U.S. Department of Health & Human Services Divider Arrow National Institutes of Health Divider Arrow NCATS

Details

Stereochemistry ACHIRAL
Molecular Formula C3H9O4P
Molecular Weight 140.0749
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of TRIMETHYL PHOSPHATE

SMILES

COP(=O)(OC)OC

InChI

InChIKey=WVLBCYQITXONBZ-UHFFFAOYSA-N
InChI=1S/C3H9O4P/c1-5-8(4,6-2)7-3/h1-3H3

HIDE SMILES / InChI

Molecular Formula C3H9O4P
Molecular Weight 140.0749
Charge 0
Count
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Approval Year

PubMed

PubMed

TitleDatePubMed
Overview of studies on rat sperm motion analysis using a Hamilton-Thorne Sperm Analyzer--collaborative working study.
2001 Dec
Methylation of neutral pseudotetrahedral zinc thiolate complexes: model reactions for alkyl group transfer to sulfur by zinc-containing enzymes.
2001 Jan
Functional modeling of cobalamine-independent methionine synthase with pyrazolylborate-zinc-thiolate complexes.
2001 Nov 19
Synthesis of (S)-isoprenoid thiodiphosphates as substrates and inhibitors.
2001 Oct 5
Gas chromatography-mass spectrometry assay of the (18)o enrichment of water as trimethyl phosphate.
2002 Jul 15
Chemistry. Whisper of magnetism tells molecules apart.
2002 Mar 22
Preparation of (cyanomethylene)trimethylphosphorane as a new Mitsunobu-type reagent.
2003 Apr
Zinc mediated methyl transfer from trimethyl phosphate to chelating and non-chelating alkyl thiols. Model for Zn-dependent methyltransferases.
2003 Feb 1
Trimethyl phosphite as a trap for alkoxy radicals formed from the ring opening of oxiranylcarbinyl radicals. Conversion to alkenes. Mechanistic applications to the study of C-C versus C-O ring cleavage.
2003 Mar 19
Gas-phase reactivity of the O=P(OCH3)2 + phosphonium ion towards alpha,beta-unsaturated esters in a quadrupole ion trap.
2005 Apr
The structure of an enzyme-product complex reveals the critical role of a terminal hydroxide nucleophile in the bacterial phosphotriesterase mechanism.
2005 Aug 31
Theoretical studies of the hydroxide-catalyzed P-O cleavage reactions of neutral phosphate triesters and diesters in aqueous solution: examination of the changes induced by H/Me substitution.
2005 Dec 1
Uranyl extraction by beta-diketonate ligands to SC-CO2: theoretical studies on the effect of ligand fluorination and on the synergistic effect of TBP.
2005 Jan 13
Effect of the TBP and water on the complexation of uranyl nitrate and the dissolution of nitric acid into supercritical CO2. A Theoretical Study.
2005 Jun 16
Thiolysis and alcoholysis of phosphate tri- and monoesters with alkyl and aryl leaving groups. An ab initio study in the gas phase.
2005 Jun 30
Zinc-thiolate complexes of the bis(pyrazolyl)(thioimidazolyl)hydroborate tripods for the modeling of thiolate alkylating enzymes.
2005 May 16
Does phosphoryl protonation occurs in aqueous phosphoesters solutions.
2005 Nov
Tris(thioimidazolyl)borate-zinc-thiolate complexes for the modeling of biological thiolate alkylations.
2005 Nov 14
Expression of mucin genes in the human testis and its relationship to spermatogenesis.
2005 Oct 31
Total dissociative electron attachment cross sections for molecular constituents of DNA.
2006 Aug 7
Five-coordinate aluminum bromides: synthesis, structure, cation formation, and cleavage of phosphate ester bonds.
2006 Feb 1
J-coupling nuclear magnetic resonance spectroscopy of liquids in nT fields.
2006 Jan 25
Synthesis, structural characterization and the first electroluminescent properties of tris- and bis-cycloiridiated complexes of sterically hindered electron-poor 2-(3,5-bis(trifluoromethyl)phenyl)-4-trifluoromethylpyridine.
2006 May 28
Mononuclear Schiff base boron halides: synthesis, characterization, and dealkylation of trimethyl phosphate.
2006 Nov 13
Air sampling with Empore solid phase extraction membranes and online single-channel desorption/liquid chromatography/mass spectrometry analysis: determination of volatile and semi-volatile organophosphate esters.
