Triphenylphosphine

Details

Stereochemistry	ACHIRAL
Molecular Formula	C18H15P
Molecular Weight	262.2855
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3

InChI

InChIKey=RIOQSEWOXXDEQQ-UHFFFAOYSA-N

InChI=1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H

HIDE SMILES / InChI

Molecular Formula	C18H15P
Molecular Weight	262.2855
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
The Sonogashira coupling reaction catalyzed by ultrafine nickel(0) powder.	2004-03-07	14973584
Synthesis of optically pure highly functionalized gamma-lactams via 2-azetidinone-tethered iminophosphoranes.	2004-02-06	14750838
Direct synthesis of sulfonamides and activated sulfonate esters from sulfonic acids.	2004-02-04	14746462
Rhodium-catalyzed methylenation of aldehydes.	2004-01-14	14709098
Synthesis, spectroscopic characterization, redox properties and catalytic activity of some ruthenium(II) complexes containing aromatic aldehyde and triphenylphosphine or triphenylarsine.	2004-01	14670468
Stereoselective synthesis of stannyl enones via palladium-catalyzed and free radical hydrostannation of alkynyl ketones with trineophyltin hydride.	2003-12-26	14682704
A non-radical chain mechanism for oxygen atom transfer with a thiorhenium(V) catalyst.	2003-12-15	14658859
Direct radical polymerization of 4-styryldiphenylphosphine: preparation of cross-linked and non-cross-linked triphenylphosphine-containing polystyrene polymers.	2003-12-12	14656118
Direct kinetic studies of atom transfer and electron transfer reactions of hydroperoxo and high-valent oxo complexes of chromium.	2003-12-03	14640640
Phosphine coordination complexes of the diphenylphosphenium cation: a versatile synthetic methodology for P-P bond formation.	2003-11-26	14624588
Role of carboxylate bridges in modulating nonheme diiron(II)/O(2) reactivity.	2003-11-17	14606847
A novel sulfonamidoglycosylation of glycals.	2003-11-13	14602037
Measurement of plasma hydroperoxide concentration by FOX-1 assay in conjunction with triphenylphosphine.	2003-11	14568191
A formal total synthesis of the salicylihalamides.	2003-10-17	14535794
Thermodynamic hydride donor abilities of [HW(CO)4L]- complexes (L = PPh3, P(OMe)3, CO) and their reactions with [C5Me5Re(PMe3)(NO)(CO)]+.	2003-10-08	14519008
[1,3-Bis(4-nitrophenyl)triazenido](triphenylphosphine)gold(I).	2003-10	14532661
Thermally induced stoichiometric and catalytic O-atom transfer by a non-heme iron(III)-nitro complex: first example of reversible [Fe-NO]7<-->FeIII-NO2 transformation in the presence of dioxygen.	2003-09-29	14520754
Kinetics and mechanism of rhenium-catalyzed O atom transfer from epoxides.	2003-09-10	12952483
Capillary electrophoresis with laser induced-fluorescence detection of profens derivatized with the water-soluble fluorogenic reagent 4-N-(4-N'-aminoethyl)piperazino-7-nitro-2,1,3-benzoxadiazole.	2003-09-05	14518776
Crystal structure of trans-dibromobis(triphenylphosphine)platinum(II).	2003-09	14516093
Chemical fixation of carbon dioxide by NaI/PPh3/PhOH.	2003-08-22	12919036
The Hendrickson reagent and the Mitsunobu reaction: a mechanistic study.	2003-08-21	12968348
Crystal structures and vibrational and solution and solid-state (CPMAS) NMR spectroscopic studies in triphenyl phosphine, arsine, and stibine silver(I) bromate systems, (R3E)xAgBrO3 (E = P, As, Sb; x = 1-4).	2003-08-11	12895118
Efficient and stereoselective synthesis of beta-trifluoromethyl alpha,beta-unsaturated esters via iron(III) porphyrin-catalyzed olefination of ketones.	2003-07-25	12868927
An easy access to halide ion-catalytic alpha-glycosylation using carbon tetrabromide and triphenylphosphine as multifunctional reagents.	2003-07-21	12956070
Acid-promoted olefination of ketones by an iron(III) porphyrin complex.	2003-07-10	12841763
