2,2':6',2''-TERPYRIDINE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C15H11N3
Molecular Weight	233.2679
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

C1=CC=C(N=C1)C2=CC=CC(=N2)C3=CC=CC=N3

InChI

InChIKey=DRGAZIDRYFYHIJ-UHFFFAOYSA-N

InChI=1S/C15H11N3/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13/h1-11H

HIDE SMILES / InChI

Molecular Formula	C15H11N3
Molecular Weight	233.2679
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
A new, highly fluorescent terpyridine which responds to zinc ions with a large red-shift in emission.	2001 Dec 7	12240041
Terpyridine Zn (II), Ru (III) and Ir (III) complexex as new asymmetric chromophores for nonlinear optics: first evidence for a shift from positive to negative value of the quadratic hyperpolarizability of a ligand carrying an electron donor substituent upon coordination to different metal centres.	2002 Apr 21	12123008
Macromolecules containing bipyridine and terpyridine metal complexes: towards metallosupramolecular polymers.	2002 Aug 16	12203414
New dinuclear Ru(II) complexes containing free chelating polypyridine sites within the bridging ligands: absorption spectra, luminescence properties, redox behavior and sensing properties.	2002 Dec	12661595
A superior polypyridine ligand for platinum(II) lumaphors. Methyl substituents with a large stereoelectronic influence.	2002 Dec 2	12444782
Novel luminescent hexanuclear platinum(II) alkynyl complex: molecular lego from a face-to-face dinuclear platinum(II) building block.	2002 Dec 2	12444753
Photoluminescence switching of azobenzene-conjugated Pt(II) terpyridine complexes by trans-cis photoisomerization.	2002 Dec 30	12495356
Synthesis and study of Ru,Rh,Ru triads: modulation of orbital energies in a supramolecular architecture.	2002 Jul 29	12132932
Synthesis of the DNA-[Ru(tpy)(dppz)(CH(3)CN)](2+) conjugates and their photo cross-linking studies with the complementary DNA strand.	2002 Nov 13	12418893
Acid-base equilibrium of aqua-chromium-dioxolene complexes aimed at formation of oxo-chromium complexes.	2002 Nov 4	12401101
Example of highly stereoregulated ruthenium amidine complex formation: synthesis, crystal structures, and spectral and redox properties of the complexes [Ru(II)(trpy)[NC(5)H(4)-CH=N-N(C(6)H(5))C(CH(3))=NH]](ClO(4))(2) (1) and [Ru(II)(trpy)(NC(5)H(4)-CH=N-NH-C(6)H(5))Cl]ClO(4) (2) (trpy = 2,2':6',2"-terpyridine).	2002 Nov 4	12401090
Inhibition of Streptomyces chromofuscus phospholipase D activity by dichloro-(2,2':6',2''-terpyridine)-platinum (II) dihydrate.	2002 Oct	12683749
Preferential solvation of an ILCT excited state in bis(terpyridine-phenylene-vinylene) Zn(II) complexes.	2002 Oct 21	12430432
Spirometallodendrimers: terpyridine-based intramacromolecular cyclization upon complexation.	2002 Sep 21	12357826
Formation of a [1 + 1] metallomacrocycle from a heterotritopic ligand containing two terpy and one bipy metal-binding domains.	2002 Sep 21	12357782
Photoluminescent supramolecular polymers: metal-ion directed polymerization of terpyridine-functionalized perylene bisimide dyes.	2002 Sep 7	12271654
Oligonucleotide duplex stabilization by end-linked terpyridine x Cu(II) complexes.	2003	14510417
Cation sensors based on terpyridine-functionalized boradiazaindacene.	2003 Aug 18	12916098
From supramolecular block copolymers to advanced nano-objects.	2003 Aug 4	12898674
Synthesis, structure, and acid-base and redox properties of a family of new Ru(II) isomeric complexes containing the trpy and the dinucleating Hbpp ligands.	2003 Dec 15	14658892
Enhancement of luminescence lifetimes of mononuclear ruthenium(II)-terpyridine complexes by manipulation of the sigma-donor strength of ligands.	2003 Dec 15	14658891
The remarkable reactivity of high oxidation state ruthenium and osmium polypyridyl complexes.	2003 Dec 15	14658865
Structural modulation of Cu(I) and Cu(II) complexes of sterically hindered tripyridine ligands by the bridgehead alkyl groups.	2003 Feb 24	12588157
Photochemical and thermal ligand exchange in a ruthenium(II) complex based on a scorpionate terpyridine ligand.	2003 Jan 21	12585384
Synthesis, characterization, and DNA binding properties of a series of Ru, Pt mixed-metal complexes.	2003 Jul 14	12844312
Routes to metallodendrimers: synthesis of isomeric neutral metallomacromolecules based on bis(2,2':6',2"-terpyridine)ruthenium(II) connectivity.	2003 Jul 21	12866080
