KOJIBIOSE

Details

Stereochemistry	ABSOLUTE
Molecular Formula	C12H22O11
Molecular Weight	342.2965
Optical Activity	UNSPECIFIED
Defined Stereocenters	9 / 9
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O)C=O

InChI

InChIKey=PZDOWFGHCNHPQD-OQPGPFOOSA-N

InChI=1S/C12H22O11/c13-1-4(16)7(17)8(18)5(2-14)22-12-11(21)10(20)9(19)6(3-15)23-12/h2,4-13,15-21H,1,3H2/t4-,5+,6-,7-,8-,9-,10+,11-,12+/m1/s1

HIDE SMILES / InChI

Molecular Formula	C12H22O11
Molecular Weight	342.2965
Charge	0
Count

Stereochemistry	ABSOLUTE
Additional Stereochemistry	No
Defined Stereocenters	9 / 9
E/Z Centers	0
Optical Activity	UNSPECIFIED

Approval Year

PubMed

Title	Date	PubMed
Enzymatic synthesis of kojioligosaccharides using kojibiose phosphorylase.	2001	16233080
Enzymatic synthesis of novel oligosaccharides from L-sorbose, maltose, and sucrose using kojibiose phosphorylase.	2001	16233079
Transfer of high-mannose-type oligosaccharides to disaccharides by endo-beta-N-acetylglucosaminidase from Arthrobacter protophormiae.	2002	16233259
Identification of mono-, oligo-, and polysaccharides secreted from soybean roots.	2002 Apr	12884130
Purification and biochemical characterization of a soluble alpha-glucosidase from the parasite Entamoeba histolytica.	2003	14574111
Synthesis and structural analysis of five novel oligosaccharides prepared by glucosyltransfer from beta-D-glucose 1-phosphate to isokestose and nystose using Thermoanaerobacter brockii kojibiose phosphorylase.	2003 Apr 22	12681912
Purification and characterization of a new type of alpha-glucosidase from Paecilomyces lilacinus that has transglucosylation activity to produce alpha-1,3- and alpha-1,2-linked oligosaccharides.	2003 Jan	12619670
Transglucosylation activities of multiple forms of alpha-glucosidase from spinach.	2003 May	12834301
Cloning and sequencing of kojibiose phosphorylase gene from Thermoanaerobacter brockii ATCC35047.	2004	16233673
Purification and characterization of Acremonium implicatum alpha-glucosidase having regioselectivity for alpha-1,3-glucosidic linkage.	2004 Aug 2	15262228
Trehalose synthase of Mycobacterium smegmatis: purification, cloning, expression, and properties of the enzyme.	2004 Nov	15511231
Overexpression and characterization of two unknown proteins, YicI and YihQ, originated from Escherichia coli.	2004 Sep	15294295
Enhancement of thermostability of kojibiose phosphorylase from Thermoanaerobacter brockii ATCC35047 by random mutagenesis.	2005 Aug	16198267
Combined NMR and quantum chemical studies on the interaction between trehalose and dienes relevant to the antioxidant function of trehalose.	2005 Feb 24	16851317
Enzymatic synthesis of a 2-O-alpha-D-glucopyranosyl cyclic tetrasaccharide by kojibiose phosphorylase.	2005 Feb 28	15680600
Influence of disaccharide structure on prebiotic selectivity in vitro.	2005 Jun 29	15969496
Hyper expression of kojibiose phosphorylase gene and trehalose phosphorylase gene from Thermoanaerobacter brockii ATCC35047 in Bacillus subtilis and selaginose synthesis utilizing two phosphorylases.	2005 Sep	16243288
Conformational and dynamical properties of disaccharides in water: a molecular dynamics study.	2006 Jun 15	16581848
Acceptor recognition of kojibiose phosphorylase from Thermoanaerobacter brockii: syntheses of glycosyl glycerol and myo-inositol.	2006 May	16781473
Construction and characterization of chimeric enzymes of kojibiose phosphorylase and trehalose phosphorylase from Thermoanaerobacter brockii.	2006 Oct 16	16872587
Vibrational circular dichroism (VCD) studies on disaccharides in the CH region: toward discrimination of the glycosidic linkage position.	2007 Apr 7	17377664
Three novel oligosaccharides synthesized using Thermoanaerobacter brockii kojibiose phosphorylase.	2007 Jun 28	17880747
Function-unknown glycoside hydrolase family 31 proteins, mRNAs of which were expressed in rice ripening and germinating stages, are alpha-glucosidase and alpha-xylosidase.	2007 Oct	17875553
Structural insights into the substrate specificity and function of Escherichia coli K12 YgjK, a glucosidase belonging to the glycoside hydrolase family 63.	2008 Aug 1	18586271
The first alpha-1,3-glucosidase from bacterial origin belonging to glycoside hydrolase family 31.	2009 Nov-Dec	19683032
Regioselective O-glucosylation by sucrose phosphorylase: a promising route for functional diversification of a range of 1,2-propanediols.	2010 Aug 16	20598292
Synthesis of an alpha-kojibiosyl substituted glycerol teichoic acid hexamer.	2010 Jun 1	20409722
Rational engineering of Lactobacillus acidophilus NCFM maltose phosphorylase into either trehalose or kojibiose dual specificity phosphorylase.	2010 Oct	20713411

Patents

Substance Class	Chemical Created by `admin` on `Fri Dec 15 17:53:43 GMT 2023` Edited by `admin` on `Fri Dec 15 17:53:43 GMT 2023`
Record UNII	9R6V2933TB
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

KOJIBIOSE

Common Name

English

(2R,3S,4R,5R)-3,4,5,6-TETRAHYDROXY-2-(((2R,3R,4S,5S,6R)-3,4,5-TRIHYDROXY-6-(HYDROXYMETHYL)TETRAHYDRO-2H-PYRAN-2-YL)OXY)HEXANAL

Systematic Name

English

2-O-.ALPHA.-D-GLUCOPYRANOSYL-D-GLUCOSE

Common Name

English

(3R,4S,5S,6R)-6-(HYDROXYMETHYL)-3-(((2R,3R,4S,5S,6R)-3,4,5-TRIHYDROXY-6-(HYDROXYMETHYL)TETRAHYDRO-2H-PYRAN-2-YL)OXY)TETRAHYDRO-2H-PYRAN-2,4,5-TRIOL

Systematic Name

English

D-GLUCOSE, 2-O-.ALPHA.-D-GLUCOPYRANOSYL-

Common Name

English

Code System Code Type Description

CAS

2140-29-6