TERT-BUTYLPEROXIDE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C8H18O2
Molecular Weight	146.2273
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

CC(C)(C)OOC(C)(C)C

InChI

InChIKey=LSXWFXONGKSEMY-UHFFFAOYSA-N

InChI=1S/C8H18O2/c1-7(2,3)9-10-8(4,5)6/h1-6H3

HIDE SMILES / InChI

Approval Year

PubMed

Title	Date	PubMed
Induction of short-term markers of tumor promotion by organic peroxides.	1991 Apr	2013121
Temperature fields during the development of autoignition in a rapid compression machine.	2001	11877997
Novel tubing microreactor for monitoring chemical reactions.	2002 Jul 1	12141671
Synthetic studies with 13-deoxybaccatin III.	2002 Oct 4	12354012
Deoxygenation of carbohydrates by thiol-catalysed radical-chain redox rearrangement of the derived benzylidene acetals.	2003 Apr 21	12929663
Using screening test data to recognize reactive chemical hazards.	2003 Nov 14	14602414
Unusual atmospheric pressure chemical ionization conditions for detection of organic peroxides.	2003 Sep	14505320
Inhibition of membrane-associated calcium-independent phospholipase A2 as a potential culprit of anthracycline cardiotoxicity.	2003 Sep 15	14522926
Source of tryptone in growth medium affects oxidative stress resistance in Escherichia coli.	2004	15186449
Benzo[d]-1,2-oxaphospholes as precursors of stabilized C-centered radicals.	2004 Feb 19	14961623
Exposure of mouse skin to organic peroxides: subchronic effects related to carcinogenic potential.	2004 Mar	14633658
Hot filament chemical vapor deposition of poly(glycidyl methacrylate) thin films using tert-butyl peroxide as an initiator.	2004 Mar 16	15835714
The influence of the solvent on the epoxidation of cis,trans,trans-1,5,9-cyclododecatriene to trans-1,2-epoxy-cis,trans-5,9-cyclododecadiene by catalytic system tert-butyl hydroperoxide/Mo(CO)6.	2005 Apr 11	15811663
Application of vinyl tris(trimethylsilyl)germanes in Pd-catalyzed couplings.	2005 Apr 15	15822995
Synthesis of heteroarenes using cascade radical cyclisation via iminyl radicals.	2005 Apr 21	15827642
The GC/AED studies on the reactions of sulfur mustard with oxidants.	2005 Aug 31	15876488
Flavonoids protect retinal ganglion cells from oxidative stress-induced death.	2005 Dec	16303981
The molecular basis of oxidative stress-induced cell death in an immortalized retinal ganglion cell line.	2005 Feb	15671309
Line strengths and transition dipole moment of the nu2 fundamental band of the methyl radical.	2005 Jan 1	15638658
Electron-transfer mechanism in the N-demethylation of N,N-dimethylanilines by the phthalimide-N-oxyl radical.	2005 Jun 24	15960517
Direct ESR detection of pentadienyl radicals and peroxyl radicals in lipid peroxidation: mechanistic insight into regioselective oxygenation in lipoxygenases.	2005 May 11	15869281
[Contractile proteins in chemical signal transduction in plant microspores].	2005 May-Jun	16004258
Initiated chemical vapor deposition of linear and cross-linked poly(2-hydroxyethyl methacrylate) for use as thin-film hydrogels.	2005 Sep 13	16142981
Free-radical scavenging by Ouratea parviflora in experimentally-induced liver injuries.	2006	16805967
Cyclodextrin-derived mimic of glutathione peroxidase exhibiting enzymatic specificity and high catalytic efficiency.	2006 Apr 24	16491491
Metabolism of nomifensine to a dihydroisoquinolinium ion metabolite by human myeloperoxidase, hemoglobin, monoamine oxidase A, and cytochrome P450 enzymes.	2006 Aug	16679384
Initiated chemical vapor deposition of trivinyltrimethylcyclotrisiloxane for biomaterial coatings.	2006 Aug 1	16863255
