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Details

Stereochemistry ACHIRAL
Molecular Formula C6H15B
Molecular Weight 97.994
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of TRIETHYLBORANE

SMILES

CCB(CC)CC

InChI

InChIKey=LALRXNPLTWZJIJ-UHFFFAOYSA-N
InChI=1S/C6H15B/c1-4-7(5-2)6-3/h4-6H2,1-3H3

HIDE SMILES / InChI

Molecular Formula C6H15B
Molecular Weight 97.994
Charge 0
Count
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Approval Year

PubMed

PubMed

TitleDatePubMed
Stereocontrol in radical processes through the exocyclic effect: dual role of triethylboron as radical initiator and in situ derivatization agent.
2001 May 3
Novel synthesis of alkenes via triethylborane-induced free-radical reactions of alkyl iodides and beta-nitrostyrenes.
2001 Sep 7
Reactivity of 1,6-bis(trimethylsilyl)-hexa-3-ene-1,5-diynes towards triethylborane, triallylborane, and 1-boraadamantane: first molecular structure of a 4-methylene-3-borahomoadamantane derivative, and the first 6,8-diborabicyclo[2.2.2]oct-2-ene derivative.
2002 Apr 2
Et3B-induced radical addition of N,N-dichlorosulfonamide to alkenes and pyrrolidine formation via radical annulation.
2003 Apr 18
Triethylborane-mediated hydrogallation and hydroindation: novel access to organogalliums and organoindiums.
2003 Aug 22
Synthesis and biological properties of 7alpha-cyano derivatives of the (17alpha,20E/Z)-[125I]iodovinyl- and 16alpha-[125I]iodo-estradiols.
2003 Dec
Radical addition to oxime ethers for asymmetric synthesis of beta-amino acid derivatives.
2003 Jan 21
Hydroxyalkylation of alpha-C-H bonds of tetrahydrofuran with aldehydes in the presence of triethylborane and tert-butyl hydroperoxide.
2003 Jan 24
[Development of carbon radical addition to imine derivatives].
2003 May
Diastereoselective solid-phase radical addition to oxime ether anchored to polymer support.
2003 May
Tributylgermanium hydride as a replacement for tributyltin hydride in radical reactions.
2004 Feb 21
Stannyl radical addition-cyclization of oxime ethers connected with olefins.
2004 Jan
Solid-phase tandem radical addition-cyclization reaction: triethylborane-induced reaction of oxime ethers anchored to polymer support.
2004 Jul
[Development of radical reactions in water aimed at environmentally benign synthetic reactions].
2004 Jun
Radical alkenylation of alpha-halo carbonyl compounds with alkenylindiums.
2004 Nov 25
Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes.
2004 Oct 7
Pd-catalyzed C3-selective allylation of indoles with allyl alcohols promoted by triethylborane.
2005 Apr 6
Radical addition approach to asymmetric amine synthesis: design, implementation, and comparison of chiral N-acylhydrazones.
2005 Aug 5
Regio- and stereoselective nickel-catalyzed homoallylation of aldehydes with 1,3-dienes.
2006 Jul 5
Catalytic intermolecular enal-alkyne [3 + 2] reductive cycloadditions.
2006 Nov 1
Direct observation of the unstable intermediates in radical addition reaction by using an interfacing microchip combined with an NMR.
2007 Nov
Deoxygenative [1,2]-hydride shift rearrangements in nucleoside and sugar chemistry: analogy with the [1,2]-electron shift in the deoxygenation of ribonucleotides by ribonucleotide reductases.
2007 Oct 26
Reductive coupling of carbon monoxide in a rhenium carbonyl complex with pendant Lewis acids.
2008 Sep 10
Macrocyclization by nickel-catalyzed, ester-promoted, epoxide-alkyne reductive coupling: total synthesis of (-)-gloeosporone.
2009
Rh-catalyzed reductive coupling reaction of aldehydes with conjugated dienes promoted by triethylborane.
2009 Sep 3
A formal synthesis of the C1-C9 fragment of amphidinolide C employing the Tamaru reaction.
2010 Jul 2
Synthesis of marine polycyclic polyethers via endo-selective epoxide-opening cascades.
2010 Mar 19
Patents
Substance Class Chemical
Created
by admin
on Sat Dec 16 02:27:48 GMT 2023
Edited
by admin
on Sat Dec 16 02:27:48 GMT 2023
Record UNII
Z3S980Z4P3
Record Status Validated (UNII)
Record Version
  • Download
Name Type Language
TRIETHYLBORANE
MI  
Systematic Name English
TRIETHYLBORON
Systematic Name English
TRIETHYLBORANE [MI]
Common Name English
BORANE, TRIETHYL-
Systematic Name English
Code System Code Type Description
FDA UNII
Z3S980Z4P3
Created by admin on Sat Dec 16 02:27:48 GMT 2023 , Edited by admin on Sat Dec 16 02:27:48 GMT 2023
PRIMARY
EPA CompTox
DTXSID2052653
Created by admin on Sat Dec 16 02:27:48 GMT 2023 , Edited by admin on Sat Dec 16 02:27:48 GMT 2023
PRIMARY
CAS
97-94-9
Created by admin on Sat Dec 16 02:27:48 GMT 2023 , Edited by admin on Sat Dec 16 02:27:48 GMT 2023
PRIMARY
ECHA (EC/EINECS)
202-620-9
Created by admin on Sat Dec 16 02:27:48 GMT 2023 , Edited by admin on Sat Dec 16 02:27:48 GMT 2023
PRIMARY
WIKIPEDIA
TRIETHYLBORANE
Created by admin on Sat Dec 16 02:27:48 GMT 2023 , Edited by admin on Sat Dec 16 02:27:48 GMT 2023
PRIMARY
MERCK INDEX
m11103
Created by admin on Sat Dec 16 02:27:48 GMT 2023 , Edited by admin on Sat Dec 16 02:27:48 GMT 2023
PRIMARY Merck Index
HSDB
897
Created by admin on Sat Dec 16 02:27:48 GMT 2023 , Edited by admin on Sat Dec 16 02:27:48 GMT 2023
PRIMARY
PUBCHEM
7357
Created by admin on Sat Dec 16 02:27:48 GMT 2023 , Edited by admin on Sat Dec 16 02:27:48 GMT 2023
PRIMARY