Details
| Stereochemistry | RACEMIC |
| Molecular Formula | C44H32P2 |
| Molecular Weight | 622.6724 |
| Optical Activity | NONE |
| Additional Stereochemistry | Yes |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
| Stereo Comments | AXIAL, RACEMIC |
SHOW SMILES / InChI
SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C56)P(C7=CC=CC=C7)C8=CC=CC=C8
InChI
InChIKey=MUALRAIOVNYAIW-UHFFFAOYSA-N
InChI=1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H
| Molecular Formula | C44H32P2 |
| Molecular Weight | 622.6724 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Pd-catalyzed asymmetric hydrogenation of alpha-fluorinated iminoesters in fluorinated alcohol: a new and catalytic enantioselective synthesis of fluoro alpha-amino acid derivatives. | 2001 Feb 8 |
|
| Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles. | 2002 Aug 14 |
|
| Construction of monomeric and polymeric porphyrin compartments by a Pd(II)-pyridine interaction and their chiral twisting by a BINAP ligand. | 2003 Feb 7 |
|
| How to turn the catalytic asymmetric hydroboration reaction of vinylarenes into a recyclable process. | 2003 Jan 3 |
|
| Preparation of an amphiphilic resin-supported BINAP ligand and its use for rhodium-catalyzed asymmetric 1,4-addition of phenylboronic acid in water. | 2004 Sep 16 |
|
| Chiroptical activity of BINAP-stabilized undecagold clusters. | 2006 Jun 22 |
|
| Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes. | 2006 Mar 22 |
|
| An unexpected possible role of base in asymmetric catalytic hydrogenations of ketones. Synthesis and characterization of several key catalytic intermediates. | 2006 Oct 25 |
|
| The hydrogenation/transfer hydrogenation network in asymmetric reduction of ketones catalyzed by [RuCl2(binap)(pica)] complexes. | 2008 Oct 6 |
|
| Synthesis and characterization of FePd magnetic nanoparticles modified with chiral BINAP ligand as a recoverable catalyst vehicle for the asymmetric coupling reaction. | 2009 Oct 21 |
|
| Origin of intense chiroptical effects in undecagold subnanometer particles. | 2010 Feb 3 |
|
| Synthesis, characterization, and catalytic properties of new electrophilic iridium(III) complexes containing the (R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl ligand. | 2010 May 3 |
|
| The preparation of bi-functional organophosphine oxides as potential antitumor agents. | 2010 Nov |
Patents
| Substance Class |
Chemical
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| Record Status |
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