TERT-BUTYLPEROXIDE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C8H18O2
Molecular Weight	146.2273
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

CC(C)(C)OOC(C)(C)C

InChI

InChIKey=LSXWFXONGKSEMY-UHFFFAOYSA-N

InChI=1S/C8H18O2/c1-7(2,3)9-10-8(4,5)6/h1-6H3

HIDE SMILES / InChI

Molecular Formula	C8H18O2
Molecular Weight	146.2273
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
Experimental and theoretical (DFT) characterization of the excited states and N-centered radical species derived from 2-aminobenzimidazole, the core substructure of a family of bioactive compounds.	2010-05-20	20423160
EPR/spin-trapping study of free radical intermediates in the photolysis of trifluoromethyl ketones with initiators.	2010-03	20058258
Heats of formation of t-butyl peroxy radical and t-butyl diazyl ion: RRKM vs SSACM rate theories in systems with kinetic and competitive shifts.	2010-01-14	20055517
Iron-catalyzed tandem oxidative coupling and annulation: an efficient approach to construct polysubstituted benzofurans.	2009-12-02	19899754
Probucol increases glutathione peroxidase-1 activity and displays long-lasting protection against methylmercury toxicity in cerebellar granule cells.	2009-12	19770487
In vivo administration of BL-3050: highly stable engineered PON1-HDL complexes.	2009-11-17	19922610
Solvent-assisted dewetting during chemical vapor deposition.	2009-10-06	19670895
Thermal radiation of di-tert-butyl peroxide pool fires-Experimental investigation and CFD simulation.	2009-08-15	19185989
The HIF-1 hypoxia-inducible factor modulates lifespan in C. elegans.	2009-07-27	19633713
Environmental chamber study of the photochemical reaction of ethyl methyl sulfide and NO(x).	2009	19402412
Risk evaluation on the basis of pressure rate measured by automatic pressure tracking adiabatic calorimeter.	2008-11-15	18313846
Spin trapping investigation of peroxide- and isoniazid-induced radicals in Mycobacterium tuberculosis catalase-peroxidase.	2008-10-28	18831539
Absolute rate constants for some intermolecular reactions of alpha-aminoalkylperoxyl radicals. Comparison with alkylperoxyls.	2008-09-05	18665644
Measurement of the transition dipole moment of the first hot band of the nu2 mode of the methyl radical by diode laser spectroscopy.	2008-07-17	18572894
Negative ion-atmospheric pressure photoionization: electron capture, dissociative electron capture, proton transfer, and anion attachment.	2007-10	17719234
Dissociative electron attachment to di-tert-butylperoxide, artemisinin, and beta-artemether.	2007-08-16	17636969
Radical carbonylation with [11C]carbon monoxide promoted by oxygen-centered radicals: experimental and DFT studies of the mechanism.	2007-07-25	17608420
On the mechanism of reaction of radicals with tirapazamine.	2007-04-18	17381087
Olefin epoxidation by alkyl hydroperoxide with a novel cross-bridged cyclam manganese complex: demonstration of oxygenation by two distinct reactive intermediates.	2007-03-19	17295471
Lipid peroxidation as a source of oxidative damage in Helicobacter pylori: protective roles of peroxiredoxins.	2006-11	17069977
Initiated chemical vapor deposition of trivinyltrimethylcyclotrisiloxane for biomaterial coatings.	2006-08-01	16863255
Metabolism of nomifensine to a dihydroisoquinolinium ion metabolite by human myeloperoxidase, hemoglobin, monoamine oxidase A, and cytochrome P450 enzymes.	2006-08	16679384
Air-Initiated Radical Polymerization of Lithium Salts of omega-(Undecamethylcarba-closo-dodecaboran-1'-yl)alk-1-enes, CH2=CH(CH2)(n-2)C(BMe)11- Li+.	2006-05-03	16637634
Li+-catalyzed radical polymerization of simple terminal alkenes.	2006-05-03	16637608
