OXYFLUORFEN

Details

Stereochemistry	ACHIRAL
Molecular Formula	C15H11ClF3NO4
Molecular Weight	361.7
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

CCOC1=CC(OC2=CC=C(C=C2Cl)C(F)(F)F)=CC=C1[N+]([O-])=O

InChI

InChIKey=OQMBBFQZGJFLBU-UHFFFAOYSA-N

InChI=1S/C15H11ClF3NO4/c1-2-23-14-8-10(4-5-12(14)20(21)22)24-13-6-3-9(7-11(13)16)15(17,18)19/h3-8H,2H2,1H3

HIDE SMILES / InChI

Molecular Formula	C15H11ClF3NO4
Molecular Weight	361.7
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Description
Sources: http://pmep.cce.cornell.edu/profiles/extoxnet/metiram-propoxur/oxyfluorfen-ext.html | https://www.apparentag.com.au/documents/brochures/66891_APPARENT_OXYFLUORFEN_240_HERBICIDE_Booklet_1.pdf

Oxyfluorfen is a selective pre and post-emergent herbicide. It is a contact herbicide and light is required for it to affect target plants. Oxyfluorfen can be used on weed-free soil to prevent germination of a wide variety of weeds or it can be applied to existing weeds at seedling stage especially with a tank mix partner to increase the variety of weeds controlled and/or the length of residual control. Oxyfluorfen can also be added at a low rate as a ‘spike’ to glyphosate or paraquat and diquat/paraquat herbicides to improve knockdown. It is available in emulsifiable concentrate and granular formulations.

Approval Year

PubMed

Title	Date	PubMed
Herbicide-induced experimental variegate porphyria in mice: tissue porphyrinogen accumulation and response to porphyrogenic drugs.	1997 Oct-Nov	9431441
Resistance of a soybean cell line to oxyfluorfen by overproduction of mitochondrial protoporphyrinogen oxidase.	2001 Aug	11517729
Toxicological effects of the herbicide oxyfluorfen on acetylcholinesterase in two fish species: Oreochromis niloticus and Gambusia affinis.	2002	12046652
Degradation of oxyfluorfen by Azotobacter chroococcum (Beijerink).	2002 Aug	12107696
Weed control in rose-scented geranium (Pelargonium spp).	2002 Dec	12477000
Jasmonate is involved in the induction of tyrosine aminotransferase and tocopherol biosynthesis in Arabidopsis thaliana.	2002 Nov	12430028
[Determination of acetochlor and oxyfluorfen by capillary gas chromatography].	2002 Sep	16358708
Dissipation of the herbicide oxyfluorfen in subtropical soils and its potential to contaminate groundwater.	2003 Feb	12550092
Oxyfluorfen toxic effect on S. obliquus evaluated by different photosynthetic and enzymatic biomarkers.	2003 Nov	14708660
A point mutation of valine-311 to methionine in Bacillus subtilis protoporphyrinogen oxidase does not greatly increase resistance to the diphenyl ether herbicide oxyfluorfen.	2003 Oct	12941291
Effect of the herbicides oxadiazon and oxyfluorfen on phosphates solubilizing microorganisms and their persistence in rice fields.	2003 Oct	12919781
Weed control and persistence of two oxyfluorfen formulations in olive groves under non tillage conditions.	2004	15765564
Screening for estrogen and androgen receptor activities in 200 pesticides by in vitro reporter gene assays using Chinese hamster ovary cells.	2004 Apr	15064155
Surface retention and photochemical reactivity of the diphenylether herbicide oxyfluorfen.	2004 Mar-Apr	15074812
Pesticide patch test series for the assessment of allergic contact dermatitis among banana plantation workers in panama.	2004 Sep	15724348
Assessment of the plasma desorption time-of-flight mass spectrometry technique for pesticide adsorption and degradation on 'as-received' treated soil samples.	2005	16047317
Herbicidal and antioxidant responses of transgenic rice overexpressing Myxococcus xanthus protoporphyrinogen oxidase.	2005 May	15890521
[Experimental study on oxyfluorfen technical herbicides induced mutagenicity].	2006 Jun	16824348
Determination of diphenylether herbicides in water samples by solid-phase microextraction coupled to liquid chromatography.	2006 Nov	17313105
Effect of systemic herbicides on N2-fixing and phosphate solubilizing microorganisms in relation to availability of nitrogen and phosphorus in paddy soils of West Bengal.	2006 Nov	16630642
Evaluation of six pesticides leaching indexes using field data of herbicide application in Casablanca Valley, Chile.	2007	17849992
Optimization of separation and detection conditions for the multiresidue analysis of pesticides in grapes by comprehensive two-dimensional gas chromatography-time-of-flight mass spectrometry.	2008 May 9	18371973
Metabolism of nitrodiphenyl ether herbicides by dioxin-degrading bacterium Sphingomonas wittichii RW1.	2008 Oct 8	18778066
Pesticide extraction from table grapes and plums using ionic liquid based dispersive liquid-liquid microextraction.	2009 Dec	19779926
Pendimethalin and oxyfluorfen degradation under two irrigation conditions over four years application.	2009 May	19365748
Ionic liquid based dispersive liquid-liquid microextraction for the extraction of pesticides from bananas.	2009 Oct 23	19700165
Development of a sample preparation method for the analysis of current-use pesticides in sediment using gas chromatography.	2010 Feb	19798461
Enhanced dissipation of oxyfluorfen, ethalfluralin, trifluralin, propyzamide, and pendimethalin in soil by solarization and biosolarization.	2010 Feb 24	20112907
[Determination of biphenyl ether herbicides in water using HPLC with cloud-point extraction].	2010 Jan	20369492
Persistence and bioaccumulation of oxyfluorfen residues in onion.	2010 Mar	19238567
Impact of environmental chemicals on key transcription regulators and correlation to toxicity end points within EPA's ToxCast program.	2010 Mar 15	20143881
Overexpression of a specific soybean GmGSTU4 isoenzyme improves diphenyl ether and chloroacetanilide herbicide tolerance of transgenic tobacco plants.	2010 Oct 1	20638428
Comparative study of human and mouse pregnane X receptor agonistic activity in 200 pesticides using in vitro reporter gene assays.	2011 Feb 27	21115097
Environmental impact on vascular development predicted by high-throughput screening.	2011 Nov	21788198
Assessment of possible carcinogenicity of oxyfluorfen to humans using mode of action analysis of rodent liver effects.	2012 Aug	22539621

