Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C4H9F3O3SSi |
| Molecular Weight | 222.258 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
C[Si](C)(C)OS(=O)(=O)C(F)(F)F
InChI
InChIKey=FTVLMFQEYACZNP-UHFFFAOYSA-N
InChI=1S/C4H9F3O3SSi/c1-12(2,3)10-11(8,9)4(5,6)7/h1-3H3
| Molecular Formula | C4H9F3O3SSi |
| Molecular Weight | 222.258 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| [NMR study on the determination of structure in the protected glucosamineoside]. | 2004 Nov |
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| A synthetic cycle for H2/CO activation and allene synthesis using recyclable zirconium complexes. | 2005 Dec 14 |
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| Semisynthetic 15-O-acyl- and 1,15-di-O-acyleurycomanones from Eurycoma longifolia as potential antimalarials. | 2005 Oct |
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| A new synthesis of alpha-arbutin via Lewis acid catalyzed selective glycosylation of tetra-O-benzyl-alpha-D-glucopyranosyl trichloroacetimidate with hydroquinone. | 2006 Aug 14 |
|
| Highly stereoselective asymmetric Pummerer reactions that incorporate intermolecular and intramolecular nonbonded S...O interactions. | 2006 Aug 2 |
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| Mononucleating bis(beta-diketonate) ligands and their titanium(IV) complexes. | 2006 Dec 11 |
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| Nucleophilic substitution at the anomeric position of 1,2-O-isopropylidenefuranose derivatives. A novel stereoselective synthesis of cyclic phosphates analogous to cAMP. | 2006 Dec 29 |
|
| Dizinc alkoxides and amides supported by binucleating bis(amidoamine) ligands. | 2006 Feb 20 |
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| Contrasting reactivity of thioglucoside and selenoglucoside donors towards promoters: implications for glycosylation stereocontrol. | 2006 Jul 24 |
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| Synthesis of a galacto-configured C-ketoside-based gamma-sugar-amino acid and its use in peptide coupling reactions. | 2006 Jul 24 |
|
| Unusual transannular cyclization products of sarcophytoxide, a 14-membered marine cembranoid: anomalous stereochemistry of epoxide-ketone rearrangement. | 2006 Jul 6 |
|
| Syntheses of alpha-D-galactosamine neoglycolipids. | 2006 May 22 |
|
| Aryl C-glycosylation of phenols with glycosyl trifluoroacetimidates. | 2006 Nov 27 |
|
| Halogen-metal exchange in 1,2-dibromobenzene and the possible intermediacy of 1,2-dilithiobenzene. | 2007 Dec 7 |
|
| Synthesis of ribonucleosides by condensation using trimethylsilyl triflate. | 2007 Jan |
|
| High-throughput five minute microwave accelerated glycosylation approach to the synthesis of nucleoside libraries. | 2007 Jan 5 |
|
| First o-glycosylation from unprotected 1-thioimidoyl hexofuranosides assisted by divalent cations. | 2007 Jul 20 |
|
| Cyclotetraphosphinophosphonium ions: synthesis, structures, and pseudorotation. | 2007 Jun 13 |
|
| Silyl-modified Bellus-Claisen rearrangement. | 2007 Mar 14 |
|
| Novel unsaturated sucrose ethers and their application as monomers. | 2007 Mar 28 |
|
| Synthesis, structure, and electrochemistry of di- and zerovalent nickel, palladium, and platinum monomers and dimers derived from an enantiopure (S,S)-tetra(tertiary phosphine). | 2007 Sep 17 |
|
| Synthesis and quantitative evaluation of Glycero-D-manno-heptose binding to concanavalin A by fluorous-tag assistance. | 2008 |
|
| Regioselective one-pot protection of glucose. | 2008 |
|
| One-pot enol silane formation-Mukaiyama aldol-type addition to dimethyl acetals mediated by TMSOTf. | 2008 Apr 18 |
|
| A diastereoselective ring contraction of 1,3-dioxepins to 2,3,4-trisubstituted and tetrasubstituted tetrahydrofurans. | 2008 Jan 18 |
|
| Trimethylsilyl trifluoromethanesulfonate (TMSOTf) assisted facile deprotection of N,O-acetonides. | 2008 Jan 18 |
|
