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Details

Stereochemistry ABSOLUTE
Molecular Formula C22H34O6
Molecular Weight 394.5018
Optical Activity UNSPECIFIED
Defined Stereocenters 9 / 9
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of GRAYANOTOXIN IV

SMILES

[H][C@@]12C[C@H](O)C(C)(C)[C@@]1(O)[C@H](O)C[C@]34C[C@@](C)(O)[C@H](CC[C@@]3([H])C2=C)[C@@]4([H])OC(C)=O

InChI

InChIKey=RVBLUTOAMOFHON-PWQJHGGPSA-N
InChI=1S/C22H34O6/c1-11-13-6-7-14-18(28-12(2)23)21(13,10-20(14,5)26)9-17(25)22(27)15(11)8-16(24)19(22,3)4/h13-18,24-27H,1,6-10H2,2-5H3/t13-,14+,15-,16-,17+,18+,20+,21-,22-/m0/s1

HIDE SMILES / InChI

Molecular Formula C22H34O6
Molecular Weight 394.5018
Charge 0
Count
Stereochemistry ABSOLUTE
Additional Stereochemistry No
Defined Stereocenters 9 / 9
E/Z Centers 0
Optical Activity UNSPECIFIED

Approval Year

Substance Class Chemical
Created
by admin
on Fri Dec 15 16:57:24 GMT 2023
Edited
by admin
on Fri Dec 15 16:57:24 GMT 2023
Record UNII
GUQ33O7179
Record Status Validated (UNII)
Record Version
  • Download
Name Type Language
GRAYANOTOXIN IV
Common Name English
.DELTA.10(18)-ACETYLANDROMEDENOL
Common Name English
ACETYLANDROMED-10(18)-ENOL
Common Name English
7,9A-METHANO-9AH-CYCLOPENTA(B)HEPTALENE-2,8,11,11A,12(1H)-PENTOL, DODECAHYDRO-1,1,8-TRIMETHYL-4-METHYLENE-, 12-ACETATE, (2S,3AS,4AS,7R,4AR,8R,9AS,11R,11AR,12R)-(-)-
Systematic Name English
GRAYANOTOX-10(20)-ENE-3,5,6,14,16-PENTOL, 14-ACETATE, (3.BETA.,6.BETA.,14R)-
Systematic Name English
.DELTA.10(18)-ANDROMEDENOL, ACETATE
Common Name English
Code System Code Type Description
FDA UNII
GUQ33O7179
Created by admin on Fri Dec 15 16:57:24 GMT 2023 , Edited by admin on Fri Dec 15 16:57:24 GMT 2023
PRIMARY
CAS
30272-17-4
Created by admin on Fri Dec 15 16:57:24 GMT 2023 , Edited by admin on Fri Dec 15 16:57:24 GMT 2023
PRIMARY
WIKIPEDIA
Grayanotoxin
Created by admin on Fri Dec 15 16:57:24 GMT 2023 , Edited by admin on Fri Dec 15 16:57:24 GMT 2023
PRIMARY Grayanotoxins can be found in honey produced from the pollen of plants such as Rhododendron ponticum that contains alkaloids that are poisonous to humans. Such honey is called 'mad honey'. Honey from Japan, Brazil, United States, Nepal, and British Columbia is most likely to be contaminated with grayanotoxins, although very rarely to toxic levels. In Nepal, this type of honey is used by the Gurung people both for its medicinal and hallucinogenic properties.Honey produced from the nectar of Andromeda polifolia contains high enough levels of grayanotoxin to cause full body paralysis and potentially fatal breathing difficulties due to diaphragm paralysis. Honey obtained from spoonwood and allied species such as sheep-laurel can also cause illness. The honey from Lestrimelitta limao also produces this paralyzing effect seen in the honey of A. polifolia and is also toxic to humans.
PUBCHEM
101316771
Created by admin on Fri Dec 15 16:57:24 GMT 2023 , Edited by admin on Fri Dec 15 16:57:24 GMT 2023
PRIMARY
EPA CompTox
DTXSID80952634
Created by admin on Fri Dec 15 16:57:24 GMT 2023 , Edited by admin on Fri Dec 15 16:57:24 GMT 2023
PRIMARY