TRIETHYLSILANE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C6H16Si
Molecular Weight	116.2767
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

CC[SiH](CC)CC

InChI

InChIKey=AQRLNPVMDITEJU-UHFFFAOYSA-N

InChI=1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3

HIDE SMILES / InChI

Molecular Formula	C6H16Si
Molecular Weight	116.2767
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
Stereoselective synthesis of 4'-carbon-substituted xylofuranosyladenines.	2004	17150471
Synthesis of highly substituted allenylsilanes by alkylidenation of silylketenes.	2005 Aug 26	16542018
Construction of fused bis(pyran) units from enones via a hydrosilylation-dihydroxylation-acetalization-reduction sequence.	2006 Dec 28	17146519
Asymmetric modular synthesis of highly functionalized medium-sized carbocycles and lactones via ring-closing metathesis of sulfoximine-substituted trienes.	2006 Dec 6	17131996
Radical reduction of aromatic azides to amines with triethylsilane.	2006 Jul 21	16839176
BF3.2CF3CH2OH (BF3.2TFE), an efficient superacidic catalyst for some organic synthetic transformations.	2006 May 12	16674072
A tetracoordinated rhodium aminyl radical complex.	2006 May 24	16704256
Rh(I) and Ir(i) derivatives of a P(S),N-substituted indene ligand: synthetic, structural, and catalytic alkene hydrosilylation studies.	2006 May 29	16711707
Highly regio- and chemoselective ring opening of oxa-bridged piperidinones toward functionalized furanones and piperidines.	2006 Oct 26	17048853
Tris(trimethylsilyl)silane (TTMSS)-derived radical reactivity toward alkenes: a combined quantum mechanical and laser flash photolysis study.	2007 Aug 17	17658850
Pd-C-induced catalytic transfer hydrogenation with triethylsilane.	2007 Aug 17	17630799
A versatile synthesis for new 9,10-bis(4-alkoxyphenyl)-2,7-diiodophenanthrenes: useful precursors for conjugated polymers.	2007 Aug 2	17629293
Concerning the selective protection of (Z)-1,5-syn-ene-diols and (E)-1,5-anti-ene-diols as allylic triethylsilyl ethers.	2007 Dec 20	18027963
Synthesis of docetaxel and butitaxel analogues through kinetic resolution of racemic beta-lactams with 7-O-triethylsilylbaccatin III.	2007 Feb 2	17253791
Deprotection of a silyl group with mesoporous silica.	2007 Jun	17541182
Nucleophilic aromatic substitution using Et3SiH/cat. t-Bu-P4 as a system for nucleophile activation.	2007 Jun 14	17534511
Short synthesis of the C16-C28 polyketide fragment of apoptolidin A aglycone.	2007 Jun 21	17844763
Vinylogous Mukaiyama aldol reactions with 4-oxy-2-trimethylsilyloxypyrroles: relevance to castanospermine synthesis.	2007 Nov 3	17980041
Iridium-catalyzed reduction of alkyl halides by triethylsilane.	2007 Oct 24	17900122
Structural Development Studies of Subtype-Selective Ligands for Peroxisome Proliferator-Activated Receptors (PPARs) Based on the 3,4-Disubstituted Phenylpropanoic Acid Scaffold as a Versatile Template.	2008	18566690
(2+2) cycloaddition reaction of alkyl enol ethers with acrylates by in situ generated silyl triflic imide catalyst.	2008 Aug	18670130
One-pot synthesis of oligosaccharides by combining reductive openings of benzylidene acetals and glycosylations.	2008 Aug 7	18578494
Scope and mechanism of the iridium-catalyzed cleavage of alkyl ethers with triethylsilane.	2008 Dec 24	19053420
Triethylsilanol: molecular conformations and role of the hydrogen-bonding oligomerization in its vibrational spectra.	2008 Feb 21	18229903
Solid-supported nitroso hetero-Diels-Alder reactions. 3. Acid-mediated transformation of cycloadducts by scission of the oxazine C-O bonds.	2008 Jan-Feb	18067270
