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Details

Stereochemistry ACHIRAL
Molecular Formula C8H6O3
Molecular Weight 150.1314
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of PIPERONAL

SMILES

O=CC1=CC2=C(OCO2)C=C1

InChI

InChIKey=SATCULPHIDQDRE-UHFFFAOYSA-N
InChI=1S/C8H6O3/c9-4-6-1-2-7-8(3-6)11-5-10-7/h1-4H,5H2

HIDE SMILES / InChI
Molecular Formula C8H6O3
Molecular Weight 150.1314
Charge 0
Count
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Approval Year

2010
465
PubMed

PubMed

TitleDatePubMed
A short synthesis of (+/-)-epiasarinin.
2002 Apr 4
[Succivil efficacy in endogenous intoxication].
2003 Jul-Aug
Bhc-diol as a photolabile protecting group for aldehydes and ketones.
2003 Jun 12
Chemical profiling of 3,4-methylenedioxymethamphetamine (MDMA) tablets seized in Hong Kong.
2003 Nov
Microbiologic oxidation of isosafrole into piperonal.
2003 Spring
First total synthesis of justicidone, a p-quinone-lignan derivative from Justicia hyssopifolia.
2005 Aug
A study of impurities in intermediates and 3,4-methylenedioxymethamphetamine (MDMA) samples produced via reductive amination routes.
2005 Dec 20
Determination of synthesis method of ecstasy based on the basic impurities.
2005 Sep 10
Synthesis, Spectral, and Biological Properties of Copper(II) Complexes of Thiosemicarbazones of Schiff Bases Derived from 4-Aminoantipyrine and Aromatic Aldehydes.
2006
Synthesis of 7-deoxypancratistatin from carbohydrates by the use of olefin metathesis.
2006 Apr 12
The fumigant and repellent activity of aliphatic lactones against Pediculus humanus capitis (Anoplura: Pediculidae).
2006 Feb
Highly efficient cyclization of o-iodobenzoates with aldehydes catalyzed by cobalt bidentate phosphine complexes: a novel entry to chiral phthalides.
2007
Development and validation of an RP-HPLC method for quantitative determination of vanillin and related phenolic compounds in Vanilla planifolia.
2007 Jan
Alpha-phenyl-N-tert-butyl nitrone (PBN) derivatives: synthesis and protective action against microvascular damages induced by ischemia/reperfusion.
2007 May 15
Novel piperidinylpyrimidine derivatives as inhibitors of HIV-1 LTR activation.
2008 Nov 15
3',6'-Bis(ethyl-amino)-2',7'-dimethyl-2-{[2-[(E)-3,4-methyl-enedioxy-benzyl-idene-amino]eth-yl}spiro-[isoindoline-1,9'-xanthen]-3-one.
2009 Jul 15
Titanium imido complexes utilizing orthometallated derivatized acetophenone and piperonal imine ligands: synthesis, isolation, and characterization.
2009 Jul 7
A combined experimental and theoretical study of the polar [3 + 2] cycloaddition of electrophilically activated carbonyl ylides with aldehydes and imines.
2009 Mar 6
4-Methyl-1,3-bis-(3,4-methyl-enedioxy-benz-yl)-2-(3,4-methyl-enedioxy-phen-yl)imidazolidine.
2009 Nov 11
(E)-N'-(1,3-Benzodioxol-5-ylmethyl-ene)nicotinohydrazide monohydrate.
2009 Sep 5
Dynamic planar solid phase microextraction-ion mobility spectrometry for rapid field air sampling and analysis of illicit drugs and explosives.
2010 Apr 1
1-(2-Bromobenzoyl)-6,7-(methylene-dioxy)isoquinoline.
2010 Dec 11
Detection of piperonal emitted from polymer controlled odor mimic permeation systems utilizing Canis familiaris and solid phase microextraction-ion mobility spectrometry.
2010 Feb 25
N-[(E)-1,3-Benzodioxol-5-yl-methyl-idene]-4-methyl-aniline.
2010 Nov 24
14-(1,3-Benzodioxol-5-yl)-7,14-dihydro-dibenzo[a,j]acridine.
2010 Nov 6
(2E)-3-(1,3-Benzodioxol-5-yl)-1-(3-bromo-2-thien-yl)prop-2-en-1-one.
2010 Sep 4
Patents