Patents

Substance Class	Chemical Created by `admin` on `Fri Dec 15 18:33:14 GMT 2023` Edited by `admin` on `Fri Dec 15 18:33:14 GMT 2023`
Record UNII	46GY4Y6567
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

OXYFLUORFEN

Common Name

English

RH 2915

Code

English

2-CHLORO-4-TRIFLUOROMETHYLPHENYL 3-ETHOXY-4-NITROPHENYL ETHER

Systematic Name

English

2'-CHLORO-3-ETHOXY-4'-TRIFLUOROMETHYL-4-NITRODIPHENYL ETHER

Common Name

English

GOAL

Brand Name

English

OXYGOLD

Brand Name

English

KOLTAR

Brand Name

English

GALIGAN

Brand Name

English

RH-2915

Code

English

BENZENE, 2-CHLORO-1-(3-ETHOXY-4-NITROPHENOXY)-4-(TRIFLUOROMETHYL)-

Systematic Name

English

OXYFLUORFEN [ISO]

Common Name

English

OXYFLUORFEN [MI]

Common Name

English

RH 2915D

Code

English

4-TRIFLUOROMETHYL-2-CHLORO-3'-ETHOXY-4'-NITROPHENYL ETHER

Common Name

English

RH-2915D

Code

English

2-CHLORO-1-(3-ETHOXY-4-NITROPHENOXY)-4-(TRIFLUOROMETHYL)BENZENE

Systematic Name

English

OXYFLUORFEN [HSDB]

Common Name

English

2-CHLORO-.ALPHA.,.ALPHA.,.ALPHA.-TRIFLUORO-P-TOLYL 3-ETHOXY-4-NITROPHENYL ETHER

Common Name

English

Classification Tree Code System Code

EPA PESTICIDE CODE

111601