BINAP, (+)-

Details

Stereochemistry	ABSOLUTE
Molecular Formula	C44H32P2
Molecular Weight	622.6724
Optical Activity	NONE
Additional Stereochemistry	Yes
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0
Stereo Comments	AXIAL, R

SHOW SMILES / InChI

Structure Search

SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=C5C=CC=C6)P(C7=CC=CC=C7)C8=CC=CC=C8

InChI

InChIKey=MUALRAIOVNYAIW-UHFFFAOYSA-N

InChI=1S/C44H32P2/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38/h1-32H

HIDE SMILES / InChI

Molecular Formula	C44H32P2
Molecular Weight	622.6724
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
The preparation of bi-functional organophosphine oxides as potential antitumor agents.	2010-11	20832917
Synthesis, characterization, and catalytic properties of new electrophilic iridium(III) complexes containing the (R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl ligand.	2010-05-03	20361755
Origin of intense chiroptical effects in undecagold subnanometer particles.	2010-02-03	20050686
Synthesis and characterization of FePd magnetic nanoparticles modified with chiral BINAP ligand as a recoverable catalyst vehicle for the asymmetric coupling reaction.	2009-10-21	20449041
The hydrogenation/transfer hydrogenation network in asymmetric reduction of ketones catalyzed by [RuCl2(binap)(pica)] complexes.	2008-10-06	18792897
An unexpected possible role of base in asymmetric catalytic hydrogenations of ketones. Synthesis and characterization of several key catalytic intermediates.	2006-10-25	17044693
Chiroptical activity of BINAP-stabilized undecagold clusters.	2006-06-22	16800452
Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes.	2006-03-22	16536531
Preparation of an amphiphilic resin-supported BINAP ligand and its use for rhodium-catalyzed asymmetric 1,4-addition of phenylboronic acid in water.	2004-09-16	15355051
Construction of monomeric and polymeric porphyrin compartments by a Pd(II)-pyridine interaction and their chiral twisting by a BINAP ligand.	2003-02-07	12558435
How to turn the catalytic asymmetric hydroboration reaction of vinylarenes into a recyclable process.	2003-01-03	12506375
Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles.	2002-08-14	12167001
Pd-catalyzed asymmetric hydrogenation of alpha-fluorinated iminoesters in fluorinated alcohol: a new and catalytic enantioselective synthesis of fluoro alpha-amino acid derivatives.	2001-02-08	11428002

Patents

Substance Class	Chemical Created by `admin` on `Wed Apr 02 13:17:28 GMT 2025` Edited by `admin` on `Wed Apr 02 13:17:28 GMT 2025`
Record UNII	4F1X2F8NA3
Record Status	`Validated (UNII)`
Record Version

Download

Name

Type

Language

(+)-BINAP

Preferred Name

English

BINAP, (+)-

Common Name

English

PHOSPHINE, 1,1'-((1R)-(1,1'-BINAPHTHALENE)-2,2'-DIYL)BIS(1,1-DIPHENYL-

Common Name

English

(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENE

Common Name

English

(R)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL

Common Name

English

(R)-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL

Common Name

English

(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL

Common Name

English

(R)-(+)-BINAP

Common Name

English

BINAP (R)-(+)-FORM [MI]

Common Name

English

Code System Code Type Description

FDA UNII

4F1X2F8NA3