Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C4H10N2Si |
| Molecular Weight | 114.2211 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 1 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
C[Si](C)(C)C=[N+]=[N-]
InChI
InChIKey=ONDSBJMLAHVLMI-UHFFFAOYSA-N
InChI=1S/C4H10N2Si/c1-7(2,3)4-6-5/h4H,1-3H3
| Molecular Formula | C4H10N2Si |
| Molecular Weight | 114.2211 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 1 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| [Relationship between changes in skin lipids by ultraviolet exposure and the cell toxicity]. | 2001 Jul |
|
| Highly diastereoselective aziridination of imines with trimethylsilyldiazomethane. Subsequent silyl substitution with electrophiles, ring opening, and metalation of C-silylaziridines--a cornucopia of highly selective transformations. | 2002 Apr 5 |
|
| Formation of (R)-2,3-dihydrogeranylgeranoic acid from geranylgeraniol in rat thymocytes. | 2002 Aug |
|
| Stereospecific entry to [4.5]spiroketal glycosides using alkylidenecarbene C-H insertion. | 2002 Feb 21 |
|
| Investigation of capillary electrophoresis-laser induced fluorescence as a tool in the characterization of sewage effluent for fluorescent acids: determination of salicylic acid. | 2002 Jul |
|
| Simultaneous determination of phthalate di- and monoesters in poly(vinylchloride) products and human saliva by gas chromatography-mass spectrometry. | 2002 Nov 15 |
|
| A new method for the preparation of silyl enol ethers from carbonyl compounds and (trimethylsilyl)diazomethane in a regiospecific and highly stereoselective manner. | 2002 Sep 4 |
|
| Multiresidue determination of acidic pesticides in water by HPLC-DAD with confirmation by GC-MS using conversion to the methyl ester with trimethylsilyldiazomethane. | 2003 Aug |
|
| Synthesis of alpha-fluorinated phosphonates from alpha-fluorovinylphosphonates: a new route to analogues of lysophosphatidic acid. | 2003 Jun 26 |
|
| Recommended methods of fatty acid methylester preparation for conjugated dienes and trienes in food and biological samples. | 2004 Apr |
|
| Dicarboxylic degradation products of nonylphenol polyethoxylates: synthesis and identification by gas chromatography-mass spectrometry using electron and chemical ionization modes. | 2004 Dec 17 |
|
| An efficient [4 + 2 + 1] entry to seven-membered rings. | 2004 Sep 15 |
|
| Synthesis of multisubstituted 1,3-butadienes using the ruthenium-catalysed double addition of trimethylsilyldiazomethane to alkynylboronates. | 2005 Apr 7 |
|
| Preparation of the methyl ester of hyaluronan and its enzymatic degradation. | 2005 Oct 17 |
|
| Quantitation of total folate in whole blood using LC-MS/MS. | 2005 Sep 21 |
|
| Interference from a glucuronide metabolite in the determination of ramipril and ramiprilat in human plasma and urine by gas chromatography-mass spectrometry. | 2006 Feb 24 |
|
| Dicarboxylic degradation products of nonylphenol polyethoxylates. Determination and structural elucidation in water samples by solid-phase extraction and gas chromatography-mass spectrometry after methylation. | 2006 Jan 20 |
|
| Synthetic studies and mechanistic insight in nickel-catalyzed [4+2+1] cycloadditions. | 2006 Mar 1 |
|
| Gas-liquid chromatographic method for analysing complex mixtures of fatty acids including conjugated linoleic acids (cis9trans11 and trans10cis12 isomers) and long-chain (n-3 or n-6) polyunsaturated fatty acids. Application to the intramuscular fat of beef meat. | 2006 Mar 31 |
|
| Mechanism of methyl esterification of carboxylic acids by trimethylsilyldiazomethane. | 2007 |
|
| 1,3-dipolar cycloadditions of trimethylsilyldiazomethane revisited: steric demand of the dipolarophile and the influence on product distribution. | 2007 Jan 19 |
|
| Copper-carbene complexes as catalysts in the synthesis of functionalized styrenes and aliphatic alkenes. | 2007 Jan 5 |
|
| Matrix assisted laser desorption ionization-time of flight mass spectrometry analysis of hyaluronan oligosaccharides. | 2007 Jun 19 |
|
| Establishing the feasibility of coupled solid-phase extraction-solid-phase derivatization for acidic herbicides. | 2007 Mar 2 |
|
| Palladium-catalyzed carbene insertion into vinyl halides and trapping with amines. | 2007 May 10 |
