Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | CHF3O3S |
| Molecular Weight | 150.077 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
OS(=O)(=O)C(F)(F)F
InChI
InChIKey=ITMCEJHCFYSIIV-UHFFFAOYSA-N
InChI=1S/CHF3O3S/c2-1(3,4)8(5,6)7/h(H,5,6,7)
| Molecular Formula | CHF3O3S |
| Molecular Weight | 150.077 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Conformational behavior and coordination chemistry of 2,11-dithia[3.3]orthocyclophane with platinum group metals. | 2002-07-15 |
|
| An efficient route for the preparation of a 21-fluoro progestin-16 alpha,17 alpha-dioxolane, a high-affinity ligand for PET imaging of the progesterone receptor. | 2002-07-12 |
|
| Stereocontrolled synthesis of linear 22R-homoallylic sterols via a triflic acid-catalyzed 2-oxonia Cope rearrangement. | 2002-07-11 |
|
| Palladium-catalyzed cross-coupling reaction of bis(pinacolato)diboron with 1-alkenyl halides or triflates: convenient synthesis of unsymmetrical 1,3-dienes via the borylation-coupling sequence. | 2002-07-10 |
|
| Hydrogenation of carbon dioxide catalyzed by ruthenium trimethylphosphine complexes: the accelerating effect of certain alcohols and amines. | 2002-07-10 |
|
| Electron-induced switching of the supramolecular chirality of optically active polythiophene aggregates. | 2002-07-10 |
|
| Silicon-based metalloprotease inhibitors: synthesis and evaluation of silanol and silanediol peptide analogues as inhibitors of angiotensin-converting enzyme. | 2002-06-26 |
|
| Investigation of silver salt metathesis: preparation of cationic germanium(II) and Tin(II) complexes, and silver adducts containing unsupported silver-germanium and silver-tin bonds. | 2002-06-17 |
|
| Substitution reactions of [Ru(dppe)(CO)(H(2)O)(3)][OTf](2). | 2002-06-17 |
|
| Influence of filled d pi-manifold and L/L' ligands on the structure, basicity, and bond rotations of the octahedral and d(6) amido complexes TpRu(L)(L')(NHPh) (Tp = hydridotris(pyrazolyl)borate; L = L' = PMe(3) or P(OMe)(3), or L = CO and L' = PPh(3)): solid-state structures of [TpRu(PMe(3))(2)(NH(2)Ph)][OTf], [TpRu[P(OMe)(3)](2)(NH(2)Ph)][OTf], and TpRu[P(OMe)(3)](2)(NHPh). | 2002-06-03 |
|
| TMS triflate-catalyzed cleavage of prenyl (3-methylbut-2-enyl) ester. | 2002-05-30 |
|
| Solution and solid state studies of a triangle-square equilibrium: anion-induced selective crystallization in supramolecular self-assembly. | 2002-05-06 |
|
| Structural and electronic characteristics of thienyl(aryl)iodonium triflates. | 2002-05-03 |
|
| Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. | 2002-05-02 |
|
| Coupling of isoprenoid triflates with organoboron nucleophiles: synthesis and biological evaluation of geranylgeranyl diphosphate analogues. | 2002-05 |
|
| Cationic complexes of iridium: diiodobenzene chelation, electrophilic behavior with olefins, and fluxionality of an Ir(I) ethylene complex. | 2002-04-22 |
|
| The role of ring D in the antitumour antibiotic streptonigrin: metal complexation, DNA binding and topoisomerase inhibition by ABC ring analogues of streptonigrin. | 2002-04-19 |
|
| Regioselective synthesis of 3-alkylindoles mediated by zinc triflate. | 2002-04-19 |
|
| Asymmetric Diels-Alder reactions catalyzed by a triflic acid activated chiral oxazaborolidine. | 2002-04-17 |
|
| Solid-phase synthesis of oligosaccharides and on-resin quantitative monitoring using gated decoupling (13)C NMR. | 2002-04-10 |
|
| Self-assembly of transition-metal-based macrocycles linked by photoisomerizable ligands: examples of photoinduced conversion of tetranuclear-dinuclear squares. | 2002-04-08 |
|
| Synthesis of 2-alkylidenecyclopentanones via palladium-catalyzed carbopalladation/ring expansion of 1-(1-alkynyl)cyclobutanols. | 2002-04-05 |
|
| p-Methoxybenzyl ether cleavage by polymer-supported sulfonamides. | 2002-04-04 |
|
| Ligand-modulated stereo- and regioselective tandem addition reactions of rhenium-bound naphthalene. | 2002-04-03 |
|
| A substrate-unspecified glycosylation reaction promoted by copper(II) trifluoromethanesulfonate in benzotrifluoride. | 2002-04-02 |
|
| Aryl-aryl coupling reaction using a novel and highly active palladium reagent prepared from Pd(OAc)2, 1,3-bis[diphenylphosphino]propane (DPPP), and Bu3P. | 2002-04 |
|
| A cyclic tetramer of [Ag(1,4,7-trithiacyclononane)]+, cyclo-tetrakis(mu-1,4,7-trithiacyclononane-kappa3S1,S4,S7:kappaS1)tetrasilver(I) tetrakis(trifluoromethanesulfonate) nitromethane disolvate. | 2002-04 |
