2,2':6',2''-TERPYRIDINE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C15H11N3
Molecular Weight	233.2679
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

C1=CC=C(N=C1)C2=CC=CC(=N2)C3=CC=CC=N3

InChI

InChIKey=DRGAZIDRYFYHIJ-UHFFFAOYSA-N

InChI=1S/C15H11N3/c1-3-10-16-12(6-1)14-8-5-9-15(18-14)13-7-2-4-11-17-13/h1-11H

HIDE SMILES / InChI

Molecular Formula	C15H11N3
Molecular Weight	233.2679
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
Module-based assembly of copper(II) chloranilate compounds: syntheses, crystal structures, and magnetic properties of [[Cu(2)(CA)(terpy)(2)][Cu(CA)(2)]](n)() and [[Cu(2)(CA)(terpy)(2)(dmso)(2)][Cu(CA)(2)(dmso)(2)](EtOH)](n)(H(2)CA = chloranilic acid, terpy = 2,2':6',2' '-terpyridine, dmso = dimethyl sulfoxide).	2004-01-12	14704057
Synthesis, structure, and acid-base and redox properties of a family of new Ru(II) isomeric complexes containing the trpy and the dinucleating Hbpp ligands.	2003-12-15	14658892
Enhancement of luminescence lifetimes of mononuclear ruthenium(II)-terpyridine complexes by manipulation of the sigma-donor strength of ligands.	2003-12-15	14658891
The remarkable reactivity of high oxidation state ruthenium and osmium polypyridyl complexes.	2003-12-15	14658865
Turning off phototriggered linkage isomerizations in ruthenium dimethyl sulfoxide complexes.	2003-11-17	14606824
Structural studies on the stepwise chelating processes of bidentate 2-(aminomethyl)pyridine and tridentate bis(2-pyridylmethyl)amine toward an acetate-bridged dirhodium(II) center.	2003-11-03	14577778
Polyoxometalates covalently bonded with terpyridine ligands.	2003-10-21	14594281
Synthesis of a copper [3]rotaxane able to function as an electrochemically driven oscillatory machine in solution, and to form SAMs on a metal surface.	2003-10-20	14552630
A high-frequency and high-field EPR study of new azide and fluoride mononuclear Mn(III) complexes.	2003-10-08	14519019
Cyclometalated analogues of platinum terpyridine complexes: kinetic study of the strong sigma-donor cis and trans effects of carbon in the presence of a pi-acceptor ligand backbone.	2003-10-06	14514330
Temperature-induced solid-state valence tautomeric interconversion in two cobalt-Schiff base diquinone complexes.	2003-10-06	14514319
Toward new paradigms in mixed-valency: ytterbocene-terpyridine charge-transfer complexes.	2003-09-21	14518902
Cation sensors based on terpyridine-functionalized boradiazaindacene.	2003-08-18	12916098
From supramolecular block copolymers to advanced nano-objects.	2003-08-04	12898674
Routes to metallodendrimers: synthesis of isomeric neutral metallomacromolecules based on bis(2,2':6',2"-terpyridine)ruthenium(II) connectivity.	2003-07-21	12866080
Synthesis, characterization, and DNA binding properties of a series of Ru, Pt mixed-metal complexes.	2003-07-14	12844312
Ferrocenyl-functionalised terpyridines and their transition-metal complexes: syntheses, structures and spectroscopic and electrochemical properties.	2003-06-16	12866548
Shape-persistant macrocycles with terpyridine units: synthesis, characterization, and structure in the crystal.	2003-06-11	12783543
Characterization of a stable ruthenium complex with an oxyl radical.	2003-06-04	12769583
Crystal structure of bromo(2,2':6',2"-terpyridine)(2-(phenylazo)-pyridine)ruthenium(II) tetrafluoroborate.	2003-06	12834249
Electron donor-acceptor dyads based on ruthenium(II) bipyridine and terpyridine complexes bound to naphthalenediimide.	2003-05-05	12716183
Relative binding strength of terpyridine model complexes under matrix-assisted laser desorption/ionization mass spectrometry conditions.	2003-05	12794871
Electrochemical and phosphorescent properties of new mixed-ligand Ir(II) complexes coordinated with both terpyridine and various bipyridine derivatives.	2003-05	12769380
Two new dimeric cadmium(II) and zinc(II) sulfate complexes with 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 2,2:6',2"-terpyridine.	2003-05	12743388
An outer-sphere two-electron platinum reagent.	2003-03-26	12643703
Zinc(II)-templated synthesis of a [2]-catenane consisting of a 2,2',6',2' '-terpyridine-incorporating cycle and a 1,10-phenanthroline-containing ring.	2003-03-24	12639120
The cyanoimido ligand as an oxo analogue. Novel approaches to the preparations of cyano(imino)-aza-phosphorus(V) and N-cyanoaziridine.	2003-03-12	12617623
