1,2-BIS(DIPHENYLPHOSPHINO)ETHANE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C26H24P2
Molecular Weight	398.4163
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure of 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE

Structure Search

SMILES

C(CP(C1=CC=CC=C1)C2=CC=CC=C2)P(C3=CC=CC=C3)C4=CC=CC=C4

InChI

InChIKey=QFMZQPDHXULLKC-UHFFFAOYSA-N

InChI=1S/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2

HIDE SMILES / InChI

Molecular Formula	C26H24P2
Molecular Weight	398.4163
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
Cerebroside Langmuir monolayers originated from the echinoderms I. Binary systems of cerebrosides and phospholipids.	2005-05-10	15833668
Effects of lipid chain unsaturation and headgroup type on molecular interactions between paclitaxel and phospholipid within model biomembrane.	2005-05-01	15797430
Iridium complex-catalyzed reaction of 1,6-enynes: cycloaddition and cycloisomerization.	2005-04-28	15844887
Reactions of the dianion [1,1,1-(CO)3-2-Ph-closo-1,2-MnCB9H9]2- with transition-metal cations: facile insertion and then extrusion of cluster vertexes.	2005-04-18	15819570
Atomic force microscopy studies of ganglioside GM1alpha in dioleoylphosphatidylcholine/dipalmitoylphosphatidylcholine mixed monolayers and hybrid bilayers.	2005-03-25	15737535
Hypervalent, low-coordinate phosphorus(III) centers in complexes of the phosphadiazonium cation with chelate ligands.	2005-03-23	15771528
From parquets to bricks: a series of lanthanide coordination polymers with bis(diphenylphosphino)ethane dioxide.	2005-03-21	15762735
Versatility of heterocyclic thioamides in the construction of a trinuclear cluster [Cu3I3(dppe)3 (SC5H4NH)] and Cu(I) linear polymers {Cu6(SC5H4NH)6I6}n x 2nCH3CN and {Cu(I)6 (SC3H6N2)6X6}n (X = Br, I).	2005-03-21	15762717
Formation and characterization of phospholipid monolayers spontaneously assembled at interfaces between aqueous phases and thermotropic liquid crystals.	2005-03-15	15752009
Interaction of the macrolide antibiotic azithromycin with lipid bilayers: effect on membrane organization, fluidity, and permeability.	2005-03	15835753
The pressure tunning Raman and IR spectral studies on the multinuclear metal carbyne complexes.	2005-03	15683808
Generation and interrogation of a pure nuclear spin state by parahydrogen-enhanced NMR spectroscopy: a defined initial state for quantum computation.	2005-03	15625721
Mechanism of cytotoxicity of copper(I) complexes of 1,2-bis(diphenylphosphino)ethane.	2005-02-24	15715467
Thermotropic and barotropic phase transitions of N-methylated dipalmitoylphosphatidylethanolamine bilayers.	2005-02-01	15670728
Lateral heterogeneity of dipalmitoylphosphatidylethanolamine-cholesterol Langmuir-Blodgett films investigated with imaging time-of-flight secondary ion mass spectrometry and atomic force microscopy.	2005-02-01	15667151
Small angle X-ray scattering (SAXS) and differential scanning calorimetry (DSC) studies of amide phospholipids.	2005-01	15589228
Reaction of [M(eta3-allyl)(eta2-amidinato)(CO)2(pyridine)] complexes (M = Mo, W) with bidentate ligands: nitrogen donor vs. phosphorus donor.	2004-12-07	15558123
Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic Grignard reagents and their application to tandem radical cyclization/cross-coupling reactions.	2004-11-05	15457521
Synthesis and properties of palladium diselenolenes: X-ray crystal structures of [Pd[SeC(R(1))=C(R(2))Se](PBu(3))(2)] [R(1), R(2) = (CH(2))(n), n = 4, 5, 6].	2004-11-01	15500348
Double phosphinylation of propargylic alcohols: a novel synthetic route to 1,2-bis(diphenylphosphino)ethane derivatives.	2004-10-28	15496082
Acidities of platinum(II) mu-hydroxo complexes bearing diphosphine ligands.	2004-10-18	15476378
Chiral molecular squares based on angular bipyridines: self-assembly, characterization, and photophysical properties.	2004-10-18	15476354
Preparation and resolution of a modular class of axially chiral quinazoline-containing ligands and their application in asymmetric rhodium-catalyzed olefin hydroboration.	2004-10-01	15387579
Stabilized arsenic(i) iodide: a ready source of arsenic iodide fragments and a useful reagent for the generation of clusters.	2004-09-20	15360247
The infrared spectra and theoretical calculations of frequencies of fac-tricarbonyl octahedral complexes of manganese(I).	2004-09	15294246
Adsorption of amyloid beta (1-40) peptide to phosphatidylethanolamine monolayers.	2004-08-20	15446741
A series of redox active, tetrathiafulvalene-based amidopyridines and bipyridines ligands: syntheses, crystal structures, a radical cation salt and group 10 transition-metal complexes.	2004-08-06	15281153
