U.S. Department of Health & Human Services Divider Arrow National Institutes of Health Divider Arrow NCATS

Details

Stereochemistry ABSOLUTE
Molecular Formula C44H32P2
Molecular Weight 622.6724
Optical Activity NONE
Additional Stereochemistry Yes
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0
Stereo Comments AXIAL, S

SHOW SMILES / InChI
Structure of BINAP, (-)-

SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C56)P(C7=CC=CC=C7)C8=CC=CC=C8

InChI

InChIKey=MUALRAIOVNYAIW-UHFFFAOYSA-N
InChI=1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H

HIDE SMILES / InChI

Molecular Formula C44H32P2
Molecular Weight 622.6724
Charge 0
Count
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Approval Year

PubMed

PubMed

TitleDatePubMed
Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles.
2002 Aug 14
Construction of monomeric and polymeric porphyrin compartments by a Pd(II)-pyridine interaction and their chiral twisting by a BINAP ligand.
2003 Feb 7
How to turn the catalytic asymmetric hydroboration reaction of vinylarenes into a recyclable process.
2003 Jan 3
Preparation of an amphiphilic resin-supported BINAP ligand and its use for rhodium-catalyzed asymmetric 1,4-addition of phenylboronic acid in water.
2004 Sep 16
Synthesis and characterization of FePd magnetic nanoparticles modified with chiral BINAP ligand as a recoverable catalyst vehicle for the asymmetric coupling reaction.
2009 Oct 21
Origin of intense chiroptical effects in undecagold subnanometer particles.
2010 Feb 3
Synthesis, characterization, and catalytic properties of new electrophilic iridium(III) complexes containing the (R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl ligand.
2010 May 3
The preparation of bi-functional organophosphine oxides as potential antitumor agents.
2010 Nov
Patents
Substance Class Chemical
Created
by admin
on Sat Dec 16 08:57:11 GMT 2023
Edited
by admin
on Sat Dec 16 08:57:11 GMT 2023
Record UNII
OX12238KWH
Record Status Validated (UNII)
Record Version
  • Download
Name Type Language
BINAP, (-)-
Common Name English
(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL
Common Name English
(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENE
Common Name English
(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL
Common Name English
(-)-BINAP
Common Name English
(S)-BINAP
Common Name English
(S)-(-)-BINAP
Common Name English
PHOSPHINE, 1,1'-((1S)-(1,1'-BINAPHTHALENE)-2,2'-DIYL)BIS(1,1-DIPHENYL-
Common Name English
(1S)-(1,1'-BINAPHTHALENE)-2,2'-DIYLBIS(DIPHENYLPHOSPHINE)
Common Name English
BINAP (S)-(-)-FORM [MI]
Common Name English
Code System Code Type Description
FDA UNII
OX12238KWH
Created by admin on Sat Dec 16 08:57:11 GMT 2023 , Edited by admin on Sat Dec 16 08:57:11 GMT 2023
PRIMARY
CAS
76189-56-5
Created by admin on Sat Dec 16 08:57:11 GMT 2023 , Edited by admin on Sat Dec 16 08:57:11 GMT 2023
PRIMARY
MERCK INDEX
m2497
Created by admin on Sat Dec 16 08:57:11 GMT 2023 , Edited by admin on Sat Dec 16 08:57:11 GMT 2023
PRIMARY Merck Index