Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C6H15B |
| Molecular Weight | 97.994 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
CCB(CC)CC
InChI
InChIKey=LALRXNPLTWZJIJ-UHFFFAOYSA-N
InChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3
| Molecular Formula | C6H15B |
| Molecular Weight | 97.994 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| A formal synthesis of the C1-C9 fragment of amphidinolide C employing the Tamaru reaction. | 2010-07-02 |
|
| Synthesis of marine polycyclic polyethers via endo-selective epoxide-opening cascades. | 2010-03-19 |
|
| Aerobic hydroxylation of N-borylenamine: triethylborane-mediated hydroxyalkylation of alpha,beta-unsaturated oxime ether. | 2009-10-15 |
|
| Base-promoted ammonia borane hydrogen-release. | 2009-10-07 |
|
| Rh-catalyzed reductive coupling reaction of aldehydes with conjugated dienes promoted by triethylborane. | 2009-09-03 |
|
| Dimethylzinc-initiated radical reactions. | 2009-02-17 |
|
| Macrocyclization by nickel-catalyzed, ester-promoted, epoxide-alkyne reductive coupling: total synthesis of (-)-gloeosporone. | 2009 |
|
| Reductive coupling of carbon monoxide in a rhenium carbonyl complex with pendant Lewis acids. | 2008-09-10 |
|
| Tin-free radical addition of acyloxymethyl to imines. | 2008-09-04 |
|
| Complexes of borane and N-heterocyclic carbenes: a new class of radical hydrogen atom donor. | 2008-08-06 |
|
| Analogues of amphibian alkaloids: total synthesis of (5R,8S,8aS)-(-)-8-methyl-5-pentyloctahydroindolizine (8-epi-indolizidine 209B) and [(1S,4R,9aS)-(-)-4-pentyloctahydro-2H-quinolizin-1-yl]methanol. | 2008-01-18 |
|
| Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins. | 2007-12-13 |
|
| Part 2. Mechanistic aspects of the reduction of S-alkyl-thionocarbonates in the presence of triethylborane and air. | 2007-12-12 |
|
| Direct observation of the unstable intermediates in radical addition reaction by using an interfacing microchip combined with an NMR. | 2007-11 |
|
| Deoxygenative [1,2]-hydride shift rearrangements in nucleoside and sugar chemistry: analogy with the [1,2]-electron shift in the deoxygenation of ribonucleotides by ribonucleotide reductases. | 2007-10-26 |
|
| A convenient allylsilane-N-acyliminium route toward indolizidine and quinolizidine alkaloids. | 2007-10-02 |
|
| Rate constants for reactions of alkyl radicals with water and methanol complexes of triethylborane. | 2007-07-06 |
|
| Synthesis of 2',3'-dideoxyinosine via radical deoxygenation. | 2007 |
|
| Catalytic intermolecular enal-alkyne [3 + 2] reductive cycloadditions. | 2006-11-01 |
|
| Structure elucidation of the intermediate in triethylborane-mediated radical addition of oxime ethers with 2D- and 3D-DOSY NMR. | 2006-08 |
|
| Regio- and stereoselective nickel-catalyzed homoallylation of aldehydes with 1,3-dienes. | 2006-07-05 |
|
| New method for facile synthesis of amphiphilic thiol-stabilized ruthenium nanoparticles and their redox-active ruthenium nanocomposite. | 2005-12-20 |
|
| Use of allyl, 2-tetrahydrofuryl, and 2-tetrahydropyranyl ethers as useful C3-, C4-, and C5-carbon sources: palladium-catalyzed allylation of aldehydes. | 2005-11-04 |
|
| Diastereoselective intermolecular radical addition to nitrones. | 2005-08-19 |
|
| Radical addition approach to asymmetric amine synthesis: design, implementation, and comparison of chiral N-acylhydrazones. | 2005-08-05 |
|
| Triethylborane-induced intermolecular radical addition to ketimines. | 2005-04-15 |
|
| Pd-catalyzed C3-selective allylation of indoles with allyl alcohols promoted by triethylborane. | 2005-04-06 |
|
| Radical alkenylation of alpha-halo carbonyl compounds with alkenylindiums. | 2004-11-25 |
|
| Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes. | 2004-10-07 |
|
| Synthesis and catalytic properties of soluble platinum nanoparticles protected by a thiol monolayer. | 2004-07-06 |
|
| Solid-phase tandem radical addition-cyclization reaction: triethylborane-induced reaction of oxime ethers anchored to polymer support. | 2004-07 |
|
| [Development of radical reactions in water aimed at environmentally benign synthetic reactions]. | 2004-06 |
|
| A convenient tin-free procedure for radical carboazidation and azidation. | 2004-04-30 |
|
| Tributylgermanium hydride as a replacement for tributyltin hydride in radical reactions. | 2004-02-21 |
|
| Stannyl radical addition-cyclization of oxime ethers connected with olefins. | 2004-01 |
|
| Stereoselective synthesis of stannyl enones via palladium-catalyzed and free radical hydrostannation of alkynyl ketones with trineophyltin hydride. | 2003-12-26 |
|
| Synthesis and biological properties of 7alpha-cyano derivatives of the (17alpha,20E/Z)-[125I]iodovinyl- and 16alpha-[125I]iodo-estradiols. | 2003-12 |
|
| Triethylborane-mediated hydrogallation and hydroindation: novel access to organogalliums and organoindiums. | 2003-08-22 |
|
| [Development of carbon radical addition to imine derivatives]. | 2003-05 |
|
| Diastereoselective solid-phase radical addition to oxime ether anchored to polymer support. | 2003-05 |
|
| Et3B-induced radical addition of N,N-dichlorosulfonamide to alkenes and pyrrolidine formation via radical annulation. | 2003-04-18 |
|
| Hydroxyalkylation of alpha-C-H bonds of tetrahydrofuran with aldehydes in the presence of triethylborane and tert-butyl hydroperoxide. | 2003-01-24 |
|
| Radical addition to oxime ethers for asymmetric synthesis of beta-amino acid derivatives. | 2003-01-21 |
|
| Reactivity of 1,6-bis(trimethylsilyl)-hexa-3-ene-1,5-diynes towards triethylborane, triallylborane, and 1-boraadamantane: first molecular structure of a 4-methylene-3-borahomoadamantane derivative, and the first 6,8-diborabicyclo[2.2.2]oct-2-ene derivative. | 2002-04-02 |
|
| Aminoborohydrides. 14. Lithium aminoborohydrides in the selective reduction or amination of alkyl methanesulfonate esters. | 2001-11-29 |
|
| Triethylborane-induced bromine atom-transfer radical addition in aqueous media: study of the solvent effect on radical addition reactions. | 2001-11-16 |
|
| Novel synthesis of alkenes via triethylborane-induced free-radical reactions of alkyl iodides and beta-nitrostyrenes. | 2001-09-07 |
|
| Stereocontrol in radical processes through the exocyclic effect: dual role of triethylboron as radical initiator and in situ derivatization agent. | 2001-05-03 |
| Substance Class |
Chemical
Created
by
admin
on
Edited
Mon Mar 31 21:13:34 GMT 2025
by
admin
on
Mon Mar 31 21:13:34 GMT 2025
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| Record UNII |
Z3S980Z4P3
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| Record Status |
Validated (UNII)
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