2006 Sep 29
Liquid chromatography/tandem mass spectrometry determination of organophosphorus flame retardants and plasticizers in drinking and surface waters.
2007
Synthesis and biological evaluation of phosphate prodrugs of 4-phospho-D-erythronohydroxamic acid, an inhibitor of 6-phosphogluconate dehydrogenase.
2007 Aug
Mechanism of SN2 disulfide bond cleavage by phosphorus nucleophiles. Implications for biochemical disulfide reducing agents.
2007 Oct 26
Phosphorescent organic light-emitting devices: working principle and iridium based emitter materials.
2008 Aug
A simple model for metal cation-phosphate interactions in nucleic acids in the gas phase: alkali metal cations and trimethyl phosphate.
2008 Feb
Hydroxyapatite coating on Ti6Al4V alloy by a sol-gel method.
2008 Jun
Are there pi* shape resonances in electron scattering from phosphate groups?
2008 May 1
A tetra-substituted chrysene: orientation of multiple electrophilic substitution and use of a tetra-substituted chrysene as a blue emitter for OLEDs.
2008 May 28
Gas-phase vibrational spectroscopy and ab initio study of organophosphorus compounds: discrimination between species and conformers.
2008 Oct 2
Kinetics and mechanism for degradation of dichlorvos by permanganate in drinking water treatment.
2009 Aug
The diatomic dication PO2+.
2009 Aug 7
Rapid estimation of trace organophosphonate used as a scale inhibitor in aqueous systems by reactive pyrolysis-gas chromatography/mass spectrometry.
2009 Jul 3
Gas-phase synchrotron FTIR spectroscopy of weakly volatile alkyl phosphonate and alkyl phosphate compounds: vibrational and conformational analysis in the terahertz/far-IR spectral domain.
2010 Dec 23
Facile small scale synthesis of nucleoside 5'-phosphate mixtures.
2010 Jan
3-Methyl-quinoxaline-2-carb-oxy-lic acid 4-oxide monohydrate.
2010 Jun 26
Mechanistic and computational study of a palladacycle-catalyzed decomposition of a series of neutral phosphorothioate triesters in methanol.
2010 Nov 24
Affinities of organophosphate flame retardants to tumor suppressor gene p53: an integrated in vitro and in silico study.
2015 Jan 22
Patents
Substance Class Chemical
Created
by admin
on Sat Dec 16 08:21:49 GMT 2023
Edited
by admin
on Sat Dec 16 08:21:49 GMT 2023
Record UNII
Z1E45TMW1Z
Record Status Validated (UNII)
Record Version
  • Download
Name Type Language
TRIMETHYL PHOSPHATE
HSDB  
Systematic Name English
TRIMETHOXYPHOSPHINE OXIDE
Systematic Name English
TMPA
Common Name English
TRIMETHYL ORTHOPHOSPHATE
Systematic Name English
METHYL PHOSPHATE, (MEO)3PO
Common Name English
TMP (PHOSPHATE)
Common Name English
NSC-58985
Code English
PHOSPHORIC ACID, TRIMETHYL ESTER
Systematic Name English
TRIMETHYL PHOSPHATE [HSDB]
Common Name English
Code System Code Type Description
FDA UNII
Z1E45TMW1Z
Created by admin on Sat Dec 16 08:21:49 GMT 2023 , Edited by admin on Sat Dec 16 08:21:49 GMT 2023
PRIMARY
EPA CompTox
DTXSID1021403
Created by admin on Sat Dec 16 08:21:49 GMT 2023 , Edited by admin on Sat Dec 16 08:21:49 GMT 2023
PRIMARY
HSDB
5090
Created by admin on Sat Dec 16 08:21:49 GMT 2023 , Edited by admin on Sat Dec 16 08:21:49 GMT 2023
PRIMARY
CAS
512-56-1
Created by admin on Sat Dec 16 08:21:49 GMT 2023 , Edited by admin on Sat Dec 16 08:21:49 GMT 2023
PRIMARY
NSC
58985
Created by admin on Sat Dec 16 08:21:49 GMT 2023 , Edited by admin on Sat Dec 16 08:21:49 GMT 2023
PRIMARY
WIKIPEDIA
Trimethyl phosphate
Created by admin on Sat Dec 16 08:21:49 GMT 2023 , Edited by admin on Sat Dec 16 08:21:49 GMT 2023
PRIMARY
ECHA (EC/EINECS)
208-144-8
Created by admin on Sat Dec 16 08:21:49 GMT 2023 , Edited by admin on Sat Dec 16 08:21:49 GMT 2023
PRIMARY
CHEBI
46324
Created by admin on Sat Dec 16 08:21:49 GMT 2023 , Edited by admin on Sat Dec 16 08:21:49 GMT 2023
PRIMARY
PUBCHEM
10541
Created by admin on Sat Dec 16 08:21:49 GMT 2023 , Edited by admin on Sat Dec 16 08:21:49 GMT 2023
PRIMARY