Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C4H10F3NS |
| Molecular Weight | 161.189 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
CCN(CC)S(F)(F)F
InChI
InChIKey=CSJLBAMHHLJAAS-UHFFFAOYSA-N
InChI=1S/C4H10F3NS/c1-3-8(4-2)9(5,6)7/h3-4H2,1-2H3
| Molecular Formula | C4H10F3NS |
| Molecular Weight | 161.189 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Diethylaminosulfur trifluoride (DAST) has proven itself to be an extremely popular reagent for nucleophilic fluorination, due to its ease of handling and versatility. It has regularly been employed in a myriad selective fluorinations of alcohols, alkenols, carbohydrates, ketones, sulfides, epoxides, thioethers, and cyanohydrins. In addition some novel organic cyclizations are possible when DAST is employed as a reagent.
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Electrophilic fluorinating reagent mediated synthesis of fluorinated alpha-keto Ethers, benzil, and 6,6'-dialkoxy-2,2'-bipyridines. | 2002 Sep 6 |
|
| Rearrangement of homoallylic alcohols induced by DAST. | 2006 May 11 |
|
| Fluorination of triptolide and its analogues and their cytotoxicity. | 2008 Apr 1 |
|
| Brassinosteroids: synthesis and activity of some fluoro analogues. | 2008 Jul 10 |
|
| Fluorination reactions in microreactors. | 2008 Jul 14 |
|
| Aminodifluorosulfinium salts: selective fluorination reagents with enhanced thermal stability and ease of handling. | 2010 May 21 |
| Substance Class |
Chemical
Created
by
admin
on
Edited
Sat Dec 16 04:29:06 GMT 2023
by
admin
on
Sat Dec 16 04:29:06 GMT 2023
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| Record UNII |
78622BV6IJ
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| Record Status |
Validated (UNII)
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| Record Version |
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DTXSID20191484
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m4394
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253-771-2
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78622BV6IJ
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38078-09-0
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DIETHYLAMINOSULFUR TRIFLUORIDE
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123472
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