Cyclodextrin-derived mimic of glutathione peroxidase exhibiting enzymatic specificity and high catalytic efficiency.	2006-04-24	16491491
Singlet oxygen production in the reaction of superoxide with organic peroxides.	2006-01-20	16408996
Free-radical scavenging by Ouratea parviflora in experimentally-induced liver injuries.	2006	16805967
Flavonoids protect retinal ganglion cells from oxidative stress-induced death.	2005-12	16303981
Initiated chemical vapor deposition of linear and cross-linked poly(2-hydroxyethyl methacrylate) for use as thin-film hydrogels.	2005-09-13	16142981
The GC/AED studies on the reactions of sulfur mustard with oxidants.	2005-08-31	15876488
[Contractile proteins in chemical signal transduction in plant microspores].	2005-07-12	16004258
Electron-transfer mechanism in the N-demethylation of N,N-dimethylanilines by the phthalimide-N-oxyl radical.	2005-06-24	15960517
Direct ESR detection of pentadienyl radicals and peroxyl radicals in lipid peroxidation: mechanistic insight into regioselective oxygenation in lipoxygenases.	2005-05-11	15869281
Synthesis of heteroarenes using cascade radical cyclisation via iminyl radicals.	2005-04-21	15827642
Application of vinyl tris(trimethylsilyl)germanes in Pd-catalyzed couplings.	2005-04-15	15822995
The influence of the solvent on the epoxidation of cis,trans,trans-1,5,9-cyclododecatriene to trans-1,2-epoxy-cis,trans-5,9-cyclododecadiene by catalytic system tert-butyl hydroperoxide/Mo(CO)6.	2005-04-11	15811663
The molecular basis of oxidative stress-induced cell death in an immortalized retinal ganglion cell line.	2005-02	15671309
Line strengths and transition dipole moment of the nu2 fundamental band of the methyl radical.	2005-01-01	15638658
Hot filament chemical vapor deposition of poly(glycidyl methacrylate) thin films using tert-butyl peroxide as an initiator.	2004-03-16	15835714
Exposure of mouse skin to organic peroxides: subchronic effects related to carcinogenic potential.	2004-03	14633658
Benzo[d]-1,2-oxaphospholes as precursors of stabilized C-centered radicals.	2004-02-19	14961623
Source of tryptone in growth medium affects oxidative stress resistance in Escherichia coli.	2004	15186449
Using screening test data to recognize reactive chemical hazards.	2003-11-14	14602414
Inhibition of membrane-associated calcium-independent phospholipase A2 as a potential culprit of anthracycline cardiotoxicity.	2003-09-15	14522926
Unusual atmospheric pressure chemical ionization conditions for detection of organic peroxides.	2003-09	14505320
Deoxygenation of carbohydrates by thiol-catalysed radical-chain redox rearrangement of the derived benzylidene acetals.	2003-04-21	12929663
Synthetic studies with 13-deoxybaccatin III.	2002-10-04	12354012
Novel tubing microreactor for monitoring chemical reactions.	2002-07-01	12141671
Temperature fields during the development of autoignition in a rapid compression machine.	2001	11877997
Induction of short-term markers of tumor promotion by organic peroxides.	1991-04	2013121

Patents

Substance Class	Chemical Created by `admin` on `Mon Mar 31 18:46:14 GMT 2025` Edited by `admin` on `Mon Mar 31 18:46:14 GMT 2025`
Record UNII	M7ZJ88F4R1
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

TERT-BUTYLPEROXIDE

Systematic Name

English

DTBP	Locators: MI Sources:

Preferred Name

English

BIS(1,1-DIMETHYLETHYL) PEROXIDE

Systematic Name

English

DI-TERT-BUTYL PEROXIDE

Systematic Name

English

NSC-673

Code

English

DTBP [MI]

Common Name

English

TERT-BUTYL PEROXIDE

Systematic Name

English

DI-T-BUTYL PEROXIDE

Systematic Name

English

T-BUTYL PEROXIDE

Systematic Name

English

BIS(1,1-DIMETHYLETHYL)PEROXIDE [HSDB]

Common Name

English

Classification Tree Code System Code

CFR

21 CFR 176.170