Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C39H32OP2 |
| Molecular Weight | 578.6183 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
CC1(C)C2=CC=CC(P(C3=CC=CC=C3)C4=CC=CC=C4)=C2OC5=C1C=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7
InChI
InChIKey=CXNIUSPIQKWYAI-UHFFFAOYSA-N
InChI=1S/C39H32OP2/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
| Molecular Formula | C39H32OP2 |
| Molecular Weight | 578.6183 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Unraveling the origin of regioselectivity in rhodium diphosphine catalyzed hydroformylation. A DFT QM/MM study. | 2001 Aug 8 |
|
| An X-ray study of the effect of the bite angle of chelating ligands on the geometry of palladium(allyl) complexes: implications for the regioselectivity in the allylic alkylation. | 2001 Jul 2 |
|
| Wide bite angle diphosphines: xantphos ligands in transition metal complexes and catalysis. | 2001 Nov |
|
| Unsymmetrical diaryl sulfones through palladium-catalyzed coupling of aryl iodides and arenesulfinates. | 2002 Dec 26 |
|
| Pd-catalyzed intermolecular amidation of aryl halides: the discovery that xantphos can be trans-chelating in a palladium complex. | 2002 May 29 |
|
| Pd-catalyzed N-arylation of heteroarylamines. | 2002 Oct 3 |
|
| Development for an efficient synthesis method of 2'-deoxyguanosine-C8 adducts with several amino/nitro-arenes. | 2003 |
|
| Amines made easily: a highly selective hydroaminomethylation of olefins. | 2003 Aug 27 |
|
| Palladium-catalyzed amination of aryl nonaflates. | 2003 Dec 12 |
|
| Alcoholysis of acylpalladium(II) complexes relevant to the alternating copolymerization of ethene and carbon monoxide and the alkoxycarbonylation of alkenes: the importance of Cis-coordinating phosphines. | 2003 May 7 |
|
| Polar phase hydroformylation: the dramatic effect of water on mono- and dirhodium catalysts. | 2003 Sep 17 |
|
| Versatile synthesis of meso-aryloxy- and alkoxy-substituted porphyrins via palladium-catalyzed C-O cross-coupling reactions. | 2003 Sep 4 |
|
| Unsymmetrical diaryl sulfones and aryl vinyl sulfones through palladium-catalyzed coupling of aryl and vinyl halides or triflates with sulfinic acid salts. | 2004 Aug 20 |
|
| Palladium-mediated arylation of 3-aminopiperidines and 3-aminopyrrolidines. | 2004 Dec 10 |
|
| General synthesis of meso-amidoporphyrins via palladium-catalyzed amidation. | 2004 May 27 |
|
| Synthesis of N,N-Dialkyl-N'-arylhydrazines via palladium-catalyzed N-arylation by using N,N-dialkylhydrazines/2LiCl adducts. | 2005 Apr 14 |
|
| Chemical synthesis of 2'-deoxyguanosine-C8 adducts with heterocyclic amines: an application to synthesis of oligonucleotides site-specifically adducted with 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine. | 2006 Jun |
|
| Pd-Xantphos-catalyzed direct arylation of nucleosides. | 2006 Sep 28 |
|
| Palladium-catalyzed highly stereoselective synthesis of N-aryl-3-arylmethylisoxazolidines via tandem arylation of O-homoallylhydroxylamines. | 2007 Apr 13 |
|
| Synthesis and antioxidant activity evaluation of new 7-aryl or 7-heteroarylamino-2,3-dimethylbenzo[b]thiophenes obtained by Buchwald-Hartwig C-N cross-coupling. | 2007 Feb 15 |
|
| Chemoselective amination of 5-bromo-2-chloro-3-fluoropyridine. | 2007 May 10 |
|
| Conformational analysis of a helically distorted gold(I) macrocycle derived from xantphos: evidence for the aurophilic Au--Au interaction from NMR. | 2007 Nov |
|
| Synthesis of new N-arylpyrimidin-2-amine derivatives using a palladium catalyst. | 2008 Apr 9 |
|
| Xantphos as an efficient ligand for palladium-catalyzed cross-coupling reactions of aryl bromides and triflates with allyl acetates and indium. | 2008 Feb 1 |