|
| High-throughput method for the quantitation of total folate in whole blood using LC-MS/MS. | 2007 May 2 |
|
| Distinct roles of jasmonates and aldehydes in plant-defense responses. | 2008 Apr 2 |
|
| cis-Jasmone induces accumulation of defence compounds in wheat, Triticum aestivum. | 2008 Jan |
|
| Organolanthanide-based synthesis of 1,2,3-triazoles from nitriles and diazo compounds. | 2008 Jan 9 |
|
| Optimized derivatization of acidic herbicides with trimethylsilyldiazomethane for GC analysis. | 2008 Mar |
|
| Palladium-catalyzed carbene insertion and trapping with carbon nucleophiles. | 2008 May 15 |
|
| Microwave-assisted derivatization of acidic herbicides for gas chromatography-mass spectrometry. | 2008 May 30 |
|
| Synthesis of substituted naphthalenes via a catalytic ring-expansion rearrangement. | 2008 Nov 6 |
|
| Dehydrogenation of LGeH by a Lewis N-heterocyclic carbene borane pair under the formation of L'Ge and its reactions with B(C(6)F(5))(3) and trimethylsilyl diazomethane: an unprecedented rearrangement of a diazocompound to an isonitrile. | 2009 Aug 17 |
|
| Diverse alkanones by catalytic carbon insertion into the formyl C-H bond. Concise access to the natural precursor of achyrofuran. | 2009 Aug 6 |
|
| Methyl 3-dehydr-oxy-3-oxoursolate. | 2009 Aug 8 |
|
| Mycangimycin, a polyene peroxide from a mutualist Streptomyces sp. | 2009 Feb 5 |
|
| Methylation of alpha-amino acids and derivatives using trimethylsilyldiazomethane. | 2009 Mar |
|
| High-throughput HPLC-MS/MS method to determine ibandronate in human plasma for pharmacokinetic applications. | 2009 Oct 1 |
|
| The AUXIN BINDING PROTEIN 1 is required for differential auxin responses mediating root growth. | 2009 Sep 24 |
|
| Catalytic and regioselective ring expansion of arylcyclobutanones with trimethylsilyldiazomethane. Ligand-dependent entry to beta-ketosilane or enolsilane adducts. | 2010 Aug 20 |
|
| Difluorobenzocyclooctyne: synthesis, reactivity, and stabilization by beta-cyclodextrin. | 2010 Aug 25 |
|
| Synthesis of marine polycyclic polyethers via endo-selective epoxide-opening cascades. | 2010 Mar 19 |
|
| Determination of butoxyacetic acid (biomarker of ethylene glycol monobutyl ether exposure) in human urine candidate reference material. | 2010 May |
|
| Structure-function relationships of the antigenicity of mycolic acids in tuberculosis patients. | 2010 Nov |
|
| Trimethylsilyldiazomethane as a versatile stitching agent for the introduction of aziridines into functionalized organic molecules. | 2010 Nov 5 |
|
| Leaf senescence signaling: the Ca2+-conducting Arabidopsis cyclic nucleotide gated channel2 acts through nitric oxide to repress senescence programming. | 2010 Oct |
|
| Virus-induced gene silencing of plastidial soluble inorganic pyrophosphatase impairs essential leaf anabolic pathways and reduces drought stress tolerance in Nicotiana benthamiana. | 2010 Sep |
Patents
| Substance Class |
Chemical
Created
by
admin
on
Edited
Sat Dec 16 08:55:13 GMT 2023
by
admin
on
Sat Dec 16 08:55:13 GMT 2023
|
| Record UNII |
QI98HQO8C4
|
| Record Status |
Validated (UNII)
|
| Record Version |
|
-
Download
| Name | Type | Language | ||
|---|---|---|---|---|
|
Systematic Name | English | ||
|
Common Name | English | ||
|
Systematic Name | English | ||
|
Systematic Name | English |
| Code System | Code | Type | Description | ||
|---|---|---|---|---|---|
|
DTXSID8074653
Created by
admin on Sat Dec 16 08:55:13 GMT 2023 , Edited by admin on Sat Dec 16 08:55:13 GMT 2023
|
PRIMARY | |||
|
QI98HQO8C4
Created by
admin on Sat Dec 16 08:55:13 GMT 2023 , Edited by admin on Sat Dec 16 08:55:13 GMT 2023
|
PRIMARY | |||
|
18107-18-1
Created by
admin on Sat Dec 16 08:55:13 GMT 2023 , Edited by admin on Sat Dec 16 08:55:13 GMT 2023
|
PRIMARY | |||
|
167693
Created by
admin on Sat Dec 16 08:55:13 GMT 2023 , Edited by admin on Sat Dec 16 08:55:13 GMT 2023
|
PRIMARY | |||
|
8011
Created by
admin on Sat Dec 16 08:55:13 GMT 2023 , Edited by admin on Sat Dec 16 08:55:13 GMT 2023
|
PRIMARY | |||
|
Trimethylsilyldiazomethane
Created by
admin on Sat Dec 16 08:55:13 GMT 2023 , Edited by admin on Sat Dec 16 08:55:13 GMT 2023
|
PRIMARY |