010-01-07 |
|
| High-throughput HPLC-MS/MS method to determine ibandronate in human plasma for pharmacokinetic applications. | 2009-10-01 |
|
| The AUXIN BINDING PROTEIN 1 is required for differential auxin responses mediating root growth. | 2009-09-24 |
|
| Dehydrogenation of LGeH by a Lewis N-heterocyclic carbene borane pair under the formation of L'Ge and its reactions with B(C(6)F(5))(3) and trimethylsilyl diazomethane: an unprecedented rearrangement of a diazocompound to an isonitrile. | 2009-08-17 |
|
| Methyl 3-dehydr-oxy-3-oxoursolate. | 2009-08-08 |
|
| Diverse alkanones by catalytic carbon insertion into the formyl C-H bond. Concise access to the natural precursor of achyrofuran. | 2009-08-06 |
|
| Methylation of alpha-amino acids and derivatives using trimethylsilyldiazomethane. | 2009-03 |
|
| Mycangimycin, a polyene peroxide from a mutualist Streptomyces sp. | 2009-02-05 |
|
| Synthesis of substituted naphthalenes via a catalytic ring-expansion rearrangement. | 2008-11-06 |
|
| Transition-metal-catalyzed chemoselective methylenation of dicarbonyl substrates. | 2008-09-05 |
|
| Improvement of an efficient separation method for chemicals in diesel exhaust particles: analysis for nitrophenols. | 2008-06 |
|
| Microwave-assisted derivatization of acidic herbicides for gas chromatography-mass spectrometry. | 2008-05-30 |
|
| Palladium-catalyzed carbene insertion and trapping with carbon nucleophiles. | 2008-05-15 |
|
| Distinct roles of jasmonates and aldehydes in plant-defense responses. | 2008-04-02 |
|
| Optimized derivatization of acidic herbicides with trimethylsilyldiazomethane for GC analysis. | 2008-03 |
|
| Organolanthanide-based synthesis of 1,2,3-triazoles from nitriles and diazo compounds. | 2008-01-09 |
|
| cis-Jasmone induces accumulation of defence compounds in wheat, Triticum aestivum. | 2008-01 |
|
| Selective C-C coupling of Ir-ethene and Ir-carbenoid radicals. | 2008 |
|
| Matrix assisted laser desorption ionization-time of flight mass spectrometry analysis of hyaluronan oligosaccharides. | 2007-06-19 |
|
| Palladium-catalyzed carbene insertion into vinyl halides and trapping with amines. | 2007-05-10 |
|
| High-throughput method for the quantitation of total folate in whole blood using LC-MS/MS. | 2007-05-02 |
|
| Establishing the feasibility of coupled solid-phase extraction-solid-phase derivatization for acidic herbicides. | 2007-03-02 |
|
| 1,3-dipolar cycloadditions of trimethylsilyldiazomethane revisited: steric demand of the dipolarophile and the influence on product distribution. | 2007-01-19 |
|
| Copper-carbene complexes as catalysts in the synthesis of functionalized styrenes and aliphatic alkenes. | 2007-01-05 |
|
| Mechanism of methyl esterification of carboxylic acids by trimethylsilyldiazomethane. | 2007 |
|
| Gas-liquid chromatographic method for analysing complex mixtures of fatty acids including conjugated linoleic acids (cis9trans11 and trans10cis12 isomers) and long-chain (n-3 or n-6) polyunsaturated fatty acids. Application to the intramuscular fat of beef meat. | 2006-03-31 |
|
| Synthetic studies and mechanistic insight in nickel-catalyzed [4+2+1] cycloadditions. | 2006-03-01 |
|
| Interference from a glucuronide metabolite in the determination of ramipril and ramiprilat in human plasma and urine by gas chromatography-mass spectrometry. | 2006-02-24 |
|
| Dicarboxylic degradation products of nonylphenol polyethoxylates. Determination and structural elucidation in water samples by solid-phase extraction and gas chromatography-mass spectrometry after methylation. | 2006-01-20 |
|
| Preparation of the methyl ester of hyaluronan and its enzymatic degradation. | 2005-10-17 |
|
| Quantitation of total folate in whole blood using LC-MS/MS. | 2005-09-21 |
|
| Synthesis of multisubstituted 1,3-butadienes using the ruthenium-catalysed double addition of trimethylsilyldiazomethane to alkynylboronates. | 2005-04-07 |
|
| Dicarboxylic degradation products of nonylphenol polyethoxylates: synthesis and identification by gas chromatography-mass spectrometry using electron and chemical ionization modes. | 2004-12-17 |
|
| An efficient [4 + 2 + 1] entry to seven-membered rings. | 2004-09-15 |
|
| Highly efficient synthesis of terminal alkenes from ketones. | 2004-09-02 |
|
| Recommended methods of fatty acid methylester preparation for conjugated dienes and trienes in food and biological samples. | 2004-04 |
Patents
| Name | Type | Language | ||
|---|---|---|---|---|
|
Preferred Name | English | ||
|
Systematic Name | English | ||
|
Systematic Name | English | ||
|
Systematic Name | English |
| Code System | Code | Type | Description | ||
|---|---|---|---|---|---|
|
DTXSID8074653
Created by
admin on Mon Mar 31 22:22:50 GMT 2025 , Edited by admin on Mon Mar 31 22:22:50 GMT 2025
|
PRIMARY | |||
|
QI98HQO8C4
Created by
admin on Mon Mar 31 22:22:50 GMT 2025 , Edited by admin on Mon Mar 31 22:22:50 GMT 2025
|
PRIMARY | |||
|
18107-18-1
Created by
admin on Mon Mar 31 22:22:50 GMT 2025 , Edited by admin on Mon Mar 31 22:22:50 GMT 2025
|
PRIMARY | |||
|
167693
Created by
admin on Mon Mar 31 22:22:50 GMT 2025 , Edited by admin on Mon Mar 31 22:22:50 GMT 2025
|
PRIMARY | |||
|
8011
Created by
admin on Mon Mar 31 22:22:50 GMT 2025 , Edited by admin on Mon Mar 31 22:22:50 GMT 2025
|
PRIMARY | |||
|
Trimethylsilyldiazomethane
Created by
admin on Mon Mar 31 22:22:50 GMT 2025 , Edited by admin on Mon Mar 31 22:22:50 GMT 2025
|
PRIMARY |
SUBSTANCE RECORD
