Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C2F6O5S2 |
| Molecular Weight | 282.139 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
FC(F)(F)S(=O)(=O)OS(=O)(=O)C(F)(F)F
InChI
InChIKey=WJKHJLXJJJATHN-UHFFFAOYSA-N
InChI=1S/C2F6O5S2/c3-1(4,5)14(9,10)13-15(11,12)2(6,7)8
| Molecular Formula | C2F6O5S2 |
| Molecular Weight | 282.139 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| A straightforward approach towards 5-substituted thiazolylpeptides via the thio-Ugi-reaction. | 2010-12-07 |
|
| Aminopyrazine inhibitors binding to an unusual inactive conformation of the mitotic kinase Nek2: SAR and structural characterization. | 2010-11-11 |
|
| Stereoselective synthesis of 2,3,6-trisubstituted tetrahydropyridines via Tf(2)O-mediated Grob fragmentation: access to indolizidines (-)-209I and (-)-223J. | 2010-11-05 |
|
| Controlled and chemoselective reduction of secondary amides. | 2010-09-22 |
|
| Difluorobenzocyclooctyne: synthesis, reactivity, and stabilization by beta-cyclodextrin. | 2010-08-25 |
|
| Synthesis and reactivity of rhodium(II) N-triflyl azavinyl carbenes. | 2010-03-03 |
|
| 2-Azido-3,4;6,7-di-O-isopropyl-idene-α-d-glycero-d-talo-heptopyran-ose. | 2010-02-06 |
|
| N-(4-Chloro-phen-yl)-1,1,1-trifluoro-N-(trifluoro-methyl-sulfon-yl)methane-sulfonamide. | 2010-02-03 |
|
| Calyculins and related marine natural products as serine-threonine protein phosphatase PP1 and PP2A inhibitors and total syntheses of calyculin A, B, and C. | 2010-01-21 |
|
| Highly stereoselective synthesis of alpha-D-mannopyranosyl phosphosugars. | 2009-12-18 |
|
| PIKfyve regulation of endosome-linked pathways. | 2009-07 |
|
| Nucleophilic reactivity of a d0 molybdenum oxo moiety. | 2009-02-21 |
|
| Efficient dehydrative sialylation of C-4-aminated sialyl-hemiketal donors with Ph2SO/Tf2O. | 2009-02-20 |
|
| Pre-activation of fully acetylated dodecyl thioglycosides with BSP-Tf2O led to efficient glycosylation at low temperature. | 2009-02-17 |
|
| Direct dehydrative N-pyridinylation of amides. | 2009-02-06 |
|
| Stereocontrolled synthesis of D- and L-beta-rhamnopyranosides with 4-O-6-S-alpha-cyanobenzylidene-protected 6-thiorhamnopyranosyl thioglycosides. | 2009-01-16 |
|
| Is donor-acceptor hydrogen bonding necessary for 4,6-O-benzylidene-directed beta-mannopyranosylation? Stereoselective synthesis of beta-C-mannopyranosides and alpha-C-glucopyranosides. | 2008-11-06 |
|
| Selective mono reduction of bis-phosphine oxides under mild conditions. | 2008-10-07 |
|
| A versatile and highly stereoselective access to vinyl triflates derived from 1,3-dicarbonyl and related compounds. | 2008-10-03 |
|
| A versatile cyclodehydration reaction for the synthesis of isoquinoline and beta-carboline derivatives. | 2008-08-21 |
|
| Electrophile-induced dearomatizing spirocyclization of N-arylisonicotinamides: a route to spirocyclic piperidines. | 2008-07-17 |
|
| Stereoselective synthesis of acetoacetate-derived enol triflates. | 2008-07-03 |
|
| Stereoselective direct glycosylation with anomeric hydroxy sugars by activation with phthalic anhydride and trifluoromethanesulfonic anhydride involving glycosyl phthalate intermediates. | 2008-07-02 |
|
| The structure of polymer-supported triphenylphosphine ditriflate: a potentially useful reagent in organic synthesis. | 2008-06-20 |
|
| Total synthesis of siomycin A: construction of synthetic segments. | 2008-06-02 |
|
| Highly chemoselective metal-free reduction of tertiary amides. | 2008-01-09 |
|
| Overall "pseudocationic" trifluoromethylation of dihydropyridines with triflic anhydride. | 2008 |
|
| Synthesis of benzo[b]thiophenes by cyclization of arylketene dithioacetal monoxides under pummerer-like conditions. | 2007-12-20 |
|
| Bis(nona-fluoro-butane-sulfonato-κO)dioxidotris(tetra-hydro-furan-κO)uranium(VI). | 2007-12-12 |
|
| Synthesis of densely functionalized enantiopure indolizidines by ring-closing metathesis (RCM) of hydroxylamines from carbohydrate-derived nitrones. | 2007-12-12 |
