U.S. Department of Health & Human Services Divider Arrow National Institutes of Health Divider Arrow NCATS

Details

Stereochemistry ACHIRAL
Molecular Formula C2H3F3O3S
Molecular Weight 164.104
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of Methyl trifluoromethanesulfonate

SMILES

COS(=O)(=O)C(F)(F)F

InChI

InChIKey=OIRDBPQYVWXNSJ-UHFFFAOYSA-N
InChI=1S/C2H3F3O3S/c1-8-9(6,7)2(3,4)5/h1H3

HIDE SMILES / InChI

Molecular Formula C2H3F3O3S
Molecular Weight 164.104
Charge 0
Count
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Approval Year

PubMed

PubMed

TitleDatePubMed
Lithium salts of [1,12-dialkyl-CB11Me10]- anions.
2010-11-15
9-(2,6-Dimethyl-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.
2010-10-23
9-Phenyl-10H-acridinium trifluoro-methane-sulfonate.
2010-10-20
10-Methyl-9-[2-(propan-2-yl)phenoxy-carbonyl]-acridinium trifluoro-methane-sulfonate.
2010-10-09
9-(4-Chloro-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.
2010-10-09
9-(4-Fluoro-phen-oxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.
2010-10-09
Room temperature palladium-catalyzed cross coupling of aryltrimethylammonium triflates with aryl Grignard reagents.
2010-10-01
Synthesis, structure, and reactivity of a stabilized phosphiranylium salt.
2010-07-26
Identification and evaluation of [11C]GSK931145 as a novel ligand for imaging the type 1 glycine transporter with positron emission tomography.
2010-07
9-Benzyl-10-methyl-acridinium trifluoro-methane-sulfonate.
2010-06-05
Effects of frozen conditions on stereoselectivity and velocity of O-glycosylation reactions.
2010-06-01
9-(4-Bromo-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.
2010-05-12
9-(4-Methyl-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.
2010-05-12
Microstructured poly(2-oxazoline) bottle-brush brushes on nanocrystalline diamond.
2010-05-07
First principles insight into the alpha-glucan structures of starch: their synthesis, conformation, and hydration.
2010-04-14
[Three cases of occupational methyl trifluoromethanesulfonate poisoning].
2010-04
10-Methyl-9-phenoxy-carbonyl-acridinium trifluoro-methane-sulfonate monohydrate.
2010-03-24
9-(2-Ethyl-phenoxy-carbon-yl)-10-methyl-acridinium trifluoro-methane-sulfonate.
2010-03-13
Catalytic (asymmetric) methylene transfer to aldehydes.
2010-02-05
H(+), CH(3)(+), and R(3)Si(+) carborane reagents: when triflates fail.
2010-01-19
Bis(4'-dibutylaminostyryl)benzene: spectroscopic behavior upon protonation or methylation.
2009-12-07
Addition of methyl triflate to a hafnocene dinitrogen complex: stepwise n(2) methylation and conversion to a hafnocene hydrazonato compound.
2009-10-21
Carbonyl-chlorido(1-methyl-sulfanylpenta-1,3-dien-1-yl-5-yl-idene)bis-(triphenyl-phosphane)osmium(II).
2009-10-07
Synthesis and reactivity of a Ru(I) dimer devoid of pi-acid ligands.
2009-08-14
Cationic heterocycles as ligands: synthesis and reactivity with anionic nucleophiles of cationic triruthenium clusters containing C-metalated N-methylquinoxalinium or N-methylpyrazinium ligands.
2009-07-27
9-Chloro-2,4-dimethoxy-acridinium trifluoro-methane-sulfonate.
2009-03-14
9-(Methyl-sulfan-yl)acridinium trifluoro-methane-sulfonate.
2009-02-21
Synthesis and reactivity of metal carbene complexes with heterobiaryl spacer substituents.
2009-01-28
Synthesis of phenol and quinone metabolites of benzo[a]pyrene, a carcinogenic component of tobacco smoke implicated in lung cancer.
2009-01-16
Lewis-acid-assisted methyl exchange reactions in silylated aminodichloroarsanes.
2008-12-15
9-Ethyl-10-methyl-acridinium trifluoro-methane-sulfonate.
2008-12-06
The preparation of stable aziridinium ions and their ring-openings.
2008-09-28
Divergent and regioselective synthesis of 1,2,4- and 1,2,5-trisubstituted imidazoles.
