ISOBUTYLENE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C4H8
Molecular Weight	56.1063
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

CC(C)=C

InChI

InChIKey=VQTUBCCKSQIDNK-UHFFFAOYSA-N

InChI=1S/C4H8/c1-4(2)3/h1H2,2-3H3

HIDE SMILES / InChI

Approval Year

PubMed

Title	Date	PubMed
Di-tert-butyl phosphate complexes of cobalt(II) and zinc(II) as precursors for ceramic M(PO3)2 and M2P2O7 materials: synthesis, spectral characterization, structural studies, and role of auxiliary ligands.	2001 Jan 29	11209598
Effect of ring size in R-(+)-pulegone-mediated hepatotoxicity: studies on the metabolism of R-(+)-4-methyl-2-(1-methylethylidene)-cyclopentanone and DL-camphorone in rats.	2001 Jun	11353750
Overview of isoprene monomer and polyisoprene production processes.	2001 Jun 1	11397389
Reactions of superoxo and oxo metal complexes with aldehydes. Radical-specific pathways for cross-disproportionation of superoxometal ions and acylperoxyl radicals.	2002 Aug 7	12149018
Reactivities of methylenetriangulanes and spirocyclopropanated bicyclopropylidenes toward bromine. Relative stabilities of spirocyclopropanated versus methyl-substituted bromonium ions.	2002 Jun 14	12054944
Synthesis and characterization of an air-stable gallium hydride, [t-Bu(H)Ga(mu-NEt(2))](2), and related chloride derivatives.	2002 Jun 3	12033900
Self-assembly of double stranded dinuclear titanium(IV)-Schiff base complexes and formation of intramolecular mu-oxo bridges.	2002 Mar 7	12120521
Synthesis of symmetrical trisubstituted olefins by cross metathesis.	2002 May 30	12027652
Gas-phase chemistry of bare and oxo-ligated protactinium ions: a contribution to a systematic understanding of actinide chemistry.	2002 Nov 4	12401099
Isolation and structure of [HC[CH(SiMe(3))(SnMe(3))](2)](+): a remarkably stable sec-alkyl cation.	2002 Sep 25	12236730
Crystal structure of 2-Se-(2-methyl-2-propenyl)-1-benzoic acid.	2003 Aug	12945687
Catalyst/cocatalyst nuclearity effects in single-site olefin polymerization. Significantly enhanced 1-octene and isobutene comonomer enchainment in ethylene polymerizations mediated by binuclear catalysts and cocatalysts.	2003 Sep 10	12952449
1H-1,3-diazepines, 5H-1,3-diazepines, 1,3-diazepinones, and 2,4-diazabicyclo[3.2.0]heptenes.	2004 Apr 21	15064802
Allyl, methallyl, prenyl, and methylprenyl ethers as protected alcohols: their selective cleavage with diphenyldisulfone under neutral conditions.	2004 Aug 5	15281746
Decomposition of alkene adducts of thianthrene cation radical in nitrile solvents. Formation of alkyl-2-oxazolines and a new class of four-component products: 5-[(1-alkoxyalkylidene)ammonio]alkylthianthrenium diperchlorates.	2004 Dec 24	15609964
Solvent-ligated manganese(II) complexes for the homopolymerization of isobutene and the copolymerization of isobutene and isoprene.	2004 Dec 3	15526318
Simple synthesis of a weak nucleophilic base (4-ethyl-2,6-diisopropyl-3,5-dimethylpyridine) evidencing a double Janus group effect.	2004 Jan 23	14725470
Vibrational relaxation in methyl hydrocarbons at high temperatures: propane, isobutene, isobutane, neopentane, and toluene.	2004 Jan 8	15267928
Room temperature olefins oligomerization over sulfated titania.	2004 Jul 7	15216349
A computational study of the role of hydrogen bonds in SN1 and E1 reactions.	2004 Mar	14735577
Reaction intermediates in acid catalysis by zeolites: prediction of the relative tendency to form alkoxides or carbocations as a function of hydrocarbon nature and active site structure.	2004 Mar 17	15012161
1-methylidenesqualene and 25-methylidenesqualene as active-site probes for bacterial squalene:hopene cyclase.	2004 Mar 4	14986979
Preparation of beta- and gamma-lactams from carbamoyl radicals derived from oxime oxalate amides.	2004 Mar 7	14985812
