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Details

Stereochemistry RACEMIC
Molecular Formula C6H14OS
Molecular Weight 134.24
Optical Activity ( + / - )
Defined Stereocenters 0 / 1
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of 3-MERCAPTOHEXANOL

SMILES

CCCC(S)CCO

InChI

InChIKey=TYZFMFVWHZKYSE-UHFFFAOYSA-N
InChI=1S/C6H14OS/c1-2-3-6(8)4-5-7/h6-8H,2-5H2,1H3

HIDE SMILES / InChI

Molecular Formula C6H14OS
Molecular Weight 134.24
Charge 0
Count
Stereochemistry RACEMIC
Additional Stereochemistry No
Defined Stereocenters 0 / 1
E/Z Centers 0
Optical Activity ( + / - )

Approval Year

PubMed

PubMed

TitleDatePubMed
Melting temperature of surface-tethered DNA.
2010-11-01
Elucidation of the 1,3-sulfanylalcohol oxidation mechanism: an unusual identification of the disulfide of 3-sulfanylhexanol in sauternes botrytized wines.
2010-10-13
Analysis, occurrence, and potential sensory significance of five polyfunctional mercaptans in white wines.
2010-09-22
Controlled orientation of DNA in a binary SAM as a key for the successful determination of DNA hybridization by means of electrochemical impedance spectroscopy.
2010-09-10
Understanding the role of thiol and disulfide self-assembled DNA receptor monolayers for biosensing applications.
2010-09
A comparison of laboratory and pilot-scale fermentations in winemaking conditions.
2010-08
Influence of juice pressing conditions on polyphenols, antioxidants, and varietal aroma of Sauvignon blanc microferments.
2010-06-23
Evolution of S-cysteinylated and S-glutathionylated thiol precursors during oxidation of Melon B. and Sauvignon blanc musts.
2010-04-14
Validation of a nanoliquid chromatography-tandem mass spectrometry method for the identification and the accurate quantification by isotopic dilution of glutathionylated and cysteinylated precursors of 3-mercaptohexan-1-ol and 4-mercapto-4-methylpentan-2-one in white grape juices.
2010-03-05
Aromatic potential of botrytized white wine grapes: identification and quantification of new cysteine-S-conjugate flavor precursors.
2010-02-15
Reactivity of volatile thiols with polyphenols in a wine-model medium: impact of oxygen, iron, and sulfur dioxide.
2010-02-15
Analysis of precursors to wine odorant 3-mercaptohexan-1-ol using HPLC-MS/MS: resolution and quantitation of diastereomers of 3-S-cysteinylhexan-1-ol and 3-S-glutathionylhexan-1-ol.
2010-02-10
Synthesis of wine thiol conjugates and labeled analogues: fermentation of the glutathione conjugate of 3-mercaptohexan-1-ol yields the corresponding cysteine conjugate and free thiol.
2010-02-10
Impact of oxygen dissolved at bottling and transmitted through closures on the composition and sensory properties of a Sauvignon Blanc wine during bottle storage.
2009-11-11
Selective preconcentration of volatile mercaptans in small SPE cartridges: quantitative determination of trace odor-active polyfunctional mercaptans in wine.
2009-11
Fate of key odorants in Sauternes wines through aging.
2009-09-23
Improved method to quantitatively determine powerful odorant volatile thiols in wine by headspace solid-phase microextraction after derivatization.
2009-07-24
Characterization of the key aroma compounds in pink guava (Psidium guajava L.) by means of aroma re-engineering experiments and omission tests.
2009-04-08
Rapid glucose detection by surface enhanced Raman scattering spectroscopy.
2009-04
The influence of yeast on the aroma of Sauvignon Blanc wine.
2009-04
A new efficient enantioselective synthesis of (+)-cis-2-methyl-4-propyl-1,3-oxathiane, a valuable ingredient for the aroma of passion fruit.
2009-01
Coinoculated fermentations using saccharomyces yeasts affect the volatile composition and sensory properties of Vitis vinifera L. cv. sauvignon blanc wines.
2008-11-26
Nitrogen catabolic repression controls the release of volatile thiols by Saccharomyces cerevisiae during wine fermentation.
2008-11
New insights on 3-mercaptohexanol (3MH) biogenesis in Sauvignon Blanc wines: Cys-3MH and (E)-hexen-2-al are not the major precursors.
2008-10-08
Nitrogen catabolite repression modulates the production of aromatic thiols characteristic of Sauvignon Blanc at the level of precursor transport.
2008-08
Hyphenated gas chromatography-mass spectrometry analysis of 3-mercaptohexan-1-ol and 3-mercaptohexyl acetate in wine: Comparison with results of other sampling procedures via a robust regression.
2008-07-21
Characterization of the aroma-active compounds in pink guava (Psidium guajava, L.) by application of the aroma extract dilution analysis.
2008-06-11
Synthesis of the individual diastereomers of the cysteine conjugate of 3-mercaptohexanol (3-MH).
2008-05-28
Quantification of cysteine S-conjugate of 3-sulfanylhexan-1-ol in must and wine of petite arvine vine by stable isotope dilution analysis.
2008-05-14
