(N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE)MANGANESE(III) CHLORIDE, (R,R)-

Details

Stereochemistry	ABSOLUTE
Molecular Formula	C36H52N2O2.Cl.Mn
Molecular Weight	635.201
Optical Activity	UNSPECIFIED
Defined Stereocenters	2 / 2
E/Z Centers	2
Charge	0

SHOW SMILES / InChI

Structure of (N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE)MANGANESE(III) CHLORIDE, (R,R)-

Structure Search

SMILES

[Cl-].[Mn+3].CC(C)(C)C1=CC(=C([O-])C(\C=N\[C@@H]2CCCC[C@H]2\N=C\C3=C([O-])C(=CC(=C3)C(C)(C)C)C(C)(C)C)=C1)C(C)(C)C

InChI

InChIKey=LJVAWOSDJSQANR-OHRASPNLSA-K

InChI=1S/C36H54N2O2.ClH.Mn/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m1../s1

HIDE SMILES / InChI

Molecular Formula	C36H52N2O2
Molecular Weight	544.8103
Charge	-2
Count

Stereochemistry	ABSOLUTE
Additional Stereochemistry	No
Defined Stereocenters	2 / 2
E/Z Centers	2
Optical Activity	UNSPECIFIED

Molecular Formula	Mn
Molecular Weight	54.938045
Charge	3
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Molecular Formula	ClH
Molecular Weight	36.461
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

Substance Class	Chemical Created by `admin` on `Mon Mar 31 22:00:16 GMT 2025` Edited by `admin` on `Mon Mar 31 22:00:16 GMT 2025`
Record UNII	WPP775Y8PO
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

(N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE)MANGANESE(III) CHLORIDE, (R,R)-

Common Name

English

(R,R)-JACOBSEN'S CATALYST

Preferred Name

English

MANGANESE, CHLORO((2,2'-((1R,2R)-1,2-CYCLOHEXANEDIYLBIS((NITRILO-.KAPPA.N)METHYLIDYNE))BIS(4,6-BIS(1,1-DIMETHYLETHYL)PHENOLATO-.KAPPA.O))(2-))-, (SP-5-13)-

Systematic Name

English

(R,R)-(N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE)MANGANESE(III) CHLORIDE

Systematic Name

English

(-)-CHLORO((1R,2R)-4,4',6,6'-TETRA-TERT-BUTYL-2,2'-(CYCLOHEXANE-1,2-DIYLBIS(NITRILOMETHYLIDYNE))DIPHENOLATO(MANGANESE(III)

Systematic Name

English

JACOBSEN'S CATALYST (R,R)-FORM [MI]

Common Name

English

Code System Code Type Description

CAS

138124-32-0

Created by admin on Mon Mar 31 22:00:16 GMT 2025 , Edited by admin on Mon Mar 31 22:00:16 GMT 2025

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FDA UNII

WPP775Y8PO

Created by admin on Mon Mar 31 22:00:16 GMT 2025 , Edited by admin on Mon Mar 31 22:00:16 GMT 2025

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MERCK INDEX

m6570

Created by admin on Mon Mar 31 22:00:16 GMT 2025 , Edited by admin on Mon Mar 31 22:00:16 GMT 2025

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Merck Index

WIKIPEDIA

Jacobsen's catalyst

Created by admin on Mon Mar 31 22:00:16 GMT 2025 , Edited by admin on Mon Mar 31 22:00:16 GMT 2025

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