Triethylsilane

Details

Stereochemistry	ACHIRAL
Molecular Formula	C6H16Si
Molecular Weight	116.2767
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

CC[SiH](CC)CC

InChI

InChIKey=AQRLNPVMDITEJU-UHFFFAOYSA-N

InChI=1S/C6H16Si/c1-4-7(5-2)6-3/h7H,4-6H2,1-3H3

HIDE SMILES / InChI

Molecular Formula	C6H16Si
Molecular Weight	116.2767
Charge	0
Count

Stereochemistry	ACHIRAL
Additional Stereochemistry	No
Defined Stereocenters	0 / 0
E/Z Centers	0
Optical Activity	NONE

Approval Year

PubMed

Title	Date	PubMed
(RS)-1-[5-(2-Chloro-prop-yl)indolin-1-yl]ethanone.	2010-12-08	21522761
Controlled and chemoselective reduction of secondary amides.	2010-09-22	20735125
2,2'-(Propane-2,2-di-yl)dibenzothia-zole.	2010-09-08	21587514
HIV-1 gp41 and TCRalpha trans-membrane domains share a motif exploited by the HIV virus to modulate T-cell proliferation.	2010-09-02	20824090
Tandem frustrated Lewis pair/tris(pentafluorophenyl)borane-catalyzed deoxygenative hydrosilylation of carbon dioxide.	2010-08-11	20681691
Preparation of iron and gold silicide nanodomains on silicon (111) by the reaction of gold, iron-gold core-shell, and alloy nanoparticles with triethylsilane.	2010-08	20735094
2-[4-Chloro-3-(4-ethoxy-benz-yl)phen-yl]-1,3-dithiane.	2010-05-19	21579467
Iridium-catalyzed (Z)-trialkylsilylation of terminal olefins.	2010-03-05	20136153
Chemoselective deprotection of triethylsilyl ethers.	2009-11	20183570
Isolable photoreactive polysilyl radicals.	2009-08-26	19722593
Photochemistry of cyclic trisilanes: "spring-loaded" precursors to methylphenylsilylene.	2009-08-24	19610002
The smallest and one of the brightest. Efficient preparation and optical description of the parent borondipyrromethene system.	2009-08-07	19572588
Conformationally constrained analogues of diacylglycerol (DAG). 31. Modulation of the biological properties of diacylgycerol lactones (DAG-lactones) containing rigid-rod acyl groups separated from the core lactone by spacer units of different lengths.	2009-05-28	19379015
Indium-catalyzed reductive alkylation of pyrroles with alkynes and hydrosilanes: selective synthesis of beta-alkylpyrroles.	2009-05-21	19382768
(S)-5-Hexyl-1-[(S)-2-hydr-oxy-1-phenyl-ethyl]-4-meth-oxy-1H-pyrrol-2(5H)-one.	2009-04-22	21583908
Inter- and intramolecular [4 + 3] cycloadditions using epoxy enol silanes as functionalized oxyallyl cation precursors.	2009-04-08	19281161
Gas-phase reactivity of ruthenium carbonyl cluster anions.	2009-04	19185511
Stereoselective hydrogenation of aromatic alkynes using water, triethylsilane, or methanol, mediated and catalyzed by Ni(0) complexes.	2009-01-05	19111065
Application of triethylsilane and palladium-charcoal-induced reductions in the synthesis of Fmoc-glutamic acid analogues.	2009	19400150
Synthesis of 1,1-Dioxobenzo[b]thiophene-2-ylmethyloxycarbonyl (Bsmoc) protected N-methyl amino acids by reduction of Bsmoc-5-oxazoli-dinones and their use in peptide synthesis.	2009	19200031
Scope and mechanism of the iridium-catalyzed cleavage of alkyl ethers with triethylsilane.	2008-12-24	19053420
Total syntheses of (+)- and (-)-peribysin E.	2008-10-15	18783227
Triethylsilane as a mild and efficient reducing agent for the preparation of alkanethiol-capped gold nanoparticles.	2008-09-07	18726022
One-pot synthesis of oligosaccharides by combining reductive openings of benzylidene acetals and glycosylations.	2008-08-07	18578494
(2+2) cycloaddition reaction of alkyl enol ethers with acrylates by in situ generated silyl triflic imide catalyst.	2008-08	18670130
Synthesis and biological evaluation of a novel pentagastrin-toxin conjugate designed for a targeted prodrug mono-therapy of cancer.	2008-05	19325786