Crystal structure of bromo(2,2':6',2"-terpyridine)(2-(phenylazo)-pyridine)ruthenium(II) tetrafluoroborate.	2003 Jun	12834249
Shape-persistant macrocycles with terpyridine units: synthesis, characterization, and structure in the crystal.	2003 Jun 11	12783543
Ferrocenyl-functionalised terpyridines and their transition-metal complexes: syntheses, structures and spectroscopic and electrochemical properties.	2003 Jun 16	12866548
Characterization of a stable ruthenium complex with an oxyl radical.	2003 Jun 4	12769583
Synthesis and DNA binding properties of a cationic 2,2':6',2"-terpyridine cobalt(II) complex containing an oligopeptide.	2003 Mar 1	12628707
Electronic tuning of the lability of Pt(II) complexes through pi-acceptor effects. Correlations between thermodynamic, kinetic, and theoretical parameters.	2003 Mar 10	12611540
Photophysics and redox behavior of chiral transition metal polymers.	2003 Mar 10	12611509
The cyanoimido ligand as an oxo analogue. Novel approaches to the preparations of cyano(imino)-aza-phosphorus(V) and N-cyanoaziridine.	2003 Mar 12	12617623
Multiple mixed-valence behavior in trans,trans-[(tpy)(Cl)2Os(III)(mu-1,3-N3)Os(III)(Cl)2(tpy)]+. An azido bridge from the reaction between trans-[Os(VI)(tpy)(Cl)2(N)]+ and NH3.	2003 Mar 12	12617621
Zinc(II)-templated synthesis of a [2]-catenane consisting of a 2,2',6',2' '-terpyridine-incorporating cycle and a 1,10-phenanthroline-containing ring.	2003 Mar 24	12639120
An outer-sphere two-electron platinum reagent.	2003 Mar 26	12643703
Relative binding strength of terpyridine model complexes under matrix-assisted laser desorption/ionization mass spectrometry conditions.	2003 May	12794871
Electrochemical and phosphorescent properties of new mixed-ligand Ir(II) complexes coordinated with both terpyridine and various bipyridine derivatives.	2003 May	12769380
Two new dimeric cadmium(II) and zinc(II) sulfate complexes with 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 2,2:6',2"-terpyridine.	2003 May	12743388
Electron donor-acceptor dyads based on ruthenium(II) bipyridine and terpyridine complexes bound to naphthalenediimide.	2003 May 5	12716183
Turning off phototriggered linkage isomerizations in ruthenium dimethyl sulfoxide complexes.	2003 Nov 17	14606824
Structural studies on the stepwise chelating processes of bidentate 2-(aminomethyl)pyridine and tridentate bis(2-pyridylmethyl)amine toward an acetate-bridged dirhodium(II) center.	2003 Nov 3	14577778
Synthesis of a copper [3]rotaxane able to function as an electrochemically driven oscillatory machine in solution, and to form SAMs on a metal surface.	2003 Oct 20	14552630
Polyoxometalates covalently bonded with terpyridine ligands.	2003 Oct 21	14594281
Cyclometalated analogues of platinum terpyridine complexes: kinetic study of the strong sigma-donor cis and trans effects of carbon in the presence of a pi-acceptor ligand backbone.	2003 Oct 6	14514330
Temperature-induced solid-state valence tautomeric interconversion in two cobalt-Schiff base diquinone complexes.	2003 Oct 6	14514319
A high-frequency and high-field EPR study of new azide and fluoride mononuclear Mn(III) complexes.	2003 Oct 8	14519019
Toward new paradigms in mixed-valency: ytterbocene-terpyridine charge-transfer complexes.	2003 Sep 21	14518902
Module-based assembly of copper(II) chloranilate compounds: syntheses, crystal structures, and magnetic properties of [[Cu(2)(CA)(terpy)(2)][Cu(CA)(2)]](n)() and [[Cu(2)(CA)(terpy)(2)(dmso)(2)][Cu(CA)(2)(dmso)(2)](EtOH)](n)(H(2)CA = chloranilic acid, terpy = 2,2':6',2' '-terpyridine, dmso = dimethyl sulfoxide).	2004 Jan 12	14704057

Patents

Substance Class	Chemical Created by `admin` on `Fri Dec 15 18:08:24 GMT 2023` Edited by `admin` on `Fri Dec 15 18:08:24 GMT 2023`
Record UNII	G5E357ISH5
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

2,2':6',2''-TERPYRIDINE

Systematic Name

English

NSC-3905

Code

English

2,6-DI(2-PYRIDYL)PYRIDINE

Systematic Name

English

2,2',2''-TERPYRIDINE

Common Name

English

2,6-BIS(2-PYRIDYL)PYRIDINE

Systematic Name

English

2,2',2''-TRIPYRIDINE

Common Name

English

NSC-36755

Code

English

.ALPHA.,.ALPHA.',.ALPHA.''-TRIPYRIDYL

Common Name

English

2,2',2''-TERPYRIDYL

Common Name

English

Code System Code Type Description

PUBCHEM

70848