Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C8H6 |
| Molecular Weight | 102.1332 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
C#CC1=CC=CC=C1
InChI
InChIKey=UEXCJVNBTNXOEH-UHFFFAOYSA-N
InChI=1S/C8H6/c1-2-8-6-4-3-5-7-8/h1,3-7H
| Molecular Formula | C8H6 |
| Molecular Weight | 102.1332 |
| Charge | 0 |
| Count |
|
| Stereochemistry | ACHIRAL |
| Additional Stereochemistry | No |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Optical Activity | NONE |
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Strained, stable 2-aza-1-phosphabicyclo[n.1.0]alkane and -alkene Fe(CO)4 complexes with dynamic phosphinidene behavior. | 2005-06-06 |
|
| Towards a better understanding of magnetic interactions within m-phenylene alpha-nitronyl nitroxide and imino nitroxide based radicals, part III: Magnetic exchange in a series of triradicals and tetraradicals based on the phenyl acetylene and biphenyl coupling units. | 2005-04-08 |
|
| Cooperative metal-boron interactions in the reaction of nido-1,2-(Cp*RuH)2B3H7, Cp* = eta5-C5Me5, with HC(triple bond)CPh. | 2005-04-06 |
|
| Length dependent folding kinetics of phenylacetylene oligomers: structural characterization of a kinetic trap. | 2005-03-22 |
|
| Effect of cyclodextrin complexation in bromine addition to unsymmetrical olefins: evidence for participation of cyclodextrin hydroxyl groups. | 2005-03-21 |
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| Enantioselective esterification of prochiral phosphonate pendants of a polyphenylacetylene assisted by macromolecular helicity: storage of a dynamic macromolecular helicity memory. | 2005-03-09 |
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| Highly enantioselective phenylacetylene addition to aromatic ketones catalyzed by cinchona alkaloid-aluminum complexes. | 2005-02-04 |
|
| Helical arrays of pendant fullerenes on optically active poly(phenylacetylene)s. | 2005-02-04 |
|
| Ultrasound-promoted alkynylation of ethynylbenzene to ketones under solvent-free condition. | 2005-02 |
|
| A family of alkynylgold(III) complexes [AuI(mu-{CH2}2PPh2)2Au(III)(C triple bond CR)2] (R = Ph, tBu, Me3Si): facile and reversible comproportionation of gold(I)/gold(III) to digold(II). | 2005-01-26 |
|
| Preparation of tertiary alkyl carbinamines, propargylamines, and alpha-heteroarylamines by ketone-based aminoalkylation. | 2005-01-07 |
|
| Phosphaallyl complexes of Ru(II) derived from dicyclohexylvinylphosphine (DCVP). | 2005-01-07 |
|
| Catalytic enantioselective alkynylation of prochiral sp3 C-H bonds adjacent to a nitrogen atom. | 2004-12-23 |
|
| pH-selective synthesis and structures of alkynyl, acyl, and ketonyl intermediates in anti-Markovnikov and Markovnikov hydrations of a terminal alkyne with a water-soluble iridium aqua complex in water. | 2004-12-22 |
|
| Surface reaction of alkynes and alkenes with H-Si(111): a density functional theory study. | 2004-12-08 |
|
| Mono- and binuclear cyclometallated palladium(II) complexes containing bridging (N,O-) and terminal (N-) imidate ligands: air stable, thermally robust and recyclable catalysts for cross-coupling processes. | 2004-12-07 |
|
| Marked effect of aromatic solvent on unfolding rate of helical ethynylhelicene oligomer. | 2004-11-17 |
|
| Highly enantioselective phenylacetylene additions to ketones catalyzed by (S)-BINOL-Ti complex. | 2004-11-11 |
|
| BINOL catalyzed enantioselective addition of titanium phenylacetylide to aromatic ketones. | 2004-11-07 |
|
| One-flask synthesis of mono- and trifunctionalized 21-thia and 21-oxaporphyrin building blocks and their application in the synthesis of covalent and noncovalent unsymmetrical porphyrin arrays. | 2004-10-01 |
|
| Catalytic efficiency of a new tridentate ferrocenyl phosphine auxiliary: Sonogashira cross-coupling reactions of alkynes with aryl bromides and chlorides at low catalyst loadings of 10(-1) to 10(-4) mol %. | 2004-09-30 |
|
| Macromolecular helicity induction on a poly(phenylacetylene) with C2-symmetric chiral [60]fullerene-bisadducts. | 2004-09-22 |
|
| Self-assembling of helical poly(phenylacetylene) carrying L-valine pendants in solution, on mica substrate, and on water surface. | 2004-08-31 |
|