(1R,1'R,3S,3'S)-5,5',10,10'-Tetra-meth-oxy-1,1',3,3'-tetra-methyl-3,3',4,4'-tetra-hydro-1H,1'H-8,8'-bi[benzo[g]isochromene].	2008-03-29	21202147
Synthetic efforts for stereo structure determination of cytotoxic marine natural product pericosines as metabolites of Periconia sp. from sea hare.	2008-03	19325758
Triethylsilanol: molecular conformations and role of the hydrogen-bonding oligomerization in its vibrational spectra.	2008-02-21	18229903
Structural Development Studies of Subtype-Selective Ligands for Peroxisome Proliferator-Activated Receptors (PPARs) Based on the 3,4-Disubstituted Phenylpropanoic Acid Scaffold as a Versatile Template.	2008	18566690
Concerning the selective protection of (Z)-1,5-syn-ene-diols and (E)-1,5-anti-ene-diols as allylic triethylsilyl ethers.	2007-12-20	18027963
Solid-supported nitroso hetero-Diels-Alder reactions. 3. Acid-mediated transformation of cycloadducts by scission of the oxazine C-O bonds.	2007-12-11	18067270
Vinylogous Mukaiyama aldol reactions with 4-oxy-2-trimethylsilyloxypyrroles: relevance to castanospermine synthesis.	2007-11-03	17980041
Iridium-catalyzed reduction of alkyl halides by triethylsilane.	2007-10-24	17900122
Tris(trimethylsilyl)silane (TTMSS)-derived radical reactivity toward alkenes: a combined quantum mechanical and laser flash photolysis study.	2007-08-17	17658850
Pd-C-induced catalytic transfer hydrogenation with triethylsilane.	2007-08-17	17630799
A versatile synthesis for new 9,10-bis(4-alkoxyphenyl)-2,7-diiodophenanthrenes: useful precursors for conjugated polymers.	2007-08-02	17629293
Short synthesis of the C16-C28 polyketide fragment of apoptolidin A aglycone.	2007-06-21	17844763
Nucleophilic aromatic substitution using Et3SiH/cat. t-Bu-P4 as a system for nucleophile activation.	2007-06-14	17534511
Deprotection of a silyl group with mesoporous silica.	2007-06	17541182
Synthesis of docetaxel and butitaxel analogues through kinetic resolution of racemic beta-lactams with 7-O-triethylsilylbaccatin III.	2007-02-02	17253791
Construction of fused bis(pyran) units from enones via a hydrosilylation-dihydroxylation-acetalization-reduction sequence.	2006-12-28	17146519
Asymmetric modular synthesis of highly functionalized medium-sized carbocycles and lactones via ring-closing metathesis of sulfoximine-substituted trienes.	2006-12-06	17131996
Highly regio- and chemoselective ring opening of oxa-bridged piperidinones toward functionalized furanones and piperidines.	2006-10-26	17048853
Radical reduction of aromatic azides to amines with triethylsilane.	2006-07-21	16839176
Rh(I) and Ir(i) derivatives of a P(S),N-substituted indene ligand: synthetic, structural, and catalytic alkene hydrosilylation studies.	2006-05-29	16711707
A tetracoordinated rhodium aminyl radical complex.	2006-05-24	16704256
BF3.2CF3CH2OH (BF3.2TFE), an efficient superacidic catalyst for some organic synthetic transformations.	2006-05-12	16674072
Synthesis of highly substituted allenylsilanes by alkylidenation of silylketenes.	2005-08-26	16542018
Stereoselective synthesis of 4'-carbon-substituted xylofuranosyladenines.	2004	17150471

Patents

Substance Class	Chemical Created by `admin` on `Mon Mar 31 21:19:38 GMT 2025` Edited by `admin` on `Mon Mar 31 21:19:38 GMT 2025`
Record UNII	0F9429873L
Record Status	`Validated (UNII)`
Record Version

Download

Name

Type

Language

NSC-93579

Preferred Name

English

Triethylsilane

Systematic Name

English

SILANE, TRIETHYL-

Systematic Name

English

TRIETHYLSILANE [MI]

Common Name

English

TRIETHYLHYDROSILANE

Common Name

English

TRIETHYLSILICON HYDRIDE

Systematic Name

English

Code System Code Type Description

EPA CompTox

DTXSID20870702