|
| A new, powerful glycosylation method: activation of thioglycosides with dimethyl disulfide-triflic anhydride. | 2007-10-25 |
|
| Synthesis and glycosylation of a series of 6-mono-, di-, and trifluoro S-phenyl 2,3,4-tri-O-benzyl-thiorhamnopyranosides. Effect of the fluorine substituents on glycosylation stereoselectivity. | 2007-09-26 |
|
| Fragmentation of nitrone triflates to 9-membered rings. | 2007-08-16 |
|
| Studies on the intramolecular cyclizations of bicyclic delta-hydroxynitriles promoted by triflic anhydride. | 2007-05-11 |
|
| On the use of 3,5-O-benzylidene and 3,5-O-(di-tert-butylsilylene)-2-O-benzylarabinothiofuranosides and their sulfoxides as glycosyl donors for the synthesis of beta-arabinofuranosides: importance of the activation method. | 2007-03-02 |
|
| 4,6-O-benzylidene-directed beta-mannopyranosylation and alpha-glucopyranosylation: the 2-deoxy-2-fluoro and 3-deoxy-3-fluoro series of donors and the importance of the O2-C2-C3-O3 interaction. | 2007-03-02 |
|
| Synthesis of pyrimidines by direct condensation of amides and nitriles. | 2007 |
|
| Preparation of the functionalizable methionine surrogate azidohomoalanine via copper-catalyzed diazo transfer. | 2007 |
|
| Synthesis of a pentasaccharide fragment of varianose, a cell wall polysaccharide from Penicillium varians. | 2006-12-22 |
|
| Single-step synthesis of pyrimidine derivatives. | 2006-11-08 |
|
| On the influence of the C2-O2 and C3-O3 bonds in 4,6-O-benzylidene-directed beta-mannopyranosylation and alpha-glucopyranosylation. | 2006-10-27 |
|
| Synthesis of L-daunosamine and L-ristosamine glycosides via photoinduced aziridination. Conversion to thioglycosides for use in glycosylation reactions. | 2006-10-13 |
|
| Barbituric acid as a substituent at aryl methylium ions. | 2006-09-29 |
|
| Chromene chromium carbene complexes in the syntheses of naphthopyran and naphthopyrandione units present in photochromic materials and biologically active natural products. | 2006-08-30 |
|
| Synthesis and cross-coupling reactions of 7-azaindoles via a new donor-acceptor cyclopropane. | 2006-08-17 |
|
| On the nitrile effect in L-rhamnopyranosylation. | 2006-07-24 |
|
| Synthesis of n-octyl 2,6-dideoxy-alpha-L-lyxo-hexopyranosyl-(1-->2)-3-amino-3-deoxy-beta-D-galactopyranoside, an analog of the H-disaccharide antigen. | 2006-07-24 |
|
| Stereoselective synthesis of Z-alpha-aryl-alpha,beta-unsaturated esters. | 2006-06-23 |
|
| Stereocontrolled synthesis of the D- and L-glycero-beta-D-manno-heptopyranosides and their 6-deoxy analogues. Synthesis of methyl alpha-l-rhamno-pyranosyl-(1-->3)-D-glycero-beta-D-manno-heptopyranosyl- (1-->3)-6-deoxy-glycero-beta-D-manno-heptopyranosyl-(1-->4)-alpha-L- rhamno-pyranoside, a tetrasaccharide subunit of the lipopolysaccharide from Plesimonas shigelloides. | 2006-06-21 |
|
| New easy approach to the synthesis of 2,5-disubstituted and 2,4,5-trisubstituted 1,3-oxazoles. The reaction of 1-(methylthio)acetone with nitriles. | 2006-04-14 |
| Substance Class |
Chemical
Created
by
admin
on
Edited
Mon Mar 31 23:34:15 GMT 2025
by
admin
on
Mon Mar 31 23:34:15 GMT 2025
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| Record UNII |
8W034LHG1U
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| Record Status |
Validated (UNII)
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| Record Version |
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8W034LHG1U
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48509
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358-23-6
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206-616-8
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m11120
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DTXSID501014629
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Trifluoromethanesulfonic anhydride
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67749
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