Improved solid-phase extraction procedure for the isolation and in-sorbent pentafluorobenzyl alkylation of polyfunctional mercaptans. Optimized procedure and analytical applications.
2008-03-21
Analysis of the diastereoisomers of the cysteinylated aroma precursor of 3-sulfanylhexanol in Vitis vinifera grape must by gas chromatography coupled with ion trap tandem mass spectrometry.
2008-03-07
Effect of skin contact and pressure on the composition of Sauvignon Blanc must.
2007-12-12
Gas chromatography-mass spectrometry determination of 3-mercaptohexan-1-ol and 3-mercaptohexyl acetate in wine: a comparison of headspace solid phase microextraction and solid phase extraction methods.
2007-07-23
Engineering volatile thiol release in Saccharomyces cerevisiae for improved wine aroma.
2007-07
Volatile organic sulfur-containing constituents in Poncirus trifoliata (L.) Raf. (Rutaceae).
2007-05-30
Quantitative determination of wine polyfunctional mercaptans at nanogram per liter level by gas chromatography-negative ion mass spectrometric analysis of their pentafluorobenzyl derivatives.
2007-04-06
Modulation of volatile sulfur compounds by wine yeast.
2007-04
Optimization of a procedure for the selective isolation of some powerful aroma thiols. Development and validation of a quantitative method for their determination in wine.
2007-03-02
Odorous impact of volatile thiols on the aroma of young botrytized sweet wines: identification and quantification of new sulfanyl alcohols.
2007-02-21
Stereoisomeric distribution of 3-mercaptohexan-1-ol and 3-mercaptohexyl acetate in dry and sweet white wines made from Vitis vinifera (Var. Sauvignon Blanc and Semillon).
2006-09-20
Aroma extraction dilution analysis of Sauternes wines. Key role of polyfunctional thiols.
2006-09-20
Automated analysis of 2-methyl-3-furanthiol and 3-mercaptohexyl acetate at ng L(-1) level by headspace solid-phase microextracion with on-fibre derivatisation and gas chromatography-negative chemical ionization mass spectrometric determination.
2006-07-14
Identification of single-strand DNA by in situ scanning tunneling microscopy.
2006-06-21
Comparison of volatile constituents of Persicaria odorata(Lour.) Soják (Polygonum odoratum Lour.) and Persicaria hydropiper L. Spach (Polygonum hydropiper L.).
2006-04-19
Effect of screwcap and cork closures on SO2 levels and aromas in a Sauvignon Blanc wine.
2005-12-28
Real-time glucose sensing by surface-enhanced Raman spectroscopy in bovine plasma facilitated by a mixed decanethiol/mercaptohexanol partition layer.
2005-10-01
Identification of odoriferous sulfanylalkanols in human axilla secretions and their formation through cleavage of cysteine precursors by a C-S lyase isolated from axilla bacteria.
2004-07
Gas chromatography-olfactometry and chemical quantitative study of the aroma of six premium quality spanish aged red wines.
2004-03-24
Stereochemical course of the generation of 3-mercaptohexanal and 3-mercaptohexanol by beta-lyase-catalyzed cleavage of cysteine conjugates.
2004-01-14
Stereoselectivity of the generation of 3-mercaptohexanal and 3-mercaptohexanol by lipase-catalyzed hydrolysis of 3-acetylthioesters.
2003-07-16
Patents
Substance Class Chemical
Created
by admin
on Mon Mar 31 20:07:20 GMT 2025
Edited
by admin
on Mon Mar 31 20:07:20 GMT 2025
Record UNII
U3TIX8Z92N
Record Status Validated (UNII)
Record Version
  • Download
Name Type Language
3-MERCAPTOHEXANOL
FHFI  
Systematic Name English
FEMA NO. 3850
Preferred Name English
3-MERCAPTO-1-HEXANOL
Systematic Name English
3-MERCAPTOHEXANOL [FHFI]
Common Name English
FEMA NO. 3851, MERCAPTOHEXANOL-
Code English
3-MERCAPTOHEXANOL, (±)-
Systematic Name English
3-SULFANYLHEXAN-1-OL
Systematic Name English
1-HEXANOL, 3-MERCAPTO-
Systematic Name English
Classification Tree Code System Code
JECFA EVALUATION 3-MERCAPTOHEXANOL
Created by admin on Mon Mar 31 20:07:20 GMT 2025 , Edited by admin on Mon Mar 31 20:07:20 GMT 2025
Code System Code Type Description
CHEBI
77690
Created by admin on Mon Mar 31 20:07:20 GMT 2025 , Edited by admin on Mon Mar 31 20:07:20 GMT 2025
PRIMARY
CAS
51755-83-0
Created by admin on Mon Mar 31 20:07:20 GMT 2025 , Edited by admin on Mon Mar 31 20:07:20 GMT 2025
PRIMARY
EPA CompTox
DTXSID70866216
Created by admin on Mon Mar 31 20:07:20 GMT 2025 , Edited by admin on Mon Mar 31 20:07:20 GMT 2025
PRIMARY
FDA UNII
U3TIX8Z92N
Created by admin on Mon Mar 31 20:07:20 GMT 2025 , Edited by admin on Mon Mar 31 20:07:20 GMT 2025
PRIMARY
MESH
C477019
Created by admin on Mon Mar 31 20:07:20 GMT 2025 , Edited by admin on Mon Mar 31 20:07:20 GMT 2025
PRIMARY
JECFA MONOGRAPH
495
Created by admin on Mon Mar 31 20:07:20 GMT 2025 , Edited by admin on Mon Mar 31 20:07:20 GMT 2025
PRIMARY
PUBCHEM
521348
Created by admin on Mon Mar 31 20:07:20 GMT 2025 , Edited by admin on Mon Mar 31 20:07:20 GMT 2025
PRIMARY