TRIMETHYL PHOSPHITE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C3H9O3P
Molecular Weight	124.0755
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

COP(OC)OC

InChI

InChIKey=CYTQBVOFDCPGCX-UHFFFAOYSA-N

InChI=1S/C3H9O3P/c1-4-7(5-2)6-3/h1-3H3

HIDE SMILES / InChI

Molecular Formula	C3H9O3P
Molecular Weight	124.0755
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
Synthesis of glycosyl phosphoramidates: novel isosteric analogues of glycosyl phosphates.	2001 Sep 17	11549440
Copper-mediated cross-coupling of functionalized arylmagnesium reagents with functionalized alkyl and benzylic halides.	2001 Sep 6	11529778
Gas-phase ion/molecule reactions between dimethoxyphosphonium ions and aromatic hydrocarbons.	2002	11921248
Electronic and medium effects on the rate of arene C [bond] H activation by cationic Ir(III) complexes.	2002 Feb 20	11841308
Gas-phase reactivity of the O=P(OCH3)2+ phosphonium ion with aliphatic esters in a quadrupole ion trap. Spontaneous elimination of ketenes.	2002 Sep	12271433
Reaction between naphthols and dimethyl acetylenedicarboxylate in the presence of phosphites. Synthesis of stable oxa-2 lambda 5-phosphaphenanthrenes, and benzochromene derivatives.	2003 Feb 7	12926260
Cobalt-catalyzed cycloisomerization of 1,6-enynes and allyl propargyl ethers.	2003 Jul 10	12841742
Trimethyl phosphite as a trap for alkoxy radicals formed from the ring opening of oxiranylcarbinyl radicals. Conversion to alkenes. Mechanistic applications to the study of C-C versus C-O ring cleavage.	2003 Mar 19	12630880
Synthesis and acid-base properties of (1H-benzimidazol-2-yl-methyl)phosphonate (Bimp2-). Evidence for intramolecular hydrogen-bond formation in aqueous solution between (N-1)H and the phosphonate group.	2003 May 21	12926375
[Hygienic standards of the occupational air quality established by the Experts on Chemical Agents, 2002].	2004	15156761
Synthesis of mono- and disaccharide analogs of moenomycin and lipid II for inhibition of transglycosylase activity of penicillin-binding protein 1b.	2004 Dec 15	15556765
Stereoselective palladium-catalyzed O-glycosylation using glycals.	2004 Feb 11	14759180
[Studies on the reactions of unsaturated chloride polyether polyol with trimethyl phosphite by FTIR].	2004 Nov	15762469
Gas-phase reactivity of the O=P(OCH3)2 + phosphonium ion towards alpha,beta-unsaturated esters in a quadrupole ion trap.	2005 Apr	15712355
cis-Dichloridobis(triisopropoxy-phosphine)-platinum(II).	2009 Oct 17	21578136
cis-Dichlorido-bis(trimethoxy-phos-phine)palladium(II) at 125 K.	2009 Oct 17	21578135
CO insertion in lithiated diene-tricarbonyliron complexes.	2010 Jul 21	20526499

Patents

Substance Class	Chemical Created by `admin` on `Fri Dec 15 17:32:46 GMT 2023` Edited by `admin` on `Fri Dec 15 17:32:46 GMT 2023`
Record UNII	26Q0321ZDG
Record Status	`Validated (UNII)`
Record Version

Download

Name

Type

Language

TRIMETHYL PHOSPHITE

Systematic Name

English

NSC-6513

Code

English

TRIMETHYL PHOSPHITE [HSDB]

Common Name

English

TRIMETHOXYPHOSPHINE

Systematic Name

English

PHOSPHOROUS ACID, TRIMETHYL ESTER

Systematic Name

English

TRIMETHYLPHOSPHITE

Systematic Name

English

Code System Code Type Description

FDA UNII

26Q0321ZDG