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Details

Stereochemistry ACHIRAL
Molecular Formula Rh
Molecular Weight 102.9055
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of RHODIUM

SMILES

[Rh]

InChI

InChIKey=MHOVAHRLVXNVSD-UHFFFAOYSA-N
InChI=1S/Rh

HIDE SMILES / InChI

Molecular Formula Rh
Molecular Weight 102.9055
Charge 0
Count
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Rhodium is a hard, shiny, silvery metal. The major use of rhodium is in catalytic converters for cars (80%). It reduces nitrogen oxides in exhaust gases. Rhodium is also used as catalysts in the chemical industry, for making nitric acid, acetic acid and hydrogenation reactions. It is used to coat optic fibres and optical mirrors, and for crucibles, thermocouple elements and headlight reflectors. It is used as an electrical contact material as it has a low electrical resistance and is highly resistant to corrosion. Rhodium is a rare element with no known natural biological function. Rhodium complexes show diverse biological activities against various targets, including enzymes and protein-protein interactions. Dimeric mu-Acetato dimers of rhodium(II) as well as monomeric square planar rhodium(I) and octahedral rhodium(III) complexes have shown interesting antitumor properties. On the other hand, rhodium is a suspected carcinogen.

Originator

Curator's Comment: Rhodium was discovered in 1803 by William Wollaston. He collaborated with Smithson Tennant in a commercial venture, part of which was to produce pure platinum for sale. The first step in the process was to dissolve ordinary platinum in aqua regia (nitric acid + hydrochloric acid). Not all of it went into solution and it left behind a black residue. (Tennant investigated this residue and from it he eventually isolated osmium and iridium.) Wollaston concentrated on the solution of dissolved platinum which also contained palladium. He removed these metals by precipitation and was left with a beautiful red solution from which he obtained rose red crystals. These were sodium rhodium chloride, Na3RhCl6. From them he eventually produced a sample of the metal itself.

Approval Year

PubMed

PubMed

TitleDatePubMed
IgE antibody responses to platinum group metals: a large scale refinery survey.
1986 Jan
Studies of interaction between Rh(I) and human serum albumin in a "nanostructured biocatalyst" active in the hydroformylation reaction.
2006 Sep
Patents
Substance Class Chemical
Created
by admin
on Fri Dec 15 17:12:24 UTC 2023
Edited
by admin
on Fri Dec 15 17:12:24 UTC 2023
Record UNII
DMK383DSAC
Record Status Validated (UNII)
Record Version
  • Download
Name Type Language
RHODIUM
HSDB   MI  
Systematic Name English
RHODIUM METALLICUM [HPUS]
Common Name English
RHODIUM [MI]
Common Name English
RHODIUM-103
Common Name English
RHODIUM BLACK
Common Name English
RHODIUM METALLICUM
HPUS  
Common Name English
RHODIUM [HSDB]
Common Name English
Classification Tree Code System Code
NCI_THESAURUS C637
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
DSLD 1935 (Number of products:23)
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
Code System Code Type Description
MESH
D012238
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
DAILYMED
DMK383DSAC
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
EPA CompTox
DTXSID3052480
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
NCI_THESAURUS
C95190
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
WIKIPEDIA
Rhodium
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
PUBCHEM
23948
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
FDA UNII
DMK383DSAC
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
HSDB
2534
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
CHEBI
33359
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
MERCK INDEX
m9580
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY Merck Index
EVMPD
SUB125949
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
CAS
7440-16-6
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
RXCUI
1311402
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY RxNorm
ECHA (EC/EINECS)
231-125-0
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
SMS_ID
100000151644
Created by admin on Fri Dec 15 17:12:24 UTC 2023 , Edited by admin on Fri Dec 15 17:12:24 UTC 2023
PRIMARY
Related Record Type Details
ACTIVE MOIETY