HEXAMETHYLDISILAZANE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C6H19NSi2
Molecular Weight	161.3928
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

C[Si](C)(C)N[Si](C)(C)C

InChI

InChIKey=FFUAGWLWBBFQJT-UHFFFAOYSA-N

InChI=1S/C6H19NSi2/c1-8(2,3)7-9(4,5)6/h7H,1-6H3

HIDE SMILES / InChI

Molecular Formula	C6H19NSi2
Molecular Weight	161.3928
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent.	2001 Aug 23	11506620
Synthesis and characterization of endcapped C18 stationary phases using a silica hydride intermediate.	2002 Feb 22	11883653
Analogues of thiolactomycin: potential drugs with enhanced anti-mycobacterial activity.	2002 Oct	12368443
Synthesis of 11C-amides using [11C]carbon monoxide and in situ activated amines by palladium-mediated carboxaminations.	2003 Feb 7	12926257
Structural studies of N,N'-di(ortho-fluorophenyl)formamidine group 1 metallation.	2003 Jan 20	12532290
Linear and cyclic polysilanes containing the bis(trimethylsilyl)amino group: synthesis, reactions, and spectroscopic characterization.	2003 Jul 28	12870947
Silylation reaction of dextran: effect of experimental conditions on silylation yield, regioselectivity, and chemical stability of silylated dextrans.	2003 Sep-Oct	12959617
The (Me5C5)Si+ cation: a stable derivative of HSi+.	2004 Aug 6	15232074
Determination of the absolute structure of (+)-cystothiazole B.	2004 Jun	15187406
Unprecedented catalytic asymmetric reduction of N-H imines.	2005 Jan 20	15646996
1,2-Eliminations in a novel reductive coupling of nitroarenes to give azoxy arenes by sodium bis(trimethylsilyl)amide.	2005 Jul 21	16018623
Base-promoted acyloin rearrangement of 1,8-di-tert-butyldimethylsilyloxybicyclo[2.2.2]oct-5-en-2-ones.	2005 Jun	15930779
C-H Activation (gamma-deprotonation) of a Sm(III) bis(trimethylsilyl)amide complex via macrocyclic stabilisation of the sodium counter ion.	2005 Mar 28	15770269
Synthesis and structural characterisation of lithium and sodium 2,6-dibenzylphenolate complexes.	2006 Jul 21	16820846
Efficient nucleophilic aromatic substitution between aryl nitrofluorides and alkynes.	2007 Jul 5	17552534
FeSO4 x 7H2O-catalyzed four-component synthesis of protected homoallylic amines.	2007 Jul 6	17550291
Zinc complexes of the biomimetic N,N,O ligand family of substituted 3,3-bis(1-alkylimidazol-2-yl)propionates: the formation of oxalate from pyruvate.	2007 Nov	17828423
Structure and reaction mechanism of basil eugenol synthase.	2007 Oct 3	17912370
A stable chiral diaminocyclopropenylidene.	2007 Sep 21	17728886
Quantification of cell edge velocities and traction forces reveals distinct motility modules during cell spreading.	2008	19011687
Silica passivation efficiency monitored by a surface-bound fluorescent dye.	2008 Aug 19	18616310
Displayed correlation between gene expression profiles and submicroscopic alterations in response to cetuximab, gefitinib and EGF in human colon cancer cell lines.	2008 Aug 8	18691415
Mercury or silver atoms bridging trinuclear titanium imido-nitrido systems.	2008 Dec 28	19057779
Ammonium benzene-phospho-nate.	2008 Jul 26	21203300
Reversibility in the protonolysis of a beta-diketiminate stabilised calcium bis(trimethylsilyl)amide with benzylamine.	2008 Mar 14	18305840
Surface property and in vitro biodegradation of microspheres fabricated by poly(epsilon-caprolactone-b-ethylene oxide) diblock copolymers.	2008 Mar 15	17647229
Sequential and selective Buchwald-Hartwig amination reactions for the controlled functionalization of 6-bromo-2-chloroquinoline: synthesis of ligands for the Tec Src homology 3 domain.	2008 Nov 21	18950225
An Ugi reaction in the total synthesis of (-)-dysibetaine.	2009	19173271
Synthesis, structure, and reactivity of low-coordinate 1,1,3,3-tetraethylguanidinate complexes.	2009 Aug 17	19624099
Newly characterised ex vivo colospheres as a three-dimensional colon cancer cell model of tumour aggressiveness.	2009 Aug 4	19603013
Bis(N-triisopropyl-silyl-quinolin-8-aminato)nickel(II).	2009 Dec 4	21579956
Synthesis and characterization of lithium hemiporphyrazines.	2009 Feb 16	19146413
Solution interaction of potassium and calcium bis(trimethylsilyl)amides; preparation of Ca[N(SiMe3)2]2 from dibenzylcalcium.	2009 Feb 16	19138130
pH-responsive biodegradable micelles based on acid-labile polycarbonate hydrophobe: synthesis and triggered drug release.	2009 Jul 13	19469499
[μ-Bis(trimethyl-silyl)amido]bis-[μ-N,N-dimethyl-N',N''-bis-(trimethyl-silyl)guanidinato]-triangulo-tricopper(I).	2009 Mar 14	21582350
Synthesis of an imprinted hybrid organic-inorganic polymeric sol-gel matrix toward the specific binding and isotherm kinetics investigation of creatinine.	2009 Mar 15	19236048
Synthesis and characterization of group 11 1,1,3,3-tetraalkylguanidinate (TAG) clusters: [M2(mu-TAG){mu-N(SiMe3)2}]2 (M = Cu, Ag, and Au).	2009 Mar 16	19209913
Beta-diketiminato calcium and magnesium amides; model complexes for hydroamination catalysis.	2009 May 18	19326917
Hydrofluoric-acid-resistant and hydrophobic pure-silica-zeolite MEL low-dielectric-constant films.	2009 May 5	19344154
Solid-state (49/47)Ti NMR of titanium-based MCM-41 hybrid materials.	2009 Nov 3	19810676
Reversible transformation of a stable monomeric silicon(II) compound into a stable disilene by phase transfer: experimental and theoretical studies of the system {[(Me3Si)2N](Me5C5)Si}n with n = 1,2.	2009 Sep 2	19655748
The pneumococcal serine-rich repeat protein is an intra-species bacterial adhesin that promotes bacterial aggregation in vivo and in biofilms.	2010 Aug 12	20714350
Difluorobenzocyclooctyne: synthesis, reactivity, and stabilization by beta-cyclodextrin.	2010 Aug 25	20666466
[Fe(4)S(4)](q) cubane clusters (q = 4+, 3+, 2+) with terminal amide ligands.	2010 Jul 19	20553035
Synthesis and antiprotozoal activity of 2,5-bis[amidinoaryl]thiazoles.	2010 May 15	20403703
Bone is not essential for osteoclast activation.	2010 Sep 17	20862258

Patents

Substance Class	Chemical Created by `admin` on `Fri Dec 15 18:26:04 GMT 2023` Edited by `admin` on `Fri Dec 15 18:26:04 GMT 2023`
Record UNII	H36C68P1BH
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

HEXAMETHYLDISILAZANE

Systematic Name

English

HEXAMETHYLDISILAZANE [MI]

Common Name

English

NSC-93895

Code

English

1,1,1-TRIMETHYL-N-(TRIMETHYLSILYL)SILANAMINE

Systematic Name

English

HEXAMETHYLDISILAZANE [HSDB]

Common Name

English

Code System Code Type Description

SMS_ID

100000170857