Multiple mixed-valence behavior in trans,trans-[(tpy)(Cl)2Os(III)(mu-1,3-N3)Os(III)(Cl)2(tpy)]+. An azido bridge from the reaction between trans-[Os(VI)(tpy)(Cl)2(N)]+ and NH3.	2003-03-12	12617621
Electronic tuning of the lability of Pt(II) complexes through pi-acceptor effects. Correlations between thermodynamic, kinetic, and theoretical parameters.	2003-03-10	12611540
Photophysics and redox behavior of chiral transition metal polymers.	2003-03-10	12611509
Synthesis and DNA binding properties of a cationic 2,2':6',2"-terpyridine cobalt(II) complex containing an oligopeptide.	2003-03-01	12628707
Structural modulation of Cu(I) and Cu(II) complexes of sterically hindered tripyridine ligands by the bridgehead alkyl groups.	2003-02-24	12588157
Photochemical and thermal ligand exchange in a ruthenium(II) complex based on a scorpionate terpyridine ligand.	2003-01-21	12585384
Oligonucleotide duplex stabilization by end-linked terpyridine x Cu(II) complexes.	2003	14510417
Photoluminescence switching of azobenzene-conjugated Pt(II) terpyridine complexes by trans-cis photoisomerization.	2002-12-30	12495356
A superior polypyridine ligand for platinum(II) lumaphors. Methyl substituents with a large stereoelectronic influence.	2002-12-02	12444782
Novel luminescent hexanuclear platinum(II) alkynyl complex: molecular lego from a face-to-face dinuclear platinum(II) building block.	2002-12-02	12444753
New dinuclear Ru(II) complexes containing free chelating polypyridine sites within the bridging ligands: absorption spectra, luminescence properties, redox behavior and sensing properties.	2002-12	12661595
Synthesis of the DNA-[Ru(tpy)(dppz)(CH(3)CN)](2+) conjugates and their photo cross-linking studies with the complementary DNA strand.	2002-11-13	12418893
Acid-base equilibrium of aqua-chromium-dioxolene complexes aimed at formation of oxo-chromium complexes.	2002-11-04	12401101
Example of highly stereoregulated ruthenium amidine complex formation: synthesis, crystal structures, and spectral and redox properties of the complexes [Ru(II)(trpy)[NC(5)H(4)-CH=N-N(C(6)H(5))C(CH(3))=NH]](ClO(4))(2) (1) and [Ru(II)(trpy)(NC(5)H(4)-CH=N-NH-C(6)H(5))Cl]ClO(4) (2) (trpy = 2,2':6',2"-terpyridine).	2002-11-04	12401090
Preferential solvation of an ILCT excited state in bis(terpyridine-phenylene-vinylene) Zn(II) complexes.	2002-10-21	12430432
Inhibition of Streptomyces chromofuscus phospholipase D activity by dichloro-(2,2':6',2''-terpyridine)-platinum (II) dihydrate.	2002-10	12683749
Spirometallodendrimers: terpyridine-based intramacromolecular cyclization upon complexation.	2002-09-21	12357826
Formation of a [1 + 1] metallomacrocycle from a heterotritopic ligand containing two terpy and one bipy metal-binding domains.	2002-09-21	12357782
Photoluminescent supramolecular polymers: metal-ion directed polymerization of terpyridine-functionalized perylene bisimide dyes.	2002-09-07	12271654
Macromolecules containing bipyridine and terpyridine metal complexes: towards metallosupramolecular polymers.	2002-08-16	12203414
Synthesis and study of Ru,Rh,Ru triads: modulation of orbital energies in a supramolecular architecture.	2002-07-29	12132932
Terpyridine Zn (II), Ru (III) and Ir (III) complexex as new asymmetric chromophores for nonlinear optics: first evidence for a shift from positive to negative value of the quadratic hyperpolarizability of a ligand carrying an electron donor substituent upon coordination to different metal centres.	2002-04-21	12123008
A new, highly fluorescent terpyridine which responds to zinc ions with a large red-shift in emission.	2001-12-07	12240041

Patents

Substance Class	Chemical Created by `admin` on `Mon Mar 31 19:04:28 GMT 2025` Edited by `admin` on `Mon Mar 31 19:04:28 GMT 2025`
Record UNII	G5E357ISH5
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

2,2':6',2''-TERPYRIDINE

Systematic Name

English

NSC-36755

Preferred Name

English

NSC-3905

Code

English

2,6-DI(2-PYRIDYL)PYRIDINE

Systematic Name

English

2,2',2''-TERPYRIDINE

Common Name

English

2,6-BIS(2-PYRIDYL)PYRIDINE

Systematic Name

English

2,2',2''-TRIPYRIDINE

Common Name

English

.ALPHA.,.ALPHA.',.ALPHA.''-TRIPYRIDYL

Common Name

English

2,2',2''-TERPYRIDYL

Common Name

English

Code System Code Type Description

PUBCHEM

70848