BIPHENYLENE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C12H8
Molecular Weight	152.1919
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

C1=CC2=C(C=C1)C3=CC=CC=C23

InChI

InChIKey=IFVTZJHWGZSXFD-UHFFFAOYSA-N

InChI=1S/C12H8/c1-2-6-10-9(5-1)11-7-3-4-8-12(10)11/h1-8H

HIDE SMILES / InChI

Molecular Formula	C12H8
Molecular Weight	152.1919
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
A hot molecule as an intermediate in multiphoton reactions: first photoinduced reactions of biphenylene.	2001 Oct 17	11592909
Alkyl and aryl substituted corroles. 2. Synthesis and characterization of linked "face-to-face" biscorroles. X-ray structure of (BCA)Co(2)(py)(3), where BCA represents a biscorrole with an anthracenyl bridge.	2001 Sep 10	11531431
Electron-capture detector and multiple negative ions of aromatic hydrocarbons.	2002 Apr 5	12064529
Alkyl and aryl substituted corroles. 3. Reactions of cofacial cobalt biscorroles and porphyrin-corroles with pyridine and carbon monoxide.	2002 Jul 29	12132926
Highly efficient recognition of native TpT by artificial ditopic hydrogen-bonding receptors possessing a conformationally well-defined linkage.	2003 Feb 7	12558445
Alkyl- and aryl-substituted corroles. 5. Synthesis, physicochemical properties, and X-ray structural characterization of copper biscorroles and porphyrin-corrole dyads.	2004 Nov 15	15530095
Orientational control of electronic coupling in mixed-valence, binuclear ruthenium(II)-bis(2,2':6',2' '-terpyridine) complexes.	2004 Oct 27	15493916
Tris(benzocyclobutadieno)triphenylene and its lower biphenylene homologues by palladium-catalyzed cyclizations of 2,3-didehydrobiphenylene.	2004 Sep 30	15387547
Dynamic evolution of Kohn-Sham electron density in the real-time domain with finite basis expansion.	2005 Apr	15881581
The phane properties of anti-[2.2](1,4)biphenylenophane.	2005 Apr 29	15844991
Efficient C-F and C-C activation by a novel N-heterocyclic carbene-nickel(0) complex.	2005 Aug 19	15973748
Electrochemistry and spectroelectrochemistry of heterobimetallic porphyrin-corrole dyads. Influence of the spacer, metal ion, and oxidation state on the pyridine binding ability.	2005 Nov 28	16296858
Electrochemistry, spectroelectrochemistry, chloride binding, and O2 catalytic reactions of free-base porphyrin-cobalt corrole dyads.	2005 Sep 19	16156633
Intercepting palladacycles derived by C-H insertion. A mechanism-driven entry to heterocyclic tetraphenylenes.	2006 Jan 25	16417339
Regioselective [5,5]-sigmatropic rearrangement reactions of aryl hydrazides.	2006 May 11	16671778
Fast, through-bond mediated energy transfer from Ir(III) to Ru(II) in di- and tetranuclear heterometallic assemblies: elucidation of a two-step Ir --> Ir --> Ru energy transfer process.	2007 Apr	17404634
Ligand-field dependence of the excited state dynamics of Hangman bisporphyrin dyad complexes.	2007 Jul 19	17590036
On the destabilization (strain) energy of biphenylene.	2008 Aug 21	18661931
Mechanisms of molecular product and persistent radical formation from the pyrolysis of hydroquinone.	2008 Mar	18023845
Strain in biphenylene and some of its derivatives.	2008 Mar 20	18278889
4'-Hydroxy-biphenyl-4-carboxylic acid.	2008 May 17	21202602
Geometric and chelation influences on the electronic structure and optical properties of tetra(carboxylic acid)phenyleneethynylene dyes.	2008 May 8	18399673
Linker dependence of energy and hole transfer in neutral and oxidized multiporphyrin arrays.	2009 Dec 31	19961169
Synthesis and properties of oligophenylene-layered polymers.	2009 Jul 1	21706572
A reliable quantum-chemical protocol for the characterization of organic mixed-valence compounds.	2009 Nov 11	19831383
Solid-state molecular rotors with perdeuterated stators: mechanistic insights from biphenylene rotational dynamics in ordered and disordered crystal forms.	2010 Apr 16	20232842
Electronic properties of the biphenylene sheet and its one-dimensional derivatives.	2010 Aug 24	20669980
Variable products in dielectric-barrier discharge assisted benzene oxidation.	2010 Jun 15	20188466
Scope and limitations of accurate structure determination of solutes dissolved in liquid crystals.	2010 May 13	20405883
Correlations between local aromaticity indices of bipartite conjugated hydrocarbons.	2010 May 13	20397682
An overview of recent development in composite catalysts from porous materials for various reactions and processes.	2010 May 18	20559508
Common household chemicals and the allergy risks in pre-school age children.	2010 Oct 18	20976153
The electrical properties of biphenylenes.	2010 Sep 17	20722383

Substance Class	Chemical Created by `admin` on `Fri Dec 15 18:50:48 GMT 2023` Edited by `admin` on `Fri Dec 15 18:50:48 GMT 2023`
Record UNII	0Z64I7D5M2
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

BIPHENYLENE

Systematic Name

English

DIBENZOCYCLOBUTADIENE

Common Name

English

NSC-101862

Code

English

CYCLOBUTADIBENZENE

Common Name

English

DIPHENYLENE

Common Name

English

Code System Code Type Description

NSC

101862