2,2,6,6-TETRAMETHYLPIPERIDINE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C9H19N
Molecular Weight	141.2539
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure of 2,2,6,6-TETRAMETHYLPIPERIDINE

Structure Search

SMILES

CC1(C)CCCC(C)(C)N1

InChI

InChIKey=RKMGAJGJIURJSJ-UHFFFAOYSA-N

InChI=1S/C9H19N/c1-8(2)6-5-7-9(3,4)10-8/h10H,5-7H2,1-4H3

HIDE SMILES / InChI

Molecular Formula	C9H19N
Molecular Weight	141.2539
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
Monocyclic zwitterionic lambda(5)Si-silicates with an SiO(2)FC(2) framework: syntheses and structural characterization in the solid state and in solution.	2001 May 21	11350229
Synthesis of meso-substituted chlorins via tetrahydrobilene-a intermediates.	2001 Nov 2	11681947
Deciphering the mechanistic dichotomy in the cyclization of 1-(2-ethynylphenyl)-3,3-dialkyltriazenes: competition between pericyclic and pseudocoarctate pathways.	2002 Nov 13	12418899
Carbolithiation of aromatic rings: cyclohexadienes from N-aroyl-2,2,6,6-tetramethylpiperidines.	2002 Sep 21	12357813
Effect of psoralens on Fenton-like reaction generating reactive oxygen species.	2003	12400092
A novel P450-catalyzed transformation of the 2,2,6,6-tetramethyl piperidine moiety to a 2,2-dimethyl pyrrolidine in human liver microsomes: characterization by high resolution quadrupole-time-of-flight mass spectrometry and 1H-NMR.	2003 Feb	12527703
Scavenging of reactive oxygen species by some nonsteroidal anti-inflammatory drugs and fenofibrate.	2006 Jun 5	16245331
Catalytic enantioselective synthesis of chiral phthalides by SmI2-mediated reductive cyclization of 2-acylarylcarboxylates.	2006 May 3	16637615
Intramolecular cyclopropanation of unsaturated terminal epoxides and chlorohydrins.	2007 Apr 11	17373790
Boron-pnictogen multiple bonds: donor-stabilized P=B and As=B bonds and a hindered iminoborane with a B-N triple bond.	2007 Apr 16	17338516
UVA photoirradiation of anhydroretinol--formation of singlet oxygen and superoxide.	2007 Nov	18717521
Aldosterone-induced increases in superoxide production counters nitric oxide inhibition of epithelial Na channel activity in A6 distal nephron cells.	2007 Nov	17804482
On the kinetic and thermodynamic reactivity of lithium di(alkyl)amidozincate bases in directed ortho metalation.	2007 Oct 24	17910445
Coupling into the base pair stack is necessary for DNA-mediated electrochemistry.	2007 Sep-Oct	17580927
2,2,6,6-Tetra-methyl-piperidinium penta-chloro-benzene-thiol-ate.	2008 Aug 20	21201761
2,2,6,6-tetramethylpiperidinogallium as a terminal and bridging ligand in homo- and heteroleptic chromium, nickel, and cobalt complexes.	2008 Dec 1	18975940
Using a two-step hydride transfer to achieve 1,4-reduction in the catalytic hydrogenation of an acyl pyridinium cation.	2008 Dec 19	18986202
A 140 GHz prepolarizer for dissolution dynamic nuclear polarization.	2008 Jun 28	18601309
UVA photoirradiation of oxygenated benz[a]anthracene and 3-methylcholanthene--generation of singlet oxygen and induction of lipid peroxidation.	2008 Mar	18441402
Diffusion of 2,2,6,6-tetramethylpiperidine 1-oxyl derivatives of variable hydrophobicity in tropocollagen I solution.	2008 Nov	18805068
Molecular tweezers for hydrogen: synthesis, characterization, and reactivity.	2008 Oct 29	18826306
Regio- and chemoselective metalation of chloropyrimidine derivatives with TMPMgCl x LiCl and TMP(2)Zn x 2 MgCl(2) x 2 LiCl.	2009	19115285
Alkyl-substituted amides as ligands in homometallic and heterobimetallic calcium complexes.	2009 Jan 5	19053338
Photoreduction of oxoisoaporphines by amines: laser flash and steady-state photolysis, pulse radiolysis, and TD-DFT studies.	2009 Jul 9	19505106
2,2,6,6-Tetra-methyl-piperidinium triisopropoxysilanethiol-ate.	2009 Oct 23	21578416
Deprotonative metalation of functionalized aromatics using mixed lithium-cadmium, lithium-indium, and lithium-zinc species.	2009 Oct 5	19688794
Hand-held mass spectrometer for environmentally relevant analytes using a variety of sampling and ionization methods.	2010	20065521
Tandem frustrated Lewis pair/tris(pentafluorophenyl)borane-catalyzed deoxygenative hydrosilylation of carbon dioxide.	2010 Aug 11	20681691
Mesoscale spatial distribution of electron spins studied by time-resolved small-angle and ultrasmall-angle neutron scattering with dynamic nuclear polarization: a case of 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO) doped in high-density polyethylene.	2010 Aug 7	20707539
Frequency dependent study of the correlation functions in EPR spectroscopy--The Cole-Davidson approach. II. 2,N-(4-n-Butyl benzilidene) 4-amino 2,2,6,6-tetramethyl piperidine 1-oxide in toluene.	2010 Nov	20843735
The influence of pre-emptive analgesia on postoperative analgesia and its objective evaluation.	2010 Oct	22419937

Patents

Substance Class	Chemical Created by `admin` on `Fri Dec 15 17:45:11 GMT 2023` Edited by `admin` on `Fri Dec 15 17:45:11 GMT 2023`
Record UNII	44N9S1YCFM
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

2,2,6,6-TETRAMETHYLPIPERIDINE

Systematic Name

English

TNV 622

Brand Name

English

NSC-102838

Code

English

PIPERIDINE, 2,2,6,6-TETRAMETHYL-

Systematic Name

English

NORPEMPIDINE

Common Name

English

Code System Code Type Description

MESH

C551336