Details
| Stereochemistry | ABSOLUTE |
| Molecular Formula | C19H26N2 |
| Molecular Weight | 282.4231 |
| Optical Activity | UNSPECIFIED |
| Defined Stereocenters | 2 / 2 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
CC[C@]12CCC[N@](C1)CCC3=C(CC2)NC4=C3C=CC=C4
InChI
InChIKey=FDNDLNFGITWTOZ-LJQANCHMSA-N
InChI=1S/C19H26N2/c1-2-19-10-5-12-21(14-19)13-9-16-15-6-3-4-7-17(15)20-18(16)8-11-19/h3-4,6-7,20H,2,5,8-14H2,1H3/t19-/m1/s1
| Molecular Formula | C19H26N2 |
| Molecular Weight | 282.4231 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ABSOLUTE |
| Additional Stereochemistry | No |
| Defined Stereocenters | 1 / 1 |
| E/Z Centers | 0 |
| Optical Activity | UNSPECIFIED |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Stereoselective formation of fused tricyclic amines from acyclic aldehydes by a cascade process involving condensation, cyclization, and dipolar cycloaddition. | 2009-03-20 |
|
| Rhazinilam and quebrachamine derivatives from Yunnan Kopsia arborea. | 2009-02-27 |
|
| Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis. | 2009-01-28 |
|
| Organometallic chemistry: catalyst takes control to heart. | 2008-12-18 |
|
| Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis. | 2008-12-18 |
|
| Enantioselective synthesis of 3,3-disubstituted piperidine derivatives by enolate dialkylation of phenylglycinol-derived oxazolopiperidone lactams. | 2007-06-08 |
|
| Highly efficient synthesis of tricyclic amines by a cyclization/cycloaddition cascade: total syntheses of aspidospermine, aspidospermidine, and quebrachamine. | 2007 |
|
| Formal synthesis of aspidosperma alkaloids via the intramolecular [3 + 2] cycloaddition of 2-azapentdienyllithiums. | 2006-04-13 |
|
| Four decades of structure determination by mass spectrometry: from alkaloids to heparin. | 2002-11 |
|
| Synthesis of vinca alkaloids and related compounds. 100. Stereoselective oxidation reactions of compounds with the aspidospermane and quebrachamine ring system. First synthesis of some alkaloids containing the epoxy ring. | 2002-10-18 |
|
| An efficient approach to Aspidosperma alkaloids via [4 + 2] cycloadditions of aminosiloxydienes: stereocontrolled total synthesis of (+/-)-tabersonine. Gram-scale catalytic asymmetric syntheses of (+)-tabersonine and (+)-16-methoxytabersonine. Asymmetric syntheses of (+)-aspidospermidine and (-)-quebrachamine. | 2002-05-01 |
| Substance Class |
Chemical
Created
by
admin
on
Edited
Mon Mar 31 22:51:54 GMT 2025
by
admin
on
Mon Mar 31 22:51:54 GMT 2025
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| Record UNII |
7M37I29KEU
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| Record Status |
Validated (UNII)
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| Record Version |
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7M37I29KEU
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4850-21-9
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DTXSID50878438
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m9416
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225-440-2
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92990
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