| Characterization of Aquifex aeolicus 4-diphosphocytidyl-2C-methyl-d-erythritol kinase - ligand recognition in a template for antimicrobial drug discovery. | 2008 Jun |
|
| A direct and stereospecific approach to the synthesis of alpha-glycosyl thiols. | 2008 Jun 21 |
|
| A tungstenVI nitride having a W2(mu-N)2 core. | 2008 Mar 3 |
|
| Tertiary arsine-stabilised arsenium salts: syntheses and comparisons with phosphine analogues. | 2008 May 14 |
|
| Reagent-based, modular, tandem Michael approach for obtaining different indoline alkaloid-inspired polycyclic architectures. | 2008 May-Jun |
|
| 2,3-Diphosphino-1,4-diphosphonium ions. | 2008 Nov 19 |
|
| Concise synthesis of a pentasaccharide related to the anti-leishmanial triterpenoid saponin isolated from Maesa balansae. | 2008 Sep 5 |
|
| On reactions of steroidal 23-oxo and 23,24-epoxysapogenins with Lewis acids. | 2009 Aug |
|
| Remarkable effect of 2,2'-bipyridyl: mild and highly chemoselective deprotection of methoxymethyl (MOM) ethers in combination with TMSOTf (TESOTf)-2,2'-bipyridyl. | 2009 Aug 7 |
|
| Intramolecular formal [4 + 2] cycloaddition of nitriles with amides triggered by TMSOTf/Et3N: highly efficient construction of pyrrolo[1,2-a]pyrimidin-4(6H)-ones. | 2009 Aug 7 |
|
| Divergent synthesis of three classes of aryl N-glycosides by solvent control. | 2009 Jan 16 |
|
| Synthesis of novel purine nucleosides towards a selective inhibition of human butyrylcholinesterase. | 2009 Jul 15 |
|
| Structure-based design of benzimidazole sugar conjugates: synthesis, SAR and in vivo anti-inflammatory and analgesic activities. | 2009 Nov |
|
| Estrone derived steroidal diepoxide: biologically active compound and precursor of a stable steroidal A,B-spiro system. | 2009 Nov |
|
| An N,N'-diamidocarbene: studies in C-H insertion, reversible carbonylation, and transition-metal coordination chemistry. | 2009 Nov 11 |
|
| Acetic acid aldol reactions in the presence of trimethylsilyl trifluoromethanesulfonate. | 2010 Aug 6 |
|
| FerriCast: a macrocyclic photocage for Fe3+. | 2010 Feb 1 |
|
| Synthesis of 1H-indole-2,3-dione-3-thiosemicarbazone ribonucleosides as antibacterial agents. | 2010 Jan |
|
| Mild deprotection of methylene acetals in combination with trimethylsilyl triflate-2,2'-bipyridyl. | 2010 Mar |
|
| Synthesis of marine polycyclic polyethers via endo-selective epoxide-opening cascades. | 2010 Mar 19 |
|
| N-myristoyltransferase from Leishmania donovani: structural and functional characterisation of a potential drug target for visceral leishmaniasis. | 2010 Mar 5 |
|
| Improved synthesis of 2'-deoxy-2'-[18F]-fluoro-1-beta-D-arabinofuranosyl-5-iodouracil ([18F]-FIAU). | 2010 May |
|
| Activation of glycosyl trichloroacetimidates with perchloric acid on silica (HClO(4)-SiO(2)) provides enhanced alpha-selectivity. | 2010 Sep 23 |
|
| Synthesis and reactivity of sulfur(II) dications stabilized using monodentate ligands. | 2010 Sep 6 |
| Substance Class |
Chemical
Created
by
admin
on
Edited
Sat Dec 16 04:18:10 GMT 2023
by
admin
on
Sat Dec 16 04:18:10 GMT 2023
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| Record UNII |
Z84V0CBH9J
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| Record Status |
Validated (UNII)
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| Record Version |
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27607-77-8
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248-565-4
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Trimethylsilyl triflate
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65367
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m11161
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PRIMARY | Merck Index | ||
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DTXSID2067325
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Z84V0CBH9J
Created by
admin on Sat Dec 16 04:18:10 GMT 2023 , Edited by admin on Sat Dec 16 04:18:10 GMT 2023
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PRIMARY |