An improved procedure for the preparation of 8-substituted guanines.	2003-06-21	12841287
On the regiochemistry of nucleophilic attack on 2-halo pi-allyl complexes. 4. The effect of silver acetate and nucleophile concentrations in competitive nucleophilic attack with malonate and phenoxide nucleophiles.	2003-05-16	12737572
Iron(III) and ruthenium(II) porphyrin complex-catalyzed selective olefination of aldehydes with ethyl diazoacetate.	2003-05-02	12713386
Progress in the palladium-catalyzed cyanation of aryl chlorides.	2003-04-14	12698441
(eta2-tetracyanoethene)bis(triphenylphosphine-kappaP)palladium-dichloromethane (1/0.7).	2003-04	12682392
Synthesis and spectroelectrochemical studies of mixed heteroleptic chelate complexes of ruthenium(II) with 1,8-bis(2-pyridyl)-3,6-dithiaoctane (pdto) and substituted 1,10-phenanthrolines.	2003-03-24	12639114
Regioselective reductive coupling of alkynes and aldehydes leading to allylic alcohols.	2003-03-06	12605482
A thermally stable and sterically unprotected terminal electrophilic phosphinidene complex of cobalt and its conversion to an eta(1)-phosphirene.	2003-03-05	12603123
Synthesis of p, p'-divinylazobenzene.	2003-03	12651252
A mono-diazenide complex from perrhenate: toward a new core for rhenium radiopharmaceuticals.	2003-02-24	12588118
Specificity of the ferrous oxidation of xylenol orange assay: analysis of autoxidation products of cholesteryl arachidonate.	2003-02-15	12605870
Aerobic oxidations catalyzed by chromium corroles.	2003-02-05	12553806
Template synthesis of benzannulated N-heterocyclic carbene ligands.	2003-02-03	12569463
Distributions of hydroperoxide positional isomers generated by oxidation of 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine in liposomes and in methanol solution.	2003-01	12669821
End-group analysis of blue light-emitting polymers using matrix-assisted laser desorption/ ionization time-of-flight mass spectrometry.	2002-12-15	12510746
Solid-phase synthesis of amine-bridged cyclic enkephalin analogues via on-resin cyclization utilizing the Fukuyama-Mitsunobu reaction.	2002-12-13	12467394
Design and synthesis of a hydrophilic fluorescent derivatization reagent for carboxylic acids, 4-N-(4-N-aminoethyl)piperazino-7-nitro-2,1,3-benzoxadiazole (NBD-PZ-NH2), and its application to capillary electrophoresis with laser-induced fluorescence detection.	2002-12	12474216
One-step synthesis of non-anomeric sugar isothiocyanates from sugar azides.	2002-11-19	12433497
Asymmetric synthesis of 2H-azirines derived from phosphine oxides using solid-supported amines. Ring opening of azirines with carboxylic acids.	2002-10-18	12375955
High-pressure vibrational study of the catalyst candidate cis-dimercaptobis(triphenylphosphine)platinum(II), cis-[(Ph3P)2Pt(SH)2].	2002-10	12396040
Stoichiometric and catalytic oxygen activation by trimesityliridium(III).	2002-09-09	12206710
EPR spectra from "EPR-silent" species: high-frequency and high-field EPR spectroscopy of pseudotetrahedral complexes of nickel(II).	2002-08-26	12184765
Synthesis and in vitro studies of novel pyrimidinyl peptidomimetics as potential antimalarial therapeutic agents.	2002-08-01	12139460
Direct evidence for a ruthenium(IV) oxo complex-mediated oxidation of a hydroxamic acid in the presence of phosphine oxide donors.	2001-09-21	12240327

Patents

Substance Class	Chemical Created by `admin` on `Mon Mar 31 19:23:33 GMT 2025` Edited by `admin` on `Mon Mar 31 19:23:33 GMT 2025`
Record UNII	26D26OA393
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

Triphenylphosphine

Systematic Name

English

NSC-10

Preferred Name

English

TRIPHENYL PHOSPHINE

Systematic Name

English

TRIPHENYLPHOSPHINE [HSDB]

Common Name

English

NSC-215203

Code

English

TRIPHENYLPHOSPHINE [MI]

Common Name

English

Code System Code Type Description

WIKIPEDIA

TRIPHENYLPHOSPHINE