Trimethylchlorosilane

Details

Stereochemistry	ACHIRAL
Molecular Formula	C3H9ClSi
Molecular Weight	108.642
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

C[Si](C)(C)Cl

InChI

InChIKey=IJOOHPMOJXWVHK-UHFFFAOYSA-N

InChI=1S/C3H9ClSi/c1-5(2,3)4/h1-3H3

HIDE SMILES / InChI

Molecular Formula	C3H9ClSi
Molecular Weight	108.642
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
Influence of the degree of coverage of C18-bonded stationary phases on the mass transfer mechanism and its kinetics.	2006-09-22	16854425
Chlorosilane acute inhalation toxicity and development of an LC50 prediction model.	2006-07	16717023
Development and validation of a new gas flame ionization detector method for the determination of finasteride in tablets.	2006-05-15	16527234
Novel calixarene hemisphere synthesized via pinacol rearrangement of [2.1.2.1]metacyclophane.	2006-05-11	16671765
Electroreductive intramolecular coupling of aromatic imino esters: is four-membered cyclization much more favorable than six-membered cyclization?	2006-03-30	16562882
Inhibition of hepatitis B virus (HBV) replication by pyrimidines bearing an acyclic moiety: effect on wild-type and mutant HBV.	2006-03-23	16539393
Dioxomolybdenum(VI) and dioxotungsten(VI) complexes supported by an amido ligand.	2006-03-14	16505908
An efficient diethyl ether-based soxhlet protocol to quantify faecal sterols from catchment waters.	2006-03-03	16430911
A general and chemoselective synthesis of phosphoramidates through reaction of silylated nucleoside di- and triphosphates with silylated amines containing multifunctional groups.	2006-02-17	16468833
Synthesis and anti-HSV-1 activity of quinolonic acyclovir analogues.	2006-02-15	16321530
Effective controlled release of captopril by silylation of mesoporous MCM-41.	2006-02-13	16411260
Absence of halogen...halogen interactions in chlorotrimethylsilane polymorphs.	2006-02	16434795
Synthesis of nicotine derivatives via reductive disilylation of (S)-nicotine.	2006-01-19	16408869
A synthetic cycle for H2/CO activation and allene synthesis using recyclable zirconium complexes.	2005-12-14	16332063
Total selective synthesis of enantiopure O1-acyl-3-aminoalkane-1,2-diols by ring opening of aminoepoxides with carboxylic acids.	2005-12-09	16323844
Leukotoxin diols from ground corncob bedding disrupt estrous cyclicity in rats and stimulate MCF-7 breast cancer cell proliferation.	2005-12	16330350
The vibrational spectra of (CH3)3SiX (S=H, F, Br) molecules, revisited Transferable scale factor sets for methylsilane derivatives.	2005-12	15967707
Electroreductive acylation of aromatic ketones with acylimidazoles.	2005-11-11	16268614
Asymmetric synthesis of 2-aryl-2,3-dihydro-4-quinolones by rhodium-catalyzed 1,4-addition of arylzinc reagents in the presence of chlorotrimethylsilane.	2005-11-10	16268567
Vibrational spectrum of chlorotrimethylsilane.	2005-11	16257728
Diastereochemical diversity of imidazoline scaffolds via substrate controlled TMSCl mediated cycloaddition of azlactones.	2005-10-27	16235965
Synthetic and structural chemistry of amidinate-substituted boron halides.	2005-10-07	16172649
Separation of microorganisms using electromigration techniques.	2005-08-19	16114253
Novel synthesis of nucleoside 5'-phosphoramidates through reaction of nucleoside triphosphates with amines mediated by trimethylsilyl chloride.	2005-08-19	16095286
[Preparation and infrared spectral analysis of nanoporous silica thin film].	2005-07	16241051
Biomarker metabolites capturing the metabolite variance present in a rice plant developmental period.	2005-05-31	15927065
