Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C3H5Cl3Si |
| Molecular Weight | 175.516 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
Cl[Si](Cl)(Cl)CC=C
InChI
InChIKey=HKFSBKQQYCMCKO-UHFFFAOYSA-N
InChI=1S/C3H5Cl3Si/c1-2-3-7(4,5)6/h2H,1,3H2
| Molecular Formula | C3H5Cl3Si |
| Molecular Weight | 175.516 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Aryl tert-butyl sulfoxide-promoted highly enantioselective addition of allyltrichlorosilane to aldehydes. | 2009-09-21 |
|
| Vibrational spectra of metals treated with allyltrimethoxysilane sol-gel and self-assembled monolayer of allytrichlorosilane. | 2007-07 |
|
| C2-symmetric bissulfoxides as organocatalysts in the allylation of benzoyl hydrazones: spacer and concentration effects. | 2007-05-24 |
|
| First enantioselective organocatalytic allylation of simple aldimines with allyltrichlorosilane. | 2006-12-07 |
|
| Ultraviolet photochemistry of trichlorovinylsilane and allyltrichlorosilane: vinyl radical (HCCH2) and allyl radical (H2CCHCH2) production in 193 nm photolysis. | 2006-05-21 |
|
| Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative studies with bidentate phosphorus-based amides. | 2006-02-17 |
|
| Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative and mechanistic studies with monodentate phosphorus-based amides. | 2006-02-17 |
|
| Structurally simple pyridine N-oxides as efficient organocatalysts for the enantioselective allylation of aromatic aldehydes. | 2006-02-17 |
|
| Readily available pyridine- and quinoline-N-oxides as new organocatalysts for the enantioselective allylation of aromatic aldehydes with allyl(trichloro)silane. | 2005-08 |
|
| METHOX: a new pyridine N-oxide organocatalyst for the asymmetric allylation of aldehydes with allyltrichlorosilanes. | 2005-07-21 |
|
| Proline-based N-oxides as readily available and modular chiral catalysts. Enantioselective reactions of allyltrichlorosilane with aldehydes. | 2005-07-21 |
|
| Polystyrenes with chiral phosphoramide substituents as Lewis base catalysts for asymmetric addition of allyltrichlorosilane: enhancement of catalytic performance by polymer effect. | 2005-04-14 |
|
| The first series of chiral 2,2':6',2''-terpyridine tri-N-oxide ligands for Lewis base-catalyzed asymmetric allylation of aldehydes. | 2004-07-21 |
|
| The first catalytic asymmetric allylation of imines with the tetraallylsilane-TBAF-MeOH system, using the chiral bis-pi-allylpalladium complex. | 2004-02-06 |
|
| New Lewis-basic N-oxides as chiral organocatalysts in asymmetric allylation of aldehydes. | 2003-12-12 |
|
| Chiral sulfoxides in the enantioselective allylation of aldehydes with allyltrichlorosilane. | 2003-11-07 |
|
| A new synthetic route to enantiomerically pure axially chiral 2,2'-bipyridine N,N'-dioxides. Highly efficient catalysts for asymmetric allylation of aldehydes with allyl(trichloro)silanes. | 2003-08-08 |
|
| Polymer-supported formamides as reusable organocatalysts for allylation of aldehydes with allyltrichlorosilane. | 2003-01-21 |
|
| A novel axially chiral 2,2'-bipyridine N,N'-dioxide. Its preparation and use for asymmetric allylation of aldehydes with allyl(trichloro)silane as a highly efficient catalyst. | 2002-08-08 |
|
| Chiral 2,2'-bipyridine-type N-monoxides as organocatalysts in the enantioselective allylation of aldehydes with allyltrichlorosilane. | 2002-03-21 |
|
| Highly stereoselective synthesis of homoallylic amines based on addition of allyltrichlorosilanes to benzoylhydrazones. | 2001-10-03 |
Patents
| Substance Class |
Chemical
Created
by
admin
on
Edited
Mon Mar 31 22:21:50 GMT 2025
by
admin
on
Mon Mar 31 22:21:50 GMT 2025
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| Record UNII |
UB3N98803N
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| Record Status |
Validated (UNII)
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UB3N98803N
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7867
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2715
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DTXSID3059347
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203-485-9
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107-37-9
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Allyltrichlorosilane
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