Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C3H6O2 |
| Molecular Weight | 74.0785 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
CC1(C)OO1
InChI
InChIKey=FFHWGQQFANVOHV-UHFFFAOYSA-N
InChI=1S/C3H6O2/c1-3(2)4-5-3/h1-2H3
| Molecular Formula | C3H6O2 |
| Molecular Weight | 74.0785 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Analysis of residual chemicals on filtering facepiece respirators after decontamination. | 2010-08 |
|
| Reactions of 7,8-dithiabicyclo[4.2.1]nona-2,4-diene 7-exo-oxide with dodecacarbonyl triiron Fe3(CO)12: a novel type of sulfenato thiolato diiron hexacarbonyl complexes. | 2010-07-05 |
|
| Effect of the substrate and catalyst chirality on the diastereoselective epoxidation of limonene using Jacobsen-type catalysts. | 2010-05-05 |
|
| Regioselective control in the oxidative cleavage of 4,6-O-benzylidene acetals of glycopyranosides by dimethyldioxirane. | 2010-03-05 |
|
| A submarine journey: the pyrrole-imidazole alkaloids. | 2009-11-27 |
|
| Structural perturbations induced by the alpha-anomer of the aflatoxin B(1) formamidopyrimidine adduct in duplex and single-strand DNA. | 2009-11-11 |
|
| Preparation, X-ray structure, and oxidative reactivity of N-(2-iodylphenyl)tosylamides and 2-iodylphenyl tosylate: iodylarenes stabilized by ortho-substitution with a sulfonyl group. | 2009-11-06 |
|
| Spirodiepoxides: synthesis of epoxomicinoids. | 2009-10-16 |
|
| Silyl-substituted spirodiepoxides: stereoselective formation and regioselective opening. | 2009-10-15 |
|
| Sulfur-tagged metal-organic frameworks and their post-synthetic oxidation. | 2009-07-28 |
|
| Palladium-catalysed enantioselective alpha-hydroxylation of beta-ketoesters. | 2009-07-14 |
|
| DMD mediated formal synthesis of (+/-)-coerulescine. | 2009-06 |
|
| Iminohydantoin lesion induced in DNA by peracids and other epoxidizing oxidants. | 2009-05-06 |
|
| A facile synthesis of C-24 and C-25 oxysterols by in situ generated ethyl(trifluoromethyl)dioxirane. | 2009-01 |
|
| Preparation and X-ray crystal structure of 2-iodyl-N,N-dialkylaniline oxides: first entry into the heterocyclic system of benziodoxazole. | 2008-12-14 |
|
| Oxidation of diiron and triiron sulfurdithiolato complexes: mimics for the active site of [FeFe]-hydrogenase. | 2008-10 |
|
| Theoretical investigations of substituent effects in dimethyldioxirane epoxidation reactions. | 2008-07-18 |
|
| Synthesis of (+)-cortistatin A. | 2008-06-11 |
|
| Kinetic studies on the oxidation of aryl methyl sulfides and sulfoxides by dimethyldioxirane; absolute rate constants and activation parameters for 4-nitrophenyl methyl sulfide and sulfoxide. | 2008-02-21 |
|
| An investigation by means of correlation analysis into the mechanisms of oxidation of aryl methyl sulfides and sulfoxides by dimethyldioxirane in various solvents. | 2008-02-21 |
|
| Reactive intermediates from DMDO oxidation of ynamides. Trapping of a de novo chiral push-pull carbene via cyclopropanation. | 2008-02-21 |
|
| Concerning the reactivity of dioxiranes. Observations from experiments and theory. | 2008-01-30 |
|
| Chemical and enzymatic oxidation of furosemide: formation of pyridinium salts. | 2007-12 |
|
| Peroxidation enhances the biogas production in the anaerobic digestion of biosolids. | 2007-07-31 |
|
| Oxidation of some cage hydrocarbons by dioxiranes. Nature of the transition structure for the reaction of C-H bonds with dimethyldioxirane: a comparison of B3PW91 density functional theory with experiment. | 2007-07-21 |
|
| On the effect of 1,4-diazabicyclo[2.2.2]octane on the singlet-oxygen dimol emission: chemical generation of 1O2)2 in peroxide reactions. | 2007-05-24 |
|
| Bicyclic beta-Hydroxytetrahydrofurans as precursors of medium ring keto-lactones. | 2007-04-13 |
