TERT-BUTYLCYANOKETENE

Details

Stereochemistry	ACHIRAL
Molecular Formula	C7H9NO
Molecular Weight	123.1525
Optical Activity	NONE
Defined Stereocenters	0 / 0
E/Z Centers	1
Charge	0

SHOW SMILES / InChI

Structure Search

SMILES

CC(C)(C)C(=C=O)C#N

InChI

InChIKey=PXMIEOACHDWJQE-UHFFFAOYSA-N

InChI=1S/C7H9NO/c1-7(2,3)6(4-8)5-9/h1-3H3

HIDE SMILES / InChI

Description
Sources: DOI: 10.1021/jo00337a023 | DOI: 10.1021/jo00941a036 | DOI: 10.1021/jo01310a042

tert-Butylcyanoketene reacts with tertiary amines. The reaction of tert-butylcyanoketene with a series of isocyanides results in an unusual mode of addition involving the carbonyl bond of the ketene. tert-Butylcyanoketene cycloadds to ketene, methylketene, dimethylketene, and ethylmethylketene.

Originator

Approval Year

Conditions

Condition	Modality	Targets	Highest Phase	Product
Unknown 2578

PubMed

Title	Date	PubMed
Synthesis of spirofluorenes of biological interest.	1978 Jul	660513

Sample Use Guides

In Vivo Use Guide

Unknown

Route of Administration: Unknown

In Vitro Use Guide

Unknown

Name

Type

Language

TERT-BUTYLCYANOKETENE

Systematic Name

English

(±)-TETRAHYDROPALMATINE

Common Name

English

DL-TETRAHYDROPALMATINE

Common Name

English

6H-DIBENZO(A,G)QUINOLIZINE, 5,8,13,13A-TETRAHYDRO-2,3,9,10-TETRAMETHOXY-

Systematic Name

English

BERBINE, 2,3,9,10-TETRAMETHOXY-, (±)-

Systematic Name

English

TETRAHYDROPALMATINE DL-FORM [MI]

Common Name

English

CYANO(1,1-DIMETHYLETHYL)KETENE

Systematic Name

English

BUTYRONITRILE, 2-CARBONYL-3,3-DIMETHYL-

Systematic Name

English

MOORE'S KETENE [MI]

Common Name

English

(±)-CORYDALIS B

Common Name

English

MOORE'S KETENE

Common Name

English

Code System Code Type Description

MERCK INDEX

m7620