1,5-HEXADIENE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C6H10
Molecular Weight	82.1436
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

C=CCCC=C

InChI

InChIKey=PYGSKMBEVAICCR-UHFFFAOYSA-N

InChI=1S/C6H10/c1-3-5-6-4-2/h3-4H,1-2,5-6H2

HIDE SMILES / InChI

Molecular Formula	C6H10
Molecular Weight	82.1436
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
Insight into the phase equilibrium phenomena of systems containing dienes and dicyanamide ionic liquids as a new potential application.	2010-12-02	21062074
(2SR,3SR)-Isopropyl 3-{[dimeth-yl(phenyl)-sil-yl]meth-yl}-2-hy-droxy-2-vinyl-pent-4-enoate.	2010-11-06	21589408
On the relationship between structure and reaction rate in olefin ring-closing metathesis.	2010-10-14	20820538
Metalla-cope rearrangements: bridging organic and inorganic chemistry.	2010-08-26	20192222
Cyclopolymerization of Nonconjugated Dienes with a Tridentate Phenoxyamine Hafnium Complex Supported by an sp(3) -C Donor: Isotactic Enchainment and Diastereoselective cis-Ring Closure.	2009-11-19	21638472
ESIMS studies and calculations on alkali-metal adduct ions of ruthenium olefin metathesis catalysts and their catalytic activity in metathesis reactions.	2009-10-19	19760711
Asymmetric Rh-catalyzed intermolecular hydroacylation of 1,5-hexadiene with salicylaldehyde.	2009-10	19801881
QTAIM study on the degenerate cope rearrangements of 1,5-hexadiene and semibullvalene.	2009-04-02	19275139
Synchrotron photoionization mass spectrometry measurements of kinetics and product formation in the allyl radical (H2CCHCH2) self-reaction.	2008-10-02	18702479
Structure-activity relationship (SAR) for the gas-phase ozonolysis of aliphatic alkenes and dialkenes.	2008-04-07	18350181
Structure and reaction mechanism of basil eugenol synthase.	2007-10-03	17912370
Calculational and experimental investigations of the pressure effects on radical-radical cross combination reactions: C2H5+C2H3.	2007-07-26	17585737
Allylic hydrogen abstraction II. H-abstraction from 1,4 type polyalkenes as a model for free radical trapping by polyunsaturated fatty acids (PUFAs).	2007-04-28	17431521
Studies of the electron-promoted cope cyclization of 2,5-phenyl-substituted 1,5-hexadiene radical anions.	2007-01-19	17221966
Diastereomerically-specific zirconium complexes of chiral salan ligands: isospecific polymerization of 1-hexene and 4-methyl-1-pentene and cyclopolymerization of 1,5-hexadiene.	2006-10-11	17017780
Primary mechanism of the thermal decomposition of tricyclodecane.	2006-10-05	17004739
One-pot synthesis of polysaccharide 3,5-dimethylphenylcarbamates having a random vinyl group for immobilization on silica gel as chiral stationary phases.	2006-07	16894788
Aquasonolysis of thioethers.	2006-05	16039900
Influence of vinyl monomers and temperature on immobilization of cellulose 3,5-dimethylphenylcarbamate onto silica gel as chiral stationary phases for high-performance liquid chromatography.	2006-02-03	16359692
A joint study based on the electron localization function and catastrophe theory of the chameleonic and centauric models for the Cope rearrangement of 1,5-hexadiene and its cyano derivatives.	2005-11-15	16082660
Balancing dynamic and nondynamic correlation for diradical and aromatic transition states: a renormalized coupled-cluster study of the cope rearrangement of 1,5-hexadiene.	2005-03-02	15725016
New ligand systems incorporating two and three 4,4'-bipyridine units. Characterization of bi- and trimetallic rhodium and iridium complexes.	2004-11-01	15500357
Hydrosilylation of dienes by yttrium hydrido complexes containing a linked amido-cyclopentadienyl ligand.	2004-08-07	15278114
Catalytic reduction of acetone by [(bpy)Rh]+: a theoretical mechanistic investigation and insight into cooperativity effects in this system.	2003-09-17	16220966
Dissociative and associative mechanisms of cope rearrangements of fluorinated 1,5-hexadienes and 2,2'-bis-methylenecyclopentanes.	2003-06-04	12769581
Double-chelation-assisted Rh-catalyzed intermolecular hydroacylation.	2003-04-17	12688760
Insertion/isomerization polymerization of 1,5-hexadiene: synthesis of functional propylene copolymers and block copolymers.	2002-10-02	12296706
Conformation-dependent state selectivity in O-O cleavage of ONOONO: an "inorganic cope rearrangement" helps explain the observed negative activation energy in the oxidation of nitric oxide by dioxygen.	2002-08-14	12167043
Convergent approach to pumiliotoxin alkaloids. Asymmetric total synthesis of (+)-pumiliotoxins A, B, and 225F.	2002-08-09	12153249
Synthesis of [n]- and [n.n]cyclophanes by using Suzuki-Miyaura coupling.	2002-07-26	12126424
Preparation and cell growth inhibitory activity of [PtR(2)L(2)] (R=polyfluorophenyl, L(2)=diene, cyclohexane-1,2-diamine (chxn) or cis-(dimethyl sulfoxide)(2)) and the X-ray crystal structure of [Pt(C(6)F(5))(2)(cis-chxn)].	2002-04-28	12062134
Cyclocopolymerization: a mechanistic probe for dual-site alternating copolymerization of ethylene and alpha-olefins.	2002-04-24	11960429
Transition-metal-promoted reactions of boron hydrides. 17. Titanium-catalyzed decaborane-olefin hydroborations.	2001-12-12	11734022
The structure of ionized 1,5 hexadiene in the gas phase.	2001-07	11444607
The effect of rigidity, shape, unsaturation, and length on the anesthetic potency of hydrocarbons.	2001-06	11375829

Substance Class	Chemical Created by `admin` on `Mon Mar 31 18:55:53 GMT 2025` Edited by `admin` on `Mon Mar 31 18:55:53 GMT 2025`
Record UNII	4MTZ4764FI
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

1,5-HEXADIENE

Systematic Name

English

NSC-60690

Preferred Name

English

.ALPHA.,.OMEGA.-HEXADIENE

Common Name

English

DIALLYL

Common Name

English

BIALLYL

Common Name

English

Code System Code Type Description

PUBCHEM

11598