Synthetic efforts for stereo structure determination of cytotoxic marine natural product pericosines as metabolites of Periconia sp. from sea hare.	2008 Mar	19325758
(1R,1'R,3S,3'S)-5,5',10,10'-Tetra-meth-oxy-1,1',3,3'-tetra-methyl-3,3',4,4'-tetra-hydro-1H,1'H-8,8'-bi[benzo[g]isochromene].	2008 Mar 29	21202147
Synthesis and biological evaluation of a novel pentagastrin-toxin conjugate designed for a targeted prodrug mono-therapy of cancer.	2008 May	19325786
Total syntheses of (+)- and (-)-peribysin E.	2008 Oct 15	18783227
Triethylsilane as a mild and efficient reducing agent for the preparation of alkanethiol-capped gold nanoparticles.	2008 Sep 7	18726022
Application of triethylsilane and palladium-charcoal-induced reductions in the synthesis of Fmoc-glutamic acid analogues.	2009	19400150
Synthesis of 1,1-Dioxobenzo[b]thiophene-2-ylmethyloxycarbonyl (Bsmoc) protected N-methyl amino acids by reduction of Bsmoc-5-oxazoli-dinones and their use in peptide synthesis.	2009	19200031
Gas-phase reactivity of ruthenium carbonyl cluster anions.	2009 Apr	19185511
(S)-5-Hexyl-1-[(S)-2-hydr-oxy-1-phenyl-ethyl]-4-meth-oxy-1H-pyrrol-2(5H)-one.	2009 Apr 22	21583908
Inter- and intramolecular [4 + 3] cycloadditions using epoxy enol silanes as functionalized oxyallyl cation precursors.	2009 Apr 8	19281161
Photochemistry of cyclic trisilanes: "spring-loaded" precursors to methylphenylsilylene.	2009 Aug 24	19610002
Isolable photoreactive polysilyl radicals.	2009 Aug 26	19722593
The smallest and one of the brightest. Efficient preparation and optical description of the parent borondipyrromethene system.	2009 Aug 7	19572588
Stereoselective hydrogenation of aromatic alkynes using water, triethylsilane, or methanol, mediated and catalyzed by Ni(0) complexes.	2009 Jan 5	19111065
Indium-catalyzed reductive alkylation of pyrroles with alkynes and hydrosilanes: selective synthesis of beta-alkylpyrroles.	2009 May 21	19382768
Conformationally constrained analogues of diacylglycerol (DAG). 31. Modulation of the biological properties of diacylgycerol lactones (DAG-lactones) containing rigid-rod acyl groups separated from the core lactone by spacer units of different lengths.	2009 May 28	19379015
Chemoselective deprotection of triethylsilyl ethers.	2009 Nov	20183570
Preparation of iron and gold silicide nanodomains on silicon (111) by the reaction of gold, iron-gold core-shell, and alloy nanoparticles with triethylsilane.	2010 Aug	20735094
Tandem frustrated Lewis pair/tris(pentafluorophenyl)borane-catalyzed deoxygenative hydrosilylation of carbon dioxide.	2010 Aug 11	20681691
(RS)-1-[5-(2-Chloro-prop-yl)indolin-1-yl]ethanone.	2010 Dec 8	21522761
Iridium-catalyzed (Z)-trialkylsilylation of terminal olefins.	2010 Mar 5	20136153
2-[4-Chloro-3-(4-ethoxy-benz-yl)phen-yl]-1,3-dithiane.	2010 May 19	21579467
HIV-1 gp41 and TCRalpha trans-membrane domains share a motif exploited by the HIV virus to modulate T-cell proliferation.	2010 Sep 2	20824090
Controlled and chemoselective reduction of secondary amides.	2010 Sep 22	20735125
2,2'-(Propane-2,2-di-yl)dibenzothia-zole.	2010 Sep 8	21587514

Patents

Substance Class	Chemical Created by `admin` on `Sat Dec 16 03:46:37 GMT 2023` Edited by `admin` on `Sat Dec 16 03:46:37 GMT 2023`
Record UNII	0F9429873L
Record Status	`Validated (UNII)`
Record Version

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Name

Type

Language

TRIETHYLSILANE

Systematic Name

English

SILANE, TRIETHYL-

Systematic Name

English

TRIETHYLSILANE [MI]

Common Name

English

TRIETHYLHYDROSILANE

Common Name

English

NSC-93579

Code

English

TRIETHYLSILICON HYDRIDE

Systematic Name

English

Code System Code Type Description

EPA CompTox

DTXSID20870702