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Details

Stereochemistry ACHIRAL
Molecular Formula C4H6O
Molecular Weight 70.0898
Optical Activity NONE
Defined Stereocenters 0 / 0
E/Z Centers 0
Charge 0

SHOW SMILES / InChI
Structure of METHYL VINYL KETONE

SMILES

CC(=O)C=C

InChI

InChIKey=FUSUHKVFWTUUBE-UHFFFAOYSA-N
InChI=1S/C4H6O/c1-3-4(2)5/h3H,1H2,2H3

HIDE SMILES / InChI

Approval Year

PubMed

PubMed

TitleDatePubMed
Enantioselective Michael addition catalyzed by cinchona alkaloids.
2001
Characterization of chemical interferences in the determination of unsaturated aldehydes using aromatic hydrazine reagents and liquid chromatography.
2001 Jun
Electron-transfer-induced tautomerization in methylindanones: electronic control of the tunneling rate for enolization.
2001 Mar 14
New auxiliaries for copper-catalyzed asymmetric Michael reactions: generation of quaternary stereocenters at room temperature.
2001 Mar 2
Antioxidative function and substrate specificity of NAD(P)H-dependent alkenal/one oxidoreductase. A new role for leukotriene B4 12-hydroxydehydrogenase/15-oxoprostaglandin 13-reductase.
2001 Nov 2
Enantioselective Michael addition of beta-keto esters to methyl vinyl ketone employing a chiral N,N'-dioxide-scandium trifluoromethanesulfonate complex as a catalyst.
2001 Sep 7
Intermolecular Diels-Alder reactions of brominated masked o-benzoquinones with electron-deficient dienophiles. A