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Details

Stereochemistry ACHIRAL
Molecular Formula C3H9O3P
Molecular Weight 124.0755
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of TRIMETHYL PHOSPHITE

SMILES

COP(OC)OC

InChI

InChIKey=CYTQBVOFDCPGCX-UHFFFAOYSA-N
InChI=1S/C3H9O3P/c1-4-7(5-2)6-3/h1-3H3

HIDE SMILES / InChI

Approval Year

PubMed

PubMed

TitleDatePubMed
Correlation between the rate order and the number of molecules in the reaction of trimethyl phosphite with water in acetonitrile solvent.
2010-11-04
Rapid modification of the insect elicitor N-linolenoyl-glutamate via a lipoxygenase-mediated mechanism on Nicotiana attenuata leaves.
2010-08-09
CO insertion in lithiated diene-tricarbonyliron complexes.
2010-07-21
An overview of recent development in composite catalysts from porous materials for various reactions and processes.
2010-05-18
cis-Dichloridobis(triisopropoxy-phosphine)-platinum(II).
2009-10-17
cis-Dichlorido-bis(trimethoxy-phos-phine)palladium(II) at 125 K.
2009-10-17
Alkylamine sensing using langmuir-blodgett films of n-alkyl-N-phenylamide-substituted zinc porphyrins.
2008-09-11
Methyl [hydr-oxy(phen-yl)phosphono-meth-yl]phospho-nate methanol solvate.
2008-09-06
Dinuclear Cp* cobalt complexes of the 1,2,4,5-benzenetetrathiolate bischelating ligand.
2008-02-18
Electron-rich heteroaroylphosphonates and their reaction with trimethyl phosphite.
2008-02-07
17O NMR investigation of phosphite hydrolysis mechanisms.
2007-12
Mechanism of the sulfurisation of phosphines and phosphites using 3-amino-1,2,4-dithiazole-5-thione (xanthane hydride).
2007-02-07
New modification of the Perkow reaction: halocarboxylate anions as leaving groups in 3-acyloxyquinoline-2,4(1H,3H)-dione compounds.
2005-12-09
Tuning haptotropic rearrangements of arene-chromium complexes: steric and electronic effects of phosphorus coligands.
2005-09-05
Gas-phase reactivity of the O=P(OCH3)2 + phosphonium ion towards alpha,beta-unsaturated esters in a quadrupole ion trap.
2005-04
Synthesis of mono- and disaccharide analogs of moenomycin and lipid II for inhibition of transglycosylase activity of penicillin-binding protein 1b.
2004-12-15
[Studies on the reactions of unsaturated chloride polyether polyol with trimethyl phosphite by FTIR].
2004-11
Stereoselective palladium-catalyzed O-glycosylation using glycals.
2004-02-11
[Hygienic standards of the occupational air quality established by the Experts on Chemical Agents, 2002].
2004
Cobalt-catalyzed cycloisomerization of 1,6-enynes and allyl propargyl ethers.
2003-07-10
Synthesis and acid-base properties of (1H-benzimidazol-2-yl-methyl)phosphonate (Bimp2-). Evidence for intramolecular hydrogen-bond formation in aqueous solution between (N-1)H and the phosphonate group.
2003-05-21
Trimethyl phosphite as a trap for alkoxy radicals formed from the ring opening of oxiranylcarbinyl radicals. Conversion to alkenes. Mechanistic applications to the study of C-C versus C-O ring cleavage.
2003-03-19
Reaction between naphthols and dimethyl acetylenedicarboxylate in the presence of phosphites. Synthesis of stable oxa-2 lambda 5-phosphaphenanthrenes, and benzochromene derivatives.
2003-02-07
Gas-phase reactivity of the O=P(OCH3)2+ phosphonium ion with aliphatic esters in a quadrupole ion trap. Spontaneous elimination of ketenes.
2002-09
Electronic and medium effects on the rate of arene C [bond] H activation by cationic Ir(III) complexes.
2002-02-20
Gas-phase ion/molecule reactions between dimethoxyphosphonium ions and aromatic hydrocarbons.
2002
Synthesis of glycosyl phosphoramidates: novel isosteric analogues of glycosyl phosphates.
2001-09-17
Copper-mediated cross-coupling of functionalized arylmagnesium reagents with functionalized alkyl and benzylic halides.
2001-09-06
Patents
Name Type Language
NSC-6513
Preferred Name English
TRIMETHYL PHOSPHITE
HSDB  
Systematic Name English
TRIMETHYL PHOSPHITE [HSDB]
Common Name English
TRIMETHOXYPHOSPHINE
Systematic Name English
PHOSPHOROUS ACID, TRIMETHYL ESTER
Systematic Name English
TRIMETHYLPHOSPHITE
Systematic Name English
Code System Code Type Description
FDA UNII
26Q0321ZDG
Created by admin on Mon Mar 31 18:48:03 GMT 2025 , Edited by admin on Mon Mar 31 18:48:03 GMT 2025
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SMS_ID
300000053678
Created by admin on Mon Mar 31 18:48:03 GMT 2025 , Edited by admin on Mon Mar 31 18:48:03 GMT 2025
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CAS
121-45-9
Created by admin on Mon Mar 31 18:48:03 GMT 2025 , Edited by admin on Mon Mar 31 18:48:03 GMT 2025
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PUBCHEM
8472
Created by admin on Mon Mar 31 18:48:03 GMT 2025 , Edited by admin on Mon Mar 31 18:48:03 GMT 2025
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HSDB
1007
Created by admin on Mon Mar 31 18:48:03 GMT 2025 , Edited by admin on Mon Mar 31 18:48:03 GMT 2025
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ECHA (EC/EINECS)
204-471-5
Created by admin on Mon Mar 31 18:48:03 GMT 2025 , Edited by admin on Mon Mar 31 18:48:03 GMT 2025
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WIKIPEDIA
TRIMETHYL PHOSPHITE
Created by admin on Mon Mar 31 18:48:03 GMT 2025 , Edited by admin on Mon Mar 31 18:48:03 GMT 2025
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EPA CompTox
DTXSID4026979
Created by admin on Mon Mar 31 18:48:03 GMT 2025 , Edited by admin on Mon Mar 31 18:48:03 GMT 2025
PRIMARY
NSC
6513
Created by admin on Mon Mar 31 18:48:03 GMT 2025 , Edited by admin on Mon Mar 31 18:48:03 GMT 2025
PRIMARY