Is the allylpalladium structure altered between solid and solutions?	2004-07-28	15264841
Biodistribution of pH-responsive liposomes for MRI and a novel approach to improve the pH-responsiveness.	2004-07-23	15245892
Silver coordination chemistry of a new versatile "Janus"-type N(2),O(2)-bichelating donor, formation of an unprecedented supramolecular network of binuclear silver building blocks containing a five-coordinate beta-diketonate, and isolation of unexpected silver-tin-silver heterotrimetallic complexes from silver metathesis reactions.	2004-07-12	15236552
Cholera toxin assault on lipid monolayers containing ganglioside GM1.	2004-06	15189866
Synthesis and structural characterization of silanethiolato complexes having tert-butyldimethylsilyl and trimethylsilyl groups.	2004-05-21	15252612
Preparation, structures and some reactions of novel diynyl complexes of iron and ruthenium.	2004-05-21	15252610
Preparation and solid-state characterization of mixed-ligand coordination/organometallic oligomers and polymers of copper(I) and silver(I) using diphosphine and mono- and diisocyanide ligands.	2004-05-17	15132618
Proton transfer to nickel-thiolate complexes. 1. Protonation of [Ni(SC(6)H(4)R-4)(2)(Ph(2)PCH(2)CH(2)PPh(2))] (R = Me, MeO, H, Cl, or NO(2)).	2004-05-17	15132615
NiCl(2)(dppe)-catalyzed cross-coupling of aryl mesylates, arenesulfonates, and halides with arylboronic acids.	2004-05-14	15132555
A study on the interaction between 1-decyloxymethyl-3-carbamoylpyridinium salts and model membranes--the effect of counterions.	2004-05-01	15110945
Micro-ethane-1,2-diylbis(diphenylphosphine oxide)-kappa(2)O:O'-bis[dibenzyldichlorotin(IV)]: a centrosymmetric complex containing trigonal-bipyramidal tin(IV), linked into chains of rings by C-H.pi(arene) hydrogen bonds.	2004-04	15071208
Lateral and vertical nanophase separation in Langmuir-Blodgett films of phospholipids and semifluorinated alkanes.	2004-03-16	15835680
Organometallic oligomers based on 1,8-Diisocyano-p-menthane (dmb): syntheses and characterization of the [[M(diphos)(dmb)]BF4]n and [[Pd2(diphos)2(dmb)](ClO4)2]n materials (M = Cu, Ag; diphos = dppe, dppp).	2004-02-23	14966987
Synthesis and characterisation of cyanodithioimidocarbonate [C2N2S2]2- complexes.	2004-02-07	15252541
The kinetics and mechanism of the formation of crystalline phase of dipalmitoylphosphatidylethanolamine dispersed in aqueous dimethyl sulfoxide solutions.	2004-02	14725998
Phase III study of N,N-diethyl-2-[4-(phenylmethyl) phenoxy]ethanamine (BMS-217380-01) combined with doxorubicin versus doxorubicin alone in metastatic/recurrent breast cancer: National Cancer Institute of Canada Clinical Trials Group Study MA.19.	2004-01-15	14722035
Construction of a novel copper(I) chain polymer of hexanuclear Cu6(2-SC5H4NH)6I6 cores with a new (mu 3-S) mode of bonding of pyridine-2-thione and of an unusual triangular Cu3I3(dppe)3(2-SC5H4NH) cluster.	2003-12-01	14632486
Efficacy of immunoliposomes on cancer models in a cell-surface-antigen-density-dependent manner.	2003-10-20	14562030
The evolution of [[Ph2P(CH2)nPPh2]Pt(mu-S)2Pt[Ph2P(CH2)nPPh2]] (n=2, 3) metalloligands in protic acids: a cascade of sequential reactions.	2003-10-17	14562320
Iridium complex-catalyzed highly selective cross [2 + 2 + 2] cycloaddition of two different monoynes: 2:1 coupling versus 1:2 coupling.	2003-10-02	14507198
Syntheses and structures of dinuclear gold(I) dithiophosphonate complexes and the reaction of the dithiophosphonate complexes with phosphines: diverse coordination types.	2003-08-25	12924903
Catalytic synthesis of thiobutyrolactones via CO insertion into the C-S bond of thietanes in the presence of a heterodinuclear organoplatinum-cobalt complex.	2003-08-21	12934904
Mechanisms of C-C and C-H alkane reductive eliminations from octahedral Pt(IV): reaction via five-coordinate intermediates or direct elimination?	2003-08-06	12889975

Patents

Substance Class	Chemical Created by `admin` on `Mon Mar 31 22:40:29 GMT 2025` Edited by `admin` on `Mon Mar 31 22:40:29 GMT 2025`
Record UNII	KL33QE52I4
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

1,2-BIS(DIPHENYLPHOSPHINO)ETHANE

Systematic Name

English

NSC-76285

Preferred Name

English

DPPE [MI]

Common Name

English

P,P'-ETHYLENEBIS(DIPHENYLPHOSPHINE)

Systematic Name

English

ETHANEDIYLBIS(DIPHENYLPHOSPHINE)

Systematic Name

English

PHOSPHINE, 1,2-ETHANEDIYLBIS(DIPHENYL-

Systematic Name

English

ETHYLENEBIS(DIPHENYLPHOSPHINE)

Systematic Name

English

Code System Code Type Description

WIKIPEDIA

1,2-Bis(diphenylphosphino)ethane