ALLYL ACETATE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C5H8O2
Molecular Weight	100.1158
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	0
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

CC(=O)OCC=C

InChI

InChIKey=FWZUNOYOVVKUNF-UHFFFAOYSA-N

InChI=1S/C5H8O2/c1-3-4-7-5(2)6/h3H,1,4H2,2H3

HIDE SMILES / InChI

Approval Year

Doses

Dose	Population	Adverse events

PubMed

Title	Date	PubMed
Allyl compounds selectively killed human immunodeficiency virus (type 1)-infected cells.	1993 Jul 30	8343148
Inhibition of HIV-1 Rev-RRE interaction by diphenylfuran derivatives.	1996 Oct 22	8885849
Ruthenium-catalyzed intramolecular oxidative amination of aminoalkenes enables rapid synthesis of cyclic imines.	2002 Jan 16	11782166
Antitumour polycyclic acridines. Palladium(0) mediated syntheses of quino[4,3,2-kl]acridines bearing peripheral substituents as potential telomere maintenance inhibitors.	2003 Oct 7	14584801
Stereodivergent and regioselective synthesis of 3,4-cis- and 3,4-trans-pyrrolidinediols from alpha-amino acids.	2004 Jun 24	15200338
Allylation of alcohols and carboxylic acids with allyl acetate catalyzed by [Ir(cod)2](+)BF4- complex.	2004 May 14	15132558
Effectiveness of allyl acetate as a fumigant against five stored grain beetle pests.	2005 Jan	15593061
Beta-alkyl-alpha-allylation of Michael acceptors through the palladium-catalyzed three-component coupling between allylic substrates, trialkylboranes, and activated olefins.	2006 Mar 17	16526804
Letter: Silver mediated ester bond formation in the gas phase: substrate structure is important.	2007	18192731
TIMES-SS--a mechanistic evaluation of an external validation study using reaction chemistry principles.	2007 Sep	17713962
Preparation of sigma- and pi-allylcopper(III) intermediates in SN2 and SN2' reactions of organocuprate(I) reagents with allylic substrates.	2008 Aug 27	18671398
Enantioselective iridium-catalyzed carbonyl allylation from the alcohol or aldehyde oxidation level using allyl acetate as an allyl metal surrogate.	2008 May 21	18444616
Enantioselective iridium-catalyzed carbonyl allylation from the alcohol or aldehyde oxidation level via transfer hydrogenative coupling of allyl acetate: departure from chirally modified allyl metal reagents in carbonyl addition.	2008 Nov 5	18841896
anti-Diastereo- and enantioselective carbonyl crotylation from the alcohol or aldehyde oxidation level employing a cyclometallated iridium catalyst: alpha-methyl allyl acetate as a surrogate to preformed crotylmetal reagents.	2009 Feb 25	19191498
Palladium nanoparticle-catalyzed C-N bond formation. A highly regio- and stereoselective allylic amination by allyl acetates.	2009 May 15	19382763
Highly enantioselective Cu-catalyzed conjugate addition-elimination of activated allylic acetates with glycine derivatives.	2009 May 21	19358567
Enantioselective carbonyl reverse prenylation from the alcohol or aldehyde oxidation level employing 1,1-dimethylallene as the prenyl donor.	2009 May 27	19453190
Nickel-catalyzed, sodium iodide-promoted reductive dimerization of alkyl halides, alkyl pseudohalides, and allylic acetates.	2010 Aug 21	20582373
Iridium-catalyzed anti-diastereo- and enantioselective carbonyl (trimethylsilyl)allylation from the alcohol or aldehyde oxidation level.	2010 Jul 7	20540509
Enantioselective carbonyl allylation, crotylation, and tert-prenylation of furan methanols and furfurals via iridium-catalyzed transfer hydrogenation.	2010 Mar 5	20131774
A unified strategy targeting the thiodiketopiperazine mycotoxins exserohilone, gliotoxin, the epicoccins, the epicorazines, rostratin A and aranotin.	2010 Oct 11	20809554

Patents

Name

Type

Language

ALLYL ACETATE

Systematic Name

English

ACETIC ACID, ALLYL ESTER [HSDB]

Common Name

English

ALLYL ACETATE [MI]

Common Name

English

NSC-7612

Code

English

Code System Code Type Description

MESH

C498551