Photoinduced graft-copolymer synthesis and characterization of methacrylic acid onto natural biodegradable lignocellulose fiber.	2004 May-Jun	15132702
Cobalt-catalyzed cross-coupling reactions of alkyl halides with allylic and benzylic Grignard reagents and their application to tandem radical cyclization/cross-coupling reactions.	2004 Nov 5	15457521
Palladium(0)-catalyzed cyclization of electron-deficient enynes and enediynes.	2004 Oct 1	15387592
Field validation of sound mitigation models and air pollutant emission testing in support of missile motor disposal activities.	2005 Aug	16187581
A combined crossed-beam and theoretical investigation of radical-radical reaction dynamics of O(3P)+t-C4H9-->OH+iso-C4H8.	2005 Dec 1	16356032
Formation of a bridging planar trimethylenemethane dianion from a neopentyl precursor via sequential beta-alkyl elimination and C-H activation.	2005 Feb 2	15669823
Overall rate constant measurements of the reaction of chloroalkylperoxy radicals with nitric oxide.	2005 Jul 7	16833921
Differentiation of Boc- alpha,beta- and beta,alpha-peptides and a pair of diastereomeric beta,alpha-dipeptides by positive and negative ion electrospray tandem mass spectrometry (ESI-MS/MS).	2005 Nov	16220504
Identification of photoproducts of hexahydroquinoline derivatives by GC-EI-MS and HPLC-ESI-MS.	2005 Oct	16305997
Thermochemical and kinetic analyses on oxidation of isobutenyl radical and 2-hydroperoxymethyl-2-propenyl radical.	2005 Oct 13	16332010
Theoretical study of the heptamethylbenzenium ion. Intramolecular isomerizations and C2, C3, C4 alkene elimination.	2005 Oct 6	16834295
Probing the structural and electronic factors affecting the adsorption and reactivity of alkenes in acidic zeolites using DFT calculations and multivariate statistical methods.	2005 Sep-Oct	16180907
Controlled delivery of paclitaxel from stent coatings using poly(hydroxystyrene-b-isobutylene-b-hydroxystyrene) and its acetylated derivative.	2005 Sep-Oct	16153094
A theoretical investigation of the gas-phase oxidation reaction of the saturated tert-butyl radical.	2006 Dec 11	17091514
Rate coefficients for the gas-phase reaction of OH radicals with dimethyl sulfide: temperature and O2 partial pressure dependence.	2006 Feb 14	16482313
Low-pressure pyrolysis of tBu2SO: synthesis and IR spectroscopic detection of HSOH.	2006 Jan 11	16240313
Kinetic study of the gas-phase reactions of OH and NO3 radicals and O3 with selected vinyl ethers.	2006 Jun 15	16759126
Mechanism of the diphenyldisulfone-catalyzed isomerization of alkenes. Origin of the chemoselectivity: experimental and quantum chemistry studies.	2006 Jun 21	16771492
A theoretical study of the reaction of O(3P) with isobutene.	2006 Jun 29	16789773
Mechanistic study on adsorptive removal of tert-butanethiol on Ag-Y zeolite under ambient conditions.	2006 Nov 16	17092003
Hafnocene catalysts for selective propylene oligomerization: efficient synthesis of 4-methyl-1-pentene by beta-methyl transfer.	2006 Oct 4	17002399
Metabolism of new-generation taxanes in human, pig, minipig and rat liver microsomes.	2006 Sep	16971343
Treating dispersion effects in extended systems by hybrid MP2:DFT calculations--protonation of isobutene in zeolite ferrierite.	2006 Sep 14	17028686
Evaluation of the in-situ aerobic cometabolism of chlorinated ethenes by toluene-utilizing microorganisms using push-pull tests.	2007 Feb 20	17101190
Removal of methyl tert-butyl ether (MTBE) with Nafion.	2007 Jun 1	17110027

Patents

Name

Type

Language

ISOBUTYLENE

Systematic Name

English

ISOBUTENE

Systematic Name

English

ISOBUTYLENE [HSDB]

Common Name

English

Isobutylene [WHO-DD]

Common Name

English

ISOBUTYLENE [MI]

Common Name

English

2-METHYL-1-PROPENE

Systematic Name

English

Code System Code Type Description

SMS_ID

100000128502