Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C6H5BO2 |
| Molecular Weight | 119.914 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
B1OC2=C(O1)C=CC=C2
InChI
InChIKey=CENMEJUYOOMFFZ-UHFFFAOYSA-N
InChI=1S/C6H5BO2/c1-2-4-6-5(3-1)8-7-9-6/h1-4,7H
| Molecular Formula | C6H5BO2 |
| Molecular Weight | 119.914 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Asymmetric reduction of ketones with catecholborane using 2,6-BODOL complexes of titanium(IV) as catalysts. | 2001 May 18 |
|
| An unprecedented recyclable catalyst system for asymmetric hydroboration. | 2001 Sep 21 |
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| Asymmetric synthesis of a selective endothelin A receptor antagonist. | 2002 Aug |
|
| Asymmetric synthesis of syn- and anti-1,3-amino alcohols. | 2002 Jun 12 |
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| Borane-mediated aldol cycloreduction of monoenone monoketones: diastereoselective formation of quaternary centers. | 2003 Jan 10 |
|
| Substrate-controlled highly diastereoselective synthesis of primary and secondary diorganozinc reagents by hydroboration/boron-zinc exchange sequence. | 2003 Jun 16 |
|
| Addition reactions at the 16(17) double bond of 3-methoxy-13alpha-estra-1,3,5(10),16-tetraene. | 2003 Mar |
|
| Effective modular iminooxazoline (IMOX) ligands for asymmetric catalysis: [Zn(IMOX)]-promoted enantioselective reduction of ketones by catecholborane. | 2003 Oct 20 |
|
| Development and application of a new general method for the asymmetric synthesis of syn- and anti-1,3-amino alcohols. | 2003 Sep 17 |
|
| On the origin of regio- and stereoselectivity in the rhodium-catalyzed vinylarenes hydroboration reaction. | 2004 Apr 16 |
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| Formation of inclusion organoactinide complexes with boron-containing macrocycles. | 2004 Apr 28 |
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| Regio- and enantiocontrol in the room-temperature hydroboration of vinyl arenes with pinacol borane. | 2004 Aug 4 |
|
| Six- and eightfold palladium-catalyzed cross-coupling reactions of hexa- and octabromoarenes. | 2004 Dec 17 |
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| In quest of factors that control the enantioselective catalytic Markovnikov hydroboration/oxidation of vinylarenes. | 2004 Dec 3 |
|
| Structure investigation of TiIV-BODOLates involved in the catalytic asymmetric reduction of ketones using catecholborane. | 2004 Jan 5 |
|
| Transition-metal-mediated synthesis of novel carbocyclic nucleoside analogues with antitumoral activity. | 2004 Oct 11 |
|
| Eremophilane sesquiterpenes from capsidiol. | 2004 Oct 29 |
|
| Fully stereocontrolled total syntheses of the prostacyclin analogues 16S-iloprost and 16S-3-oxa-iloprost by a common route, using alkenylcopper-azoalkene conjugate addition, asymmetric olefination, and allylic alkylation. | 2005 Dec 21 |
|
| A convenient synthesis of immunosuppressive agent FTY720 using the petasis reaction. | 2005 Jan |
|
| Photoswitching of the Lewis acidity of a catecholborane bearing an azo group based on the change in coordination number of boron. | 2005 Sep 1 |
|
| Development of a common fully stereocontrolled access to the medicinally important and promising prostacyclin analogues iloprost, 3-oxa-iloprost and cicaprost. | 2006 Jul 17 |
|
| TADDOL-derived phosphites and phosphoramidites for efficient rhodium-catalyzed asymmetric hydroboration. | 2006 Jul 6 |
|
| Rhodium-catalyzed asymmetric cyclization/hydroboration of 1,6-enynes. | 2006 May 11 |
|
| Structural elucidation of a nickel boryl complex. A recyclable borylation Ni(II) reagent of bromobenzene. | 2007 Nov 21 |
|
| C-H bond activation of heteroarenes mediated by a half-sandwich iron complex of N-heterocyclic carbene. | 2008 Dec 17 |
|
| Activation of B-H bonds by an oxo-rhenium complex. | 2008 Dec 21 |
|
| Chemo-, regio-, and stereoselectivity of F-ring opening reactions in the cephalostatin series. | 2008 Jan 1 |
|
| Oxygen-directed intramolecular hydroboration. | 2008 Jul 23 |
|
| Synthesis, characterization, and reactivity of rhodium(I) acetylacetonato complexes containing pyridinecarboxaldimine ligands. | 2008 Oct 6 |
|
| Highly enantioselective oxazaborolidine-catalyzed reduction of 1,3-dicarbonyl compounds: role of the additive diethylaniline. | 2009 Apr 2 |
|
| Total synthesis and absolute configuration of the marine norditerpenoid xestenone. | 2009 Nov 24 |
|
| Enantioselective, organocatalytic reduction of ketones using bifunctional thiourea-amine catalysts. | 2010 Apr 16 |
|
| An efficient nickel catalyst for the reduction of carbon dioxide with a borane. | 2010 Jul 7 |
|
| Synthesis of syn-gamma-amino-beta-hydroxyphosphonates by reduction of beta-ketophosphonates derived from L-proline and L-serine. | 2010 Mar 4 |
|
| Electronic tuning of a carbene center via remote chemical induction, and relevant effects in catalysis. | 2010 Oct 4 |
| Substance Class |
Chemical
Created
by
admin
on
Edited
Sat Dec 16 02:24:40 GMT 2023
by
admin
on
Sat Dec 16 02:24:40 GMT 2023
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| Record UNII |
UB69382H5J
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| Record Status |
Validated (UNII)
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| Record Version |
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m3173
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DTXSID3059769
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67506
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274-07-7
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205-991-5
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UB69382H5J
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CATECHOLBORANE
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