Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C4H9F3Si |
| Molecular Weight | 142.195 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
C[Si](C)(C)C(F)(F)F
InChI
InChIKey=MWKJTNBSKNUMFN-UHFFFAOYSA-N
InChI=1S/C4H9F3Si/c1-8(2,3)4(5,6)7/h1-3H3
| Molecular Formula | C4H9F3Si |
| Molecular Weight | 142.195 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Reactions of difluoroenoxysilanes with glycosyl donors: synthesis of difluoro-C-glycosides and difluoro-C-disaccharides. | 2001 |
|
| Bis(acylsilanes) and trifluoromethyltrimethylsilane: a useful system for the synthesis of cyclic 2,2-difluoro-3-trialkylsilyl-1,3-ketols and cyclic 2-fluoro-1,3-diketones(1). | 2001 Jun 29 |
|
| Mixed organofluorine-organosilicon chemistry. 13. One-pot synthesis of difluoroaldols from acylsilanes and trifluoromethyltrimethylsilane. application to the synthesis of a difluoro analogue of egomaketone. | 2001 Mar 23 |
|
| Abstracts of the XV International Ecdysone Workshop. June 30- July 6, 2002. Kolymbari Crete, Greece. | 2002 |
|
| Early transition-metal perfluoroalkyl complexes. | 2003 Dec 3 |
|
| Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones. | 2003 May 30 |
|
| Regioselective nucleophilic 1,4-trifluoromethylation of 2-polyfluoroalkylchromones with (trifluoromethyl)trimethylsilane. Synthesis of fluorinated analogs of natural 2,2-dimethylchroman-4-ones and 2,2-dimethylchromenes. | 2003 Oct 3 |
|
| The first Cu(I)-mediated nucleophilic trifluoromethylation reactions using (trifluoromethyl)trimethylsilane in ionic liquids. | 2004 Oct 7 |
|
| Preparation of tri- and difluoromethylated amines from aldimines using (trifluoromethyl)trimethylsilane. | 2006 Aug 3 |
|
| Facile synthesis of TMS-protected trifluoromethylated alcohols using trifluoromethyltrimethylsilane (TMSCF3) and various nucleophilic catalysts in DMF. | 2006 Sep 1 |
|
| Enantiopure quaternary alpha-trifluoromethyl-alpha-alkoxyaldehydes from L-tartaric acid derived ketoamides. | 2008 Oct 17 |
|
| Catalytic enantioselective trifluoromethylation of azomethine imines with trimethyl(trifluoromethyl)silane. | 2009 |
|
| Cinchona alkaloid-catalyzed asymmetric trifluoromethylation of alkynyl ketones with trimethylsilyl trifluoromethane. | 2010 Nov 19 |
|
| Copper-mediated oxidative trifluoromethylation of boronic acids. | 2010 Nov 5 |
|
| Benzoyl peroxide (BPO)-promoted oxidative trifluoromethylation of tertiary amines with trimethyl(trifluoromethyl)silane. | 2010 Sep 14 |
| Substance Class |
Chemical
Created
by
admin
on
Edited
Sat Dec 16 09:11:36 GMT 2023
by
admin
on
Sat Dec 16 09:11:36 GMT 2023
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| Record UNII |
A009786QPJ
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| Record Status |
Validated (UNII)
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| Record Version |
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DTXSID20338998
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81290-20-2
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Trifluoromethyltrimethylsilane
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A009786QPJ
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m11121
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552549
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