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Details

Stereochemistry ACHIRAL
Molecular Formula C12H8
Molecular Weight 152.1919
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of BIPHENYLENE

SMILES

C1=CC2=C(C=C1)C3=CC=CC=C23

InChI

InChIKey=IFVTZJHWGZSXFD-UHFFFAOYSA-N
InChI=1S/C12H8/c1-2-6-10-9(5-1)11-7-3-4-8-12(10)11/h1-8H

HIDE SMILES / InChI

Molecular Formula C12H8
Molecular Weight 152.1919
Charge 0
Count
Stereochemistry ACHIRAL
Additional Stereochemistry No
Defined Stereocenters 0 / 0
E/Z Centers 0
Optical Activity NONE

Approval Year

PubMed

PubMed

TitleDatePubMed
Common household chemicals and the allergy risks in pre-school age children.
2010-10-18
The electrical properties of biphenylenes.
2010-09-17
Electronic properties of the biphenylene sheet and its one-dimensional derivatives.
2010-08-24
Variable products in dielectric-barrier discharge assisted benzene oxidation.
2010-06-15
An overview of recent development in composite catalysts from porous materials for various reactions and processes.
2010-05-18
Scope and limitations of accurate structure determination of solutes dissolved in liquid crystals.
2010-05-13
Correlations between local aromaticity indices of bipartite conjugated hydrocarbons.
2010-05-13
Structure and stereodynamics of aryldiimino derivatives.
2010-04-16
Solid-state molecular rotors with perdeuterated stators: mechanistic insights from biphenylene rotational dynamics in ordered and disordered crystal forms.
2010-04-16
Linker dependence of energy and hole transfer in neutral and oxidized multiporphyrin arrays.
2009-12-31
A reliable quantum-chemical protocol for the characterization of organic mixed-valence compounds.
2009-11-11
Synthesis and properties of oligophenylene-layered polymers.
2009-07-01
Flash-vacuum-pyrolytic reorganization of angular [4]phenylene.
2009-04-21
Mechanisms of product formation from the pyrolytic thermal degradation of catechol.
2008-09
On the destabilization (strain) energy of biphenylene.
2008-08-21
4'-Hydroxy-biphenyl-4-carboxylic acid.
2008-05-17
Geometric and chelation influences on the electronic structure and optical properties of tetra(carboxylic acid)phenyleneethynylene dyes.
2008-05-08
Strain in biphenylene and some of its derivatives.
2008-03-20
Mechanisms of molecular product and persistent radical formation from the pyrolysis of hydroquinone.
2008-03
Electronic spectroscopy of biphenylene inside helium nanodroplets.
2007-08-09
Ligand-field dependence of the excited state dynamics of Hangman bisporphyrin dyad complexes.
2007-07-19
Self-assembly and host-guest chemistry of a 3.5-nm coordination nanotube.
2007-04-02
Fast, through-bond mediated energy transfer from Ir(III) to Ru(II) in di- and tetranuclear heterometallic assemblies: elucidation of a two-step Ir --> Ir --> Ru energy transfer process.
2007-04
Regioselective [5,5]-sigmatropic rearrangement reactions of aryl hydrazides.
2006-05-11
Cobalt(IV) corroles as catalysts for the electroreduction of O2: reactions of heterobimetallic dyads containing a face-to-face linked Fe(III) or Mn(III) porphyrin.
2006-04
Intercepting palladacycles derived by C-H insertion. A mechanism-driven entry to heterocyclic tetraphenylenes.
2006-01-25
Electrochemistry and spectroelectrochemistry of heterobimetallic porphyrin-corrole dyads. Influence of the spacer, metal ion, and oxidation state on the pyridine binding ability.
2005-11-28