Preparation and evaluation of trimethylsilylated chitin as a versatile precursor for facile chemical modifications.	2005-05-10	15877360
Synthesis and structure of K+ [iPrN=C=P]-, a 1-aza-3lambda3-phospha-3-allenide.	2005-05-02	15847412
Synthesis of creatinine-imprinted poly(beta-cyclodextrin) for the specific binding of creatinine.	2005-05	15585280
Determination of 14 benzodiazepines and hydroxy metabolites, zaleplon and zolpidem as tert-butyldimethylsilyl derivatives compared with other common silylating reagents in whole blood by gas chromatography-mass spectrometry.	2005-04-25	15734157
Use of 15N-depleted artificial compost in bound residue studies.	2005-04	15792662
Mono-, di-, and tricoordinated phosphorus attached to a N-N unit: an experimental and theoretical study.	2005-03-21	15762701
Breaking of ketene bonds during HCl addition to trimethylsilylketene.	2005-03-17	16838983
Difluoro complexes of platinum(II) and -(IV) with monodentate phosphine ligands: an exceptional stability of d6 octahedral organometallic fluorides.	2005-03-07	15732997
Synthesis of phosphorofluoridates and phosphorofluoridothioates via the phosphoramidite approach.	2005-03-07	15731873
Monitoring dynamics of single-cell gene expression over multiple cell cycles.	2005	16729059
Detection of designer steroids.	2005	16604170
Simultaneous determination of carisoprodol and meprobamate in human hair using solid-phase extraction and gas chromatography/mass spectrometry of the trimethylsilyl derivatives.	2005	16200657
Studies on the base-promoted conversion of conjugated alkynyl esters to alpha-substituted alpha-allenyl esters.	2004-12-24	15609951
Construction of optically active CF3-containing quaternary carbon centers via stereospecific S(N)2' reaction.	2004-12-09	15575652
Dansylated aminopropyl controlled pore glass: a model for silica-liquid solvation.	2004-11-23	15544379
Electroreductive intramolecular coupling of aromatic beta- and gamma-imino esters: a new synthetic method for N-alkoxycarbonyl-2-aryl-3-ones and cis-2-aryl-3-ols of pyrrolidines and piperidines.	2004-10-29	15498001
Diagnosis of chronic alcohol consumption. Hair analysis for ethyl-glucuronide.	2004-10-29	15451088
Silylation and surface properties of chemically grafted hydrophobic silica.	2004-09-01	15276051
Chlorotrimethylsilane, a reagent for the direct quantitative analysis of fats and oils present in vegetable and meat samples.	2004-08-20	15481471
Development and validation of a gas chromatography-mass spectrometry method for the simultaneous determination of buprenorphine, flunitrazepam and their metabolites in rat plasma: application to the pharmacokinetic study.	2004-08-05	15203048
GHB in postmortem toxicology. Discrimination between endogenous production from exposure using multiple specimens.	2004-07-16	15240040
ipso-nitration of arylboronic acids with chlorotrimethylsilane-nitrate salts.	2004-06-24	15200321
Desulfation of sulfated galactans with chlorotrimethylsilane. Characterization of beta-carrageenan by 1H NMR spectroscopy.	2004-06-22	15183736
[Determination of fatty acid methyl ester ethoxylates by gas chromatography].	2004-01	15712957

Patents

Substance Class	Chemical Created by `admin` on `Mon Mar 31 21:12:07 GMT 2025` Edited by `admin` on `Mon Mar 31 21:12:07 GMT 2025`
Record UNII	62UO4690X6
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

Trimethylchlorosilane

Systematic Name

English

CHLOROTRIMETHYLSILANE

Preferred Name

English

CHLOROTRIMETHYLSILANE [MI]

Common Name

English

TRIMETHYLSILYL CHLORIDE

Systematic Name

English

NSC-15750

Code

English

TRIMETHYL CHLOROSILANE

Systematic Name

English

Code System Code Type Description

WIKIPEDIA

TRIMETHYLSILYL CHLORIDE