2008-09-05
C-H activation on a diphosphine and hydrido-bridged diiridium complex: generation and detection of an active IrII-IrII species [(Cp*Ir)2(micro-dmpm)(micro-H)]+.
2008-07-21
Pyridine ring opening at room temperature at a rhenium tricarbonyl bipyridine complex.
2008-04-30
(Carbonyl-1κC)bis-[2,3(η)-cyclo-penta-dien-yl][μ(3)-(S-methyl trithio-carbonato)methylidyne-1:2:3κC,S'':C:C](triphenyl-phosphine-1κP)(μ(3)-sulfido-1:2:3κS)dicobalt(II)iron(II) trifluoro-methane-sulfonate.
2008-04-10
Carboxylation of an ansa-zirconocene dinitrogen complex: regiospecific hydrazine synthesis from N2 and CO2.
2008-04-02
10-Methyl-9-(2-nitro-phenoxy-carbon-yl)acridinium trifluoro-methane-sulfonate.
2008-01-04
Reactivity and stability of platinum(II) formyl complexes based on PCP-type ligands. The significance of sterics.
2007-12-28
Synthesis and properties of 1-methylthiopropargylammonium salts and their use as key precursors to sulfur-containing enediynes.
2007-12-06
Phase-transfer-catalyzed asymmetric acylimidazole alkylation.
2007-11-08
Alkylation and acylation of cyclotriphosphazenes.
2007-08-20
Bifunctional building blocks for glyco-architectures by TiCl4 -promoted ring opening of cyclodextrin derivatives.
2007-07
Cyclotetraphosphinophosphonium ions: synthesis, structures, and pseudorotation.
2007-06-13
Monocyclic di- and triphosphinophosphonium cations: new foundational frameworks for catena-phosphorus chemistry.
2007-05-14
Synthesis of para-methoxybenzyl (PMB) ethers under neutral conditions.
2007-04-14
Carbon-11 labeling chemistry based upon [11C]methyl iodide.
2007
Diphosphiranium (P2C) or diphosphetanium (P2C2) cyclic cations: different fates for the electrophile-initiated cyclodimerization of a phosphaalkene.
2006-12-20
Synthesis of extended polyphosphacumulenes.
2006-11-15
Boryllithium: isolation, characterization, and reactivity as a boryl anion.
2006-10-06
Patents
Substance Class Chemical
Created
by admin
on Mon Mar 31 21:11:27 GMT 2025
Edited
by admin
on Mon Mar 31 21:11:27 GMT 2025
Record UNII
7B25Z22EPV
Record Status Validated (UNII)
Record Version
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Name Type Language
Methyl trifluoromethanesulfonate
MI  
Systematic Name English
NSC-270679
Preferred Name English
METHANESULFONIC ACID, TRIFLUORO-, METHYL ESTER
Common Name English
TRIFLUOROMETHANESULFONIC ACID METHYL ESTER
Systematic Name English
METHANESULFONIC ACID, 1,1,1-TRIFLUORO-, METHYL ESTER
Common Name English
MEOTF
Common Name English
1,1,1-TRIFLUOROMETHANESULFONIC ACID METHYL ESTER
Systematic Name English
METHYL TRIFLUOROMETHANESULFONATE [MI]
Common Name English
METHYL TRIFLATE
Systematic Name English
Code System Code Type Description
WIKIPEDIA
Methyl triflate
Created by admin on Mon Mar 31 21:11:27 GMT 2025 , Edited by admin on Mon Mar 31 21:11:27 GMT 2025
PRIMARY
ECHA (EC/EINECS)
206-371-7
Created by admin on Mon Mar 31 21:11:27 GMT 2025 , Edited by admin on Mon Mar 31 21:11:27 GMT 2025
PRIMARY
NSC
270679
Created by admin on Mon Mar 31 21:11:27 GMT 2025 , Edited by admin on Mon Mar 31 21:11:27 GMT 2025
PRIMARY
MERCK INDEX
m7474
Created by admin on Mon Mar 31 21:11:27 GMT 2025 , Edited by admin on Mon Mar 31 21:11:27 GMT 2025
PRIMARY Merck Index
EPA CompTox
DTXSID6049272
Created by admin on Mon Mar 31 21:11:27 GMT 2025 , Edited by admin on Mon Mar 31 21:11:27 GMT 2025
PRIMARY
FDA UNII
7B25Z22EPV
Created by admin on Mon Mar 31 21:11:27 GMT 2025 , Edited by admin on Mon Mar 31 21:11:27 GMT 2025
PRIMARY
PUBCHEM
9526
Created by admin on Mon Mar 31 21:11:27 GMT 2025 , Edited by admin on Mon Mar 31 21:11:27 GMT 2025
PRIMARY
CAS
333-27-7
Created by admin on Mon Mar 31 21:11:27 GMT 2025 , Edited by admin on Mon Mar 31 21:11:27 GMT 2025
PRIMARY