|
| Synthesis of a stereochemically defined 1,2-diazetine N,N'-dioxide and a study of its thermal decomposition. | 2007-02-16 |
|
| Oxyfunctionalization products of terpenoids with dimethyldioxirane and their biological activity. | 2007-02 |
|
| An alternative synthetic method for 4'-C-ethynylstavudine by means of nucleophilic substitution of 4'-benzoyloxythymine nucleoside. | 2007 |
|
| Rearrangement of a (dithiolato)platinum(II) complex formed by reaction of cyclic disulfide 7,8-dithiabicyclo[4.2.1]nona-2,4-diene with a platinum(0) complex: oxidation of the rearranged (dithiolato)platinum(II) complex. | 2007 |
|
| Direct epoxidation of D-glucal and D-galactal derivatives with in situ generated DMDO. | 2006-11-27 |
|
| Mechanisms of killing of spores of Bacillus subtilis by dimethyldioxirane. | 2006-11 |
|
| 2-iodylphenol ethers: preparation, X-ray crystal structure, and reactivity of new hypervalent iodine(V) oxidizing reagents. | 2006-10-27 |
|
| Characterization of the amino acid adducts of the enedial derivative of teucrin A. | 2006-10 |
|
| Stereoselective epoxidation of 4-deoxypentenosides: a polarized-pi model. | 2006-09-28 |
|
| The role of asynchronous bond formation in the diastereoselective epoxidation of cyclic enol ethers: a density functional theory study. | 2006-07-21 |
|
| Reaction of thioketones with propiolic acids. | 2006-07-21 |
|
| A 2-iminohydantoin from the oxidation of guanine. | 2006-04 |
|
| Anti versus syn opening of epoxides derived from 9-(3-deoxy-beta-D-glycero-pent-3-enofuranosyl)adenine with Me3Al: factors controlling the stereoselectivity. | 2006-02-03 |
|
| Transition state effects in the acid-catalyzed hydrolysis of 5-methoxyacenaphthylene 1,2-oxide: implications for the mechanism of acid-catalyzed hydrolysis of cyclopenta[cd]pyrene 3,4-oxide. | 2006-02 |
|
| Synthesis and properties of a dithiirane trans-1,2-dioxide, a three-membered vic-disulfoxide. | 2006-01-05 |
|
| Two generalizable routes to terminal carbido complexes. | 2005-12-07 |
|
| Functionalized nanodiamonds part I. An experimental assessment of diamantane and computational predictions for higher diamondoids. | 2005-11-18 |
|
| Determination of in situ-generated dimethyldioxirane from an aqueous matrix using selected ion monitoring. | 2005-09-30 |
|
| Use of in situ-generated dimethyldioxirane for inactivation of biological agents. | 2005-08-15 |
|
| A new approach to the synthesis of 4'-carbon-substituted nucleosides: development of a highly active anti-HIV agent 2', 3'-didehydro-3'-deoxy-4'-ethynylthymidine. | 2005 |
|
| Evidence for the preventive effect of the polyunsaturated phytol side chain in tocotrienols on 17beta-estradiol epoxidation. | 2005 |
|
| Kinetics of the epoxidation of geraniol and model systems by dimethyldioxirane. | 2004-02-28 |
|
| Stereoselective synthesis of 4'-carbon-substituted xylofuranosyladenines. | 2004 |
| Substance Class |
Chemical
Created
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admin
on
Edited
Mon Mar 31 19:56:42 GMT 2025
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Mon Mar 31 19:56:42 GMT 2025
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| Record UNII |
R5RAT196DJ
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| Record Status |
Validated (UNII)
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| Record Version |
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DTXSID90224990
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DIMETHYLDIOXIRANE
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115197
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m4535
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R5RAT196DJ
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