Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C6H14N.Li |
| Molecular Weight | 107.123 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
[Li+].CC(C)[N-]C(C)C
InChI
InChIKey=ZCSHNCUQKCANBX-UHFFFAOYSA-N
InChI=1S/C6H14N.Li/c1-5(2)7-6(3)4;/h5-6H,1-4H3;/q-1;+1
| Molecular Formula | Li |
| Molecular Weight | 6.941 |
| Charge | 1 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
| Molecular Formula | C6H15N |
| Molecular Weight | 101.19 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
DescriptionCurator's Comment: description was created based on several sources, including:
http://www.fmclithium.com/Portals/FMCLithium/content/docs/DataSheet/QS-PDS-047%20r1.pdf
Curator's Comment: description was created based on several sources, including:
http://www.fmclithium.com/Portals/FMCLithium/content/docs/DataSheet/QS-PDS-047%20r1.pdf
Lithium diisopropylamide (LDA) is a prominent reagent used in organic synthesis. It is strong, low-nucleophilic base for e.g. enolisations. Corrosive to the eyes (may cause blindness), skin, mucous membranes and upper respiratory tract. Inhalation of vapors may cause dizziness, nausea, anesthesia, numbness, motor weakness in fingers and toes, incoordination, and headache.
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Lithium diisopropylamide: solution kinetics and implications for organic synthesis. | 2007 |
|
| Lithium Enolates Derived from Pyroglutaminol: Mechanism and Stereoselectivity of an Azaaldol Addition. | 2016 Aug 17 |
|
| Sodium Diisopropylamide in N,N-Dimethylethylamine: Reactivity, Selectivity, and Synthetic Utility. | 2016 Nov 18 |
|
| One-Pot Halogen Dance/Negishi Coupling of Dibromothiophenes for Regiocontrolled Synthesis of Multiply Arylated Thiophenes. | 2016 Nov 7 |
|
| Lithium Diisopropylamide: Nonequilibrium Kinetics and Lessons Learned about Rate Limitation. | 2017 May 5 |
Patents
| Substance Class |
Chemical
Created
by
admin
on
Edited
Sat Dec 16 03:46:30 GMT 2023
by
admin
on
Sat Dec 16 03:46:30 GMT 2023
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| Record UNII |
OL028KIW1I
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| Record Status |
Validated (UNII)
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| Record Version |
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OL028KIW1I
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LITHIUM DIISOPROPYLAMIDE
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DTXSID6063305
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2724682
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m4485
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4111-54-0
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223-893-0
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