Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C3H3F3O2 |
| Molecular Weight | 128.0499 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
CC1(OO1)C(F)(F)F
InChI
InChIKey=NEGUMGNBGIFXAL-UHFFFAOYSA-N
InChI=1S/C3H3F3O2/c1-2(7-8-2)3(4,5)6/h1H3
| Molecular Formula | C3H3F3O2 |
| Molecular Weight | 128.0499 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Concerning selectivity in the oxidation of peptides by dioxiranes. Further insight into the effect of carbamate protecting groups. | 2010-07-16 |
|
| Oxyfunctionalization of non-natural targets by dioxiranes. 6. On the selective hydroxylation of cubane. | 2009-08-20 |
|
| A facile synthesis of C-24 and C-25 oxysterols by in situ generated ethyl(trifluoromethyl)dioxirane. | 2009-01 |
|
| An investigation by means of correlation analysis into the mechanisms of oxidation of aryl methyl sulfides and sulfoxides by dimethyldioxirane in various solvents. | 2008-02-21 |
|
| Oxidation of peptides by methyl(trifluoromethyl)dioxirane: the protecting group matters. | 2007-01-19 |
|
| Oxidative cleavage of p-methoxybenzyl ethers with methyl(trifluoromethyl)dioxirane. | 2005-10-13 |
|
| Oxygenation of alkane C-H bonds with methyl(trifluoromethyl)dioxirane: effect of the substituents and the solvent on the reaction rate. | 2005-09-30 |
|
| Mechanism of the oxidation of sulfides by dioxiranes: conformational mobility and transannular interaction in the oxidation of thianthrene 5-oxide. | 2004-12-24 |
|
| Unexpectedly selective formation and reactions of epoxycyclooctenones under microwave-mediated conditions. | 2004-04-15 |
|
| Singlet-oxygen generation in the catalytic reaction of dioxiranes with nucleophilic anions. | 2004-02 |
|
| Epoxidation of chiral camphor N-enoylpyrazolidinones with methyl(trifluoromethyl)dioxirane and urea hydrogen peroxide/acid anhydride: reversal of stereoselectivity. | 2003-12-12 |
|
| Oxyfunctionalization of non-natural targets by dioxiranes. 5. Selective oxidation of hydrocarbons bearing cyclopropyl moieties. | 2003-10-03 |
|
| Relative reactivity of peracids versus dioxiranes (DMDO and TFDO) in the epoxidation of alkenes. A combined experimental and theoretical analysis. | 2003-01-29 |
|
| Mechanism of the oxidation of sulfides by dioxiranes. 1. Intermediacy of a 10-S-4 hypervalent sulfur adduct. | 2002-08-07 |
|
| Effect of geminal substitution on the strain energy of dioxiranes. Origin of the low ring strain of dimethyldioxirane. | 2002-05-31 |
|
| Oxyfunctionalization of non-natural targets by dioxiranes. 4. Efficient oxidation of Binor S using methyl(trifluoromethyl)dioxirane. | 2001-12-28 |
Patents
| Substance Class |
Chemical
Created
by
admin
on
Edited
Mon Mar 31 22:24:51 GMT 2025
by
admin
on
Mon Mar 31 22:24:51 GMT 2025
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| Record UNII |
A7JNM906ZN
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| Record Status |
Validated (UNII)
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| Record Version |
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