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Details

Stereochemistry ACHIRAL
Molecular Formula C4H6O3
Molecular Weight 102.0886
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of ETHYL OXOACETATE

SMILES

CCOC(=O)C=O

InChI

InChIKey=DBPFRRFGLYGEJI-UHFFFAOYSA-N
InChI=1S/C4H6O3/c1-2-7-4(6)3-5/h3H,2H2,1H3

HIDE SMILES / InChI

Molecular Formula C4H6O3
Molecular Weight 102.0886
Charge 0
Count
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Approval Year

PubMed

PubMed

TitleDatePubMed
4-(Piperidin-1-yl)-4H-benzo[b]tetra-zolo[1,5-d][1,4]diazepin-5(6H)-one.
2010-12-04
Kinetics and products of gas-phase reactions of ozone with methyl methacrylate, methyl acrylate, and ethyl acrylate.
2010-08-19
Polymeric ethyl glyoxylate in an asymmetric aldol reaction catalyzed by diarylprolinol.
2010-07-02
A straightforward three-component synthesis of alpha-amino esters containing a phenylalanine or a phenylglycine scaffold.
2010-04-16
Lewis Acid catalyzed three-component hetero-Diels-alder (povarov) reaction of N-arylimines with strained norbornene-derived dienophiles.
2010-02-05
Catalytic asymmetric three-component Mannich-type reaction of alkenyl trichloroacetates.
2009-11-19
Synthesis of (S)- and (R)-5-oxo-piperazine-2-carboxylic acid and its application to peptidomimetics.
2009-11-06
Highly efficient asymmetric synthesis of 3-indolyl(hydroxy)acetates via Friedel-Crafts alkylation of indoles.
2009-09-04
Asymmetric petasis reactions catalyzed by chiral biphenols.
2008-06-04
Organocatalytic synthesis of beta-alkylaspartates via beta-lactone ring opening.
2007-10-12
Enol esters: versatile substrates for Mannich-type multicomponent reactions.
2007-10-11
Highly enantioselective carbonyl-ene reactions catalyzed by a hindered silyl-salen-cobalt complex.
2007-09-27
The first organocatalytic carbonyl-ene reaction: isomerisation-free C-C bond formations catalysed by H-bonding thio-ureas.
2007-09-14
Enantioselective reductive coupling of 1,3-enynes to glyoxalates mediated by hydrogen: asymmetric synthesis of beta,gamma-unsaturated alpha-hydroxy esters.
2007-09-13
A rapid divergent synthesis of highly substituted delta-lactones.
2006-10-12
Synthesis of novel keto-ACE analogues as domain-selective angiotensin I-converting enzyme inhibitors.
2006-09-01
Alpha-hydroxy esters via enantioselective hydrogen-mediated C-C coupling: regiocontrolled reactions of silyl-substituted 1,3-diynes.
2006-08-17
2-Methyl-(1Z,3E)-butadiene-1,3,4-tricarboxylic acid, "isoprenetricarboxylic acid".
2005-09-02
Domino coupling relay approach to polycyclic pyrrole-2-carboxylates.
2005-08-10
Self-supported heterogeneous titanium catalysts for enantioselective carbonyl-ene and sulfoxidation reactions.
2005-07-04
Diastereoselective reductive imino-aldol reaction of alpha-imino esters promoted by titanium tetraiodide: synthesis of alpha,beta-diamino esters.
2005-06-21
Synthetic studies toward ecteinascidin 743.
2005-05-27
Synthesis of the C11-C29 fragment of amphidinolide F.
2004-10-14
New taxane derivatives: synthesis of baccatin[14,1-d]furan-2-one nucleus and its condensation with the norstatine side chain.
2004-10-01
Solid-phase synthesis of 1-substituted tetrahydroisoquinoline derivatives employing BOC-protected tetrahydroisoquinoline carboxylic acids.
2004-07-13
Highly diastereo- and enantioselective reactions of enecarbamates with ethyl glyoxylate to give optically active syn and anti alpha-alkyl-beta-hydroxy imines and ketones.
2004-06-21
The Direct catalytic asymmetric cross-Mannich reaction: a highly enantioselective route to 3-amino alcohols and alpha-amino acid derivatives.
2004-04-19
Highly enantioselective Friedel-Crafts reaction of aromatic amines with ethyl glyoxylate catalyzed by chiral titanium(IV) complexes: practical synthesis of aminomandelic acid derivatives.
2004-01-09
Polymer-supported bisBINOL ligands for the immobilization of multicomponent asymmetric catalysts.
2003-07-24
A convenient and scalable synthesis of ethyl N-[(2-Boc-amino)ethyl]glycinate and its hydrochloride. Key intermediates for peptide nucleic acid synthesis.
2003-02-21
C(2)-symmetric Sc(III)-complexes as chiral Lewis acids. Catalytic enantioselective aldol additions to glyoxylate esters.
2002-10-03
On the intermediates in chiral bis(oxazoline)copper(II)-catalyzed enantioselective reactions--experimental and theoretical investigations.
2002-04-15
Cycloaddition reaction of 2-azadienes derived from beta-amino acids with electron-rich and electron-deficient alkenes and carbonyl compounds. Synthesis of pyridine and 1,3-oxazine derivatives.
2002-04-05
Patents
Substance Class Chemical
Created
by admin
on Mon Mar 31 19:54:23 GMT 2025
Edited
by admin
on Mon Mar 31 19:54:23 GMT 2025
Record UNII
IXX9MQ1J1I
Record Status Validated (UNII)
Record Version
  • Download
Name Type Language
ETHYL OXOACETATE
Systematic Name English
NSC-49206
Preferred Name English
ACETIC ACID, OXO-, ETHYL ESTER
Common Name English
OXOACETIC ACID ETHYL ESTER
Systematic Name English
ACETIC ACID, 2-OXO-, ETHYL ESTER
Common Name English
GLYOXYLIC ACID, ETHYL ESTER
Common Name English
ETHYL 2-OXOACETATE
Systematic Name English
ETHYL GLYOXYLATE
Systematic Name English
Code System Code Type Description
CHEBI
53275
Created by admin on Mon Mar 31 19:54:23 GMT 2025 , Edited by admin on Mon Mar 31 19:54:23 GMT 2025
PRIMARY
PUBCHEM
70211
Created by admin on Mon Mar 31 19:54:23 GMT 2025 , Edited by admin on Mon Mar 31 19:54:23 GMT 2025
PRIMARY
FDA UNII
IXX9MQ1J1I
Created by admin on Mon Mar 31 19:54:23 GMT 2025 , Edited by admin on Mon Mar 31 19:54:23 GMT 2025
PRIMARY
ECHA (EC/EINECS)
213-105-3
Created by admin on Mon Mar 31 19:54:23 GMT 2025 , Edited by admin on Mon Mar 31 19:54:23 GMT 2025
PRIMARY
NSC
49206
Created by admin on Mon Mar 31 19:54:23 GMT 2025 , Edited by admin on Mon Mar 31 19:54:23 GMT 2025
PRIMARY
EPA CompTox
DTXSID6061282
Created by admin on Mon Mar 31 19:54:23 GMT 2025 , Edited by admin on Mon Mar 31 19:54:23 GMT 2025
PRIMARY
CAS
924-44-7
Created by admin on Mon Mar 31 19:54:23 GMT 2025 , Edited by admin on Mon Mar 31 19:54:23 GMT 2025
PRIMARY