Singlet oxygen production in the reaction of superoxide with organic peroxides.	2006 Jan 20	16408996
Air-Initiated Radical Polymerization of Lithium Salts of omega-(Undecamethylcarba-closo-dodecaboran-1'-yl)alk-1-enes, CH2=CH(CH2)(n-2)C(BMe)11- Li+.	2006 May 3	16637634
Li+-catalyzed radical polymerization of simple terminal alkenes.	2006 May 3	16637608
Lipid peroxidation as a source of oxidative damage in Helicobacter pylori: protective roles of peroxiredoxins.	2006 Nov	17069977
On the mechanism of reaction of radicals with tirapazamine.	2007 Apr 18	17381087
Dissociative electron attachment to di-tert-butylperoxide, artemisinin, and beta-artemether.	2007 Aug 16	17636969
Radical carbonylation with [11C]carbon monoxide promoted by oxygen-centered radicals: experimental and DFT studies of the mechanism.	2007 Jul 25	17608420
Olefin epoxidation by alkyl hydroperoxide with a novel cross-bridged cyclam manganese complex: demonstration of oxygenation by two distinct reactive intermediates.	2007 Mar 19	17295471
Negative ion-atmospheric pressure photoionization: electron capture, dissociative electron capture, proton transfer, and anion attachment.	2007 Oct	17719234
Measurement of the transition dipole moment of the first hot band of the nu2 mode of the methyl radical by diode laser spectroscopy.	2008 Jul 17	18572894
Risk evaluation on the basis of pressure rate measured by automatic pressure tracking adiabatic calorimeter.	2008 Nov 15	18313846
Spin trapping investigation of peroxide- and isoniazid-induced radicals in Mycobacterium tuberculosis catalase-peroxidase.	2008 Oct 28	18831539
Absolute rate constants for some intermolecular reactions of alpha-aminoalkylperoxyl radicals. Comparison with alkylperoxyls.	2008 Sep 5	18665644
Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and NO(x).	2009	19402412
Thermal radiation of di-tert-butyl peroxide pool fires-Experimental investigation and CFD simulation.	2009 Aug 15	19185989
Probucol increases glutathione peroxidase-1 activity and displays long-lasting protection against methylmercury toxicity in cerebellar granule cells.	2009 Dec	19770487
Iron-catalyzed tandem oxidative coupling and annulation: an efficient approach to construct polysubstituted benzofurans.	2009 Dec 2	19899754
The HIF-1 hypoxia-inducible factor modulates lifespan in C. elegans.	2009 Jul 27	19633713
In vivo administration of BL-3050: highly stable engineered PON1-HDL complexes.	2009 Nov 17	19922610
Solvent-assisted dewetting during chemical vapor deposition.	2009 Oct 6	19670895
Heats of formation of t-butyl peroxy radical and t-butyl diazyl ion: RRKM vs SSACM rate theories in systems with kinetic and competitive shifts.	2010 Jan 14	20055517
EPR/spin-trapping study of free radical intermediates in the photolysis of trifluoromethyl ketones with initiators.	2010 Mar	20058258
Experimental and theoretical (DFT) characterization of the excited states and N-centered radical species derived from 2-aminobenzimidazole, the core substructure of a family of bioactive compounds.	2010 May 20	20423160

Patents

Name

Type

Language

TERT-BUTYLPEROXIDE

Systematic Name

English

BIS(1,1-DIMETHYLETHYL) PEROXIDE

Systematic Name

English

DI-TERT-BUTYL PEROXIDE

Systematic Name

English

NSC-673

Code

English

DTBP [MI]

Common Name

English

TERT-BUTYL PEROXIDE

Systematic Name

English

DI-T-BUTYL PEROXIDE

Systematic Name

English

T-BUTYL PEROXIDE

Systematic Name

English

BIS(1,1-DIMETHYLETHYL)PEROXIDE [HSDB]

Common Name

English

DTBP	Locators: MI Sources:

Common Name

English

Classification Tree Code System Code

CFR

21 CFR 176.170