Patents

04014885
1
04024274
1
04073798
8
04125541
3
04125714
3
04182729
3
04227015
1
04344954
3
05182404
5
05233057
5
05517350
1
05574056
1
05594006
2
05661168
3
05716984
3
05719183
1
05731321
1
06133456
1
06162927
2
06218427
1
06252080
1
06306870
4
06310076
4
06310211
1
06329387
1
06448260
2
06498172
5
JP2001288179A
1
JP2004124078A
1
JP2004203839A
3
JP2004250334A
2
JP2004269376A
1
JP2006095182A
1
JP2006325902A
2
JP2006340785A
1
JP2007502860A
3
JP2011207797A
1
JPH03215835A
1
JPH0383904A
1
JPH0390004A
1
JPH04124123A
1
JPH04178388A
1
JPH04342511A
2
JPH07330755A
2
JPH0827144A
1
JPH09227568A
1
JPH10259121A
1
JPH11228368A
3
JPS5522615A
1
JPS55314A
1
JPS5535003A
1
Substance Class Chemical
Created
by admin
on Fri Dec 15 16:08:54 GMT 2023
Edited
by admin
on Fri Dec 15 16:08:54 GMT 2023
Record UNII
KE109YAK00
Record Status Validated (UNII)
Record Version
  • Download
Name Type Language
PIPERONAL
FCC   FHFI   HSDB   MART.   MI   WHO-DD  
Common Name English
PIPERONAL (CONSTITUENT OF BLACK PEPPER) [DSC]
Common Name English
HELIOTROPINE [INCI]
Common Name English
PIPERONAL [HSDB]
Common Name English
DIOXYMETHYLENEPROTOCATECHUIC ALDEHYDE
Common Name English
3,4-(METHYLENEDIOXY)BENZALDEHYDE
Systematic Name English
2H-BENZO(3,4-D)-1,3-DIOXOLAN-5-YLFORMALDEHYDE
Systematic Name English
NSC-26826
Code English
PIPERONAL [FHFI]
Common Name English
1,3-BENZODIOXOLE-6-CARBOXALDEHYDE
Systematic Name English
PIPERONAL [FCC]
Common Name English
FEMA NO. 2911
Code English
GELIOTROPIN
Common Name English
Piperonal [WHO-DD]
Common Name English
HELIOTROPINE
INCI  
INCI  
Official Name English
PIPERONAL [MI]
Common Name English
PIPERONAL [MART.]
Common Name English
PIPERONYLALDEHYDE
Systematic Name English
Classification Tree Code System Code
JECFA EVALUATION PIPERONAL
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
DEA NO. 8750
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
Code System Code Type Description
EVMPD
SUB37596
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
WIKIPEDIA
PIPERONAL
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
HSDB
581
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
EPA CompTox
DTXSID7025924
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
RXCUI
33753
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY RxNorm
SMS_ID
100000129172
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
CHEBI
8240
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
NSC
26826
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
FDA UNII
KE109YAK00
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
JECFA MONOGRAPH
808
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
DAILYMED
KE109YAK00
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
MESH
C005454
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
PUBCHEM
8438
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
MERCK INDEX
m8858
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY Merck Index
CAS
120-57-0
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
ECHA (EC/EINECS)
204-409-7
Created by admin on Fri Dec 15 16:08:55 GMT 2023 , Edited by admin on Fri Dec 15 16:08:55 GMT 2023
PRIMARY
Related Record Type Details
BLACK PEPPER
PARENT -> CONSTITUENT ALWAYS PRESENT
USP-DSC
Structure of MDE
MDE
PARENT->PRECURSOR
Structure of TENAMFETAMINE
PARENT->PRECURSOR
Related Record Type Details
Structure of METHAMPHETAMINE
PARENT -> IMPURITY
NIH
NCATS
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ACCESSIBILITY
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