Iron-dependent lysosomal destabilization initiates silica-induced apoptosis in murine macrophages.
2005-11-15
Electrochemistry, spectroelectrochemistry, chloride binding, and O2 catalytic reactions of free-base porphyrin-cobalt corrole dyads.
2005-09-19
Efficient C-F and C-C activation by a novel N-heterocyclic carbene-nickel(0) complex.
2005-08-19
PECT model analysis and predictions of experimental collisional energy transfer probabilities P(E',E) and moments for azulene and biphenylene.
2005-05-05
The phane properties of anti-[2.2](1,4)biphenylenophane.
2005-04-29
Cobalt(III) corroles as electrocatalysts for the reduction of dioxygen: reactivity of a monocorrole, biscorroles, and porphyrin-corrole dyads.
2005-04-20
Dynamic evolution of Kohn-Sham electron density in the real-time domain with finite basis expansion.
2005-04
Alkyl- and aryl-substituted corroles. 5. Synthesis, physicochemical properties, and X-ray structural characterization of copper biscorroles and porphyrin-corrole dyads.
2004-11-15
Orientational control of electronic coupling in mixed-valence, binuclear ruthenium(II)-bis(2,2':6',2' '-terpyridine) complexes.
2004-10-27
Tris(benzocyclobutadieno)triphenylene and its lower biphenylene homologues by palladium-catalyzed cyclizations of 2,3-didehydrobiphenylene.
2004-09-30
Electrophilic aromatic substitution by the fluorofullerene C60F18.
2004-09-20
Highly efficient recognition of native TpT by artificial ditopic hydrogen-bonding receptors possessing a conformationally well-defined linkage.
2003-02-07
Alkyl and aryl substituted corroles. 3. Reactions of cofacial cobalt biscorroles and porphyrin-corroles with pyridine and carbon monoxide.
2002-07-29
Electron-capture detector and multiple negative ions of aromatic hydrocarbons.
2002-04-05
A hot molecule as an intermediate in multiphoton reactions: first photoinduced reactions of biphenylene.
2001-10-17
Alkyl and aryl substituted corroles. 2. Synthesis and characterization of linked "face-to-face" biscorroles. X-ray structure of (BCA)Co(2)(py)(3), where BCA represents a biscorrole with an anthracenyl bridge.
2001-09-10
Substance Class Chemical
Created
by admin
on Mon Mar 31 19:22:24 GMT 2025
Edited
by admin
on Mon Mar 31 19:22:24 GMT 2025
Record UNII
0Z64I7D5M2
Record Status Validated (UNII)
Record Version
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Name Type Language
NSC-101862
Preferred Name English
BIPHENYLENE
Systematic Name English
DIBENZOCYCLOBUTADIENE
Common Name English
CYCLOBUTADIBENZENE
Common Name English
DIPHENYLENE
Common Name English
Code System Code Type Description
NSC
101862
Created by admin on Mon Mar 31 19:22:24 GMT 2025 , Edited by admin on Mon Mar 31 19:22:24 GMT 2025
PRIMARY
CHEBI
33079
Created by admin on Mon Mar 31 19:22:24 GMT 2025 , Edited by admin on Mon Mar 31 19:22:24 GMT 2025
PRIMARY
FDA UNII
0Z64I7D5M2
Created by admin on Mon Mar 31 19:22:24 GMT 2025 , Edited by admin on Mon Mar 31 19:22:24 GMT 2025
PRIMARY
WIKIPEDIA
BIPHENYLENE
Created by admin on Mon Mar 31 19:22:24 GMT 2025 , Edited by admin on Mon Mar 31 19:22:24 GMT 2025
PRIMARY
EPA CompTox
DTXSID3059765
Created by admin on Mon Mar 31 19:22:24 GMT 2025 , Edited by admin on Mon Mar 31 19:22:24 GMT 2025
PRIMARY
PUBCHEM
9214
Created by admin on Mon Mar 31 19:22:24 GMT 2025 , Edited by admin on Mon Mar 31 19:22:24 GMT 2025
PRIMARY
CAS
259-79-0
Created by admin on Mon Mar 31 19:22:24 GMT 2025 , Edited by admin on Mon Mar 31 19:22:24 GMT 2025
PRIMARY