|
| Studies toward the synthesis of (-)-zampanolide: preparation of N-acyl hemiaminal model systems. | 2002-03-21 |
|
| Preparation of alpha-sulfenyl enones by thermal fragmentation of beta-sulfenyl enol triflates. | 2002-03-21 |
|
| Metal trifluoromethanesulfonate-catalyzed regioselective borane-reductive ring opening of benzylidene acetals: a concise synthesis of 1,4-dideoxy-1,4-imino-L-xylitol. | 2002-03-07 |
|
| Interaction of biotin with Mg-O bonds: bifunctional binding and recognition of biotin and related ligands by the Mg(15-crown-5)2+ unit. | 2002-03-06 |
|
| Electrochemical cell for separation of [18F]fluoride from irradiated 18O-water and subsequent no carrier added nucleophilic fluorination. | 2002-03 |
|
| Rare earth metal trifluoromethanesulfonates catalyzed benzyl-etherification. | 2002-03 |
|
| Facile synthesis of 9-substituted 9-deazapurines as potential purine nucleoside phosphorylase inhibitors. | 2002-03 |
|
| Effects of host-guest recognition on kinetics of Diels-alder reaction of quinocrown ethers with cyclopentadiene. | 2002-02-22 |
|
| Synthesis of the RuIV amido complex [TpRu(CO)(PPh3)(NHPh)][OTf]2 (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and deprotonation to form an octahedral and d4 imido complex: computational study of RuIV-imido bonding. | 2002-02-21 |
|
| Synthesis of the core structure of apicularen a by transannular cyclization. | 2002-02-21 |
|
| Electronic and medium effects on the rate of arene C [bond] H activation by cationic Ir(III) complexes. | 2002-02-20 |
|
| A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. | 2002-02-20 |
|
| A simple and efficient chemoselective method for the catalytic deprotection of acetals and ketals using bismuth triflate. | 2002-02-08 |
|
| The first intermolecular Friedel-Crafts acylation with beta-lactams. | 2002-02-07 |
|
| (Z)-2-Methylbuten-1-yl(aryl)iodonium trifluoromethanesulfonates containing electron-withdrawing groups on the aryl moiety. | 2002-02 |
|
| Intercalation of alcohols in Ag sulfonates: topotactic behavior despite flexible layers. | 2002-01-28 |
|
| Asymmetric methoxyselenenylations and cyclizations with 3-camphorseleno electrophiles containing oxime substituents at C-2. Formation of an unusual oxaselenazole from an oxime-substituted selenenyl bromide. | 2002-01-25 |
|
| Coordination chemistry umpolung: a gallane ligand on a phosphine lewis acceptor. | 2002-01-23 |
|
| Formation quotients of aluminum sulfate complexes in NaCF3SO3 media at 10, 25, and 50 degrees C from potentiometric titrations using a mercury/mercurous sulfate electrode concentration cell. | 2002-01-15 |
|
| Direct thioesterification from carboxylic acids and thiols catalyzed by a Brønsted acid. | 2002-01-07 |
|
| Radiosynthesis, in vitro validation, and in vivo evaluation of 18F-labeled COX-1 and COX-2 inhibitors. | 2002-01 |
|
| Scandium ion-promoted photoinduced electron-transfer oxidation of fullerenes and derivatives by p-chloranil and p-benzoquinone. | 2001-12-19 |
|
| Chemical deglycosylation can induce methylation, succinimide formation, and isomerization. | 2001-10 |
Patents
| Substance Class |
Chemical
Created
by
admin
on
Edited
Mon Mar 31 19:19:54 GMT 2025
by
admin
on
Mon Mar 31 19:19:54 GMT 2025
|
| Record UNII |
JE2SY203E8
|
| Record Status |
Validated (UNII)
|
| Record Version |
|
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Download
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Preferred Name | English | ||
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Systematic Name | English | ||
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Common Name | English | ||
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Systematic Name | English |
| Classification Tree | Code System | Code | ||
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CFR |
21 CFR 173.395
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48511
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m11112
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62406
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JE2SY203E8
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1493-13-6
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TRIFLUOROMETHANESULFONIC ACID
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216-087-5
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C012077
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DTXSID2044397
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