| Poly(phenylacetylene)s bearing a peptide pendant: helical conformational changes of the polymer backbone stimulated by the pendant conformational change. | 2004-08-20 |
|
| 2-pyrones possessing antimicrobial and cytotoxic activities. | 2004-08-01 |
|
| Model of the iron hydrogenase active site covalently linked to a ruthenium photosensitizer: synthesis and photophysical properties. | 2004-07-26 |
|
| Ruthenium-catalyzed cyclization of epoxide with a tethered alkyne: formation of ketene intermediates via oxygen transfer from epoxides to terminal alkynes. | 2004-06-09 |
|
| Structural and rate studies of the 1,2-additions of lithium phenylacetylide to lithiated quinazolinones: influence of mixed aggregates on the reaction mechanism. | 2004-05-05 |
|
| Highly enantioselective addition of phenylacetylene to aldehydes catalyzed by a camphorsulfonamide ligand. | 2004-04-15 |
|
| Synthesis and structural characterization of an azatitanacyclobutene: the key intermediate in the catalytic anti-Markovnikov addition of primary amines to [small alpha]-alkynes. | 2004-03-21 |
|
| A helical array of pendant fullerenes on a helical poly(phenylacetylene) induced by non-covalent chiral interactions. | 2004-03-21 |
|
| BINOL-Salen-catalyzed highly enantioselective alkyne additions to aromatic aldehydes. | 2004-03-18 |
|
| Platinum participation in the hydrogenation of phenylacetylene by Ru5(CO)15(C)[Pt(PBu(t)3)]. | 2004-03-17 |
|
| Photoswitchable flexible and shape-persistent dendrimers: comparison of the interplay between a photochromic azobenzene core and dendrimer structure. | 2004-02-25 |
|
| Preparation and characterization of an isometallabenzene with the structure of a 1,2,4-cyclohexatriene. | 2004-02-25 |
|
| Vinyl and carbene ruthenium(II) complexes from hydridoruthenium(II) precursors. | 2004-02-07 |
|
| The Pd(4)(dppm)(4)(H)(2)(2+) cluster: a precatalyst for the homogeneous hydrogenation of alkynes. | 2004-01-26 |
|
| Insertion of alkynes into the Pt-Si bond of silylplatinum complexes leading to the formation of 4-sila-3-platinacyclobutenes and 5-sila-2-platina-1,4-cyclohexadienes. | 2004-01-23 |
|
| Study on the heteroatom influence in pyridine-based nitronyl nitroxide biradicals with phenylethynyl spacers on the molecular ground state. | 2003-12-26 |
|
| Photolysis of regioisomeric diazides of 1,2-diphenylacetylenes studies by matrix-isolation spectroscopy and DFT calculations. | 2003-12-21 |
|
| Highly enantioselective addition of phenylacetylene to aldehydes catalyzed by a beta-sulfonamide alcohol-titanium complex. | 2003-12-01 |
|
| Oxidative addition of phenylacetylene through C-H bond cleavage to form the MgII-dpp-bian complex: molecular structure of [Mg[dpp-bian(H)](C[triplebond]CPh)(thf)2] and its diphenylketone insertion product [Mg(dpp-bian)*-[OC(Ph2)C[triplebond]CPh](thf)]. | 2003-11-03 |
|
| Synthesis of nanostructures based on 1,4- and 1,3,5-ethynylphenyl subunits with pi-extended conjugation. Carbon dendron units. | 2003-10-17 |
|
| Facile preparation of optically pure 7,7'-disubstituted BINOLs and their application in asymmetric catalysis. | 2003-10-03 |
|
| Organometallic gold(III) compounds as catalysts for the addition of water and methanol to terminal alkynes. | 2003-10-01 |
|
| Functionalized amido ketones: new anticonvulsant agents. | 2003-09-15 |
|
| Synthesis and optical properties of unsymmetrical conjugated dendrimers focally anchored with perylenes in different geometries. | 2003-09-05 |
|
| Identification of impurities in phenylacetylene by species-selected mass-analyzed threshold ionization spectroscopy. | 2003-09 |
|
| Palladium-tetraphosphine complex: an efficient catalyst for the coupling of aryl halides with alkynes. | 2003-07-07 |
|
| Simultaneous chemical separation and surface-enhanced Raman spectral detection using silver-doped sol-gels. | 2003-04 |
Patents
| Substance Class |
Chemical
Created
by
admin
on
Edited
Mon Mar 31 19:55:29 GMT 2025
by
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| Record UNII |
239WSR2IBO
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| Record Status |
Validated (UNII)
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| Record Version |
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