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Details

Stereochemistry ACHIRAL
Molecular Formula Ce.6NO3.2H4N
Molecular Weight 548.222
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of CERIC AMMONIUM NITRATE

SMILES

[NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

InChIKey=XMPZTFVPEKAKFH-UHFFFAOYSA-P
InChI=1S/Ce.6NO3.2H3N/c;6*2-1(3)4;;/h;;;;;;;2*1H3/q+4;6*-1;;/p+2

HIDE SMILES / InChI

Molecular Formula NO3
Molecular Weight 62.0049
Charge -1
Count
MOL RATIO 6 MOL RATIO (average)
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Molecular Formula H3N
Molecular Weight 17.0305
Charge 0
Count
MOL RATIO 2 MOL RATIO (average)
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Molecular Formula Ce
Molecular Weight 140.116
Charge 4
Count
MOL RATIO 1 MOL RATIO (average)
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Description

Ceric ammonium nitrate is the orange-red, water-soluble cerium salt used as the specialized oxidizing agent in organic synthesis and a standard oxidant in quantitative analysis. Ceric ammonium nitrate is essentially an oxidizing agent that comprises one electron that allows intramolecular and intermolecular carbon to hetero and carbon to carbon atom bond formation. In addition, it is utilized as an oxidizing agent for secondary alcohols that turn it into benzylic and ketones alcohols, which are oxidized into aldehydes.

Approval Year

Substance Class Chemical
Record UNII
U99S55ED6B
Record Status Validated (UNII)
Record Version