|
| 4,6-Bis(diphenyl-phosphino)phenoxazine (nixantphos). | 2008 Mar 14 |
|
| Synthesis of Weinreb amides via Pd-catalyzed aminocarbonylation of heterocyclic-derived triflates. | 2008 Mar 7 |
|
| Pd-catalyzed carboetherification of beta,gamma-unsaturated oximes: a novel approach to Delta2-isoxazolines. | 2008 May 1 |
|
| New ferrocenic pyrrolo[1,2-a]quinoxaline derivatives: synthesis, and in vitro antimalarial activity. | 2008 Oct 15 |
|
| Palladium-catalyzed carbonylation reactions of aryl bromides at atmospheric pressure: a general system based on Xantphos. | 2008 Sep 19 |
|
| Bite angle effects of diphosphines in C-C and C-X bond forming cross coupling reactions. | 2009 Apr |
|
| Palladium-catalyzed cross-coupling reaction of secondary benzylic bromides with grignard reagents. | 2009 Dec 3 |
|
| Ruthenium xantphos complexes in hydrogen transfer processes: reactivity and mechanistic studies. | 2009 Jan 28 |
|
| PIKfyve regulation of endosome-linked pathways. | 2009 Jul |
|
| Dual palladium- and proline-catalyzed allylic alkylation of enolizable ketones and aldehydes with allylic alcohols. | 2009 Mar 19 |
|
| Nickel-catalyzed vinylation of aryl chlorides and bromides with vinyl ZnBr.MgBrCl. | 2009 May 1 |
|
| Platinum-catalyzed direct amination of allylic alcohols under mild conditions: ligand and microwave effects, substrate scope, and mechanistic study. | 2009 Oct 14 |
|
| Pincer phosphine complexes of ruthenium: formation of Ru(P-O-P)(PPh3)HCl (P-O-P = xantphos, DPEphos, (Ph2PCH2CH2)2O) and Ru(dppf)(PPh3)HCl and characterization of cationic dioxygen, dihydrogen, dinitrogen, and arene coordinated phosphine products. | 2010 Aug 16 |
|
| Ligand-mediated highly effective and selective C-N coupling for synthesizing bioactive N-aryltriazole acyclonucleosides. | 2010 Dec 17 |
|
| Iridium- and ruthenium-catalysed synthesis of 2,3-disubstituted indoles from anilines and vicinal diols. | 2010 Dec 21 |
|
| Competitive and selective Csp3-Br versus Csp2-Br bond activation in palladium-catalysed Suzuki cross-coupling: an experimental and theoretical study of the role of phosphine ligands. | 2010 Dec 3 |
|
| Gold(I) halide complexes of bis(diphenylphosphine)diphenyl ether ligands: a balance of ligand strain and non-covalent interactions. | 2010 Jun 14 |
|
| A highly efficient palladium/copper cocatalytic system for direct arylation of heteroarenes: an unexpected effect of Cu(Xantphos)I. | 2010 Mar 24 |
|
| [mu-4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene]bis[(trifluoroacetato)gold(I)] and its dichloromethane 0.58-solvate. | 2010 May |
|
| Dienyl homoallyl alcohols via palladium catalyzed ene-type reaction of aldehydes with 1,3-dienes. | 2010 Nov 24 |
|
| Oxygen gas sensing by luminescence quenching in crystals of Cu(xantphos)(phen)+ complexes. | 2010 Oct 13 |
Patents
| Substance Class |
Chemical
Created
by
admin
on
Edited
Sat Dec 16 08:13:20 GMT 2023
by
admin
on
Sat Dec 16 08:13:20 GMT 2023
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| Record UNII |
NMU72MOG9B
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| Record Status |
Validated (UNII)
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| Record Version |
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161265-03-8
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636044
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Xantphos
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m11538
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NMU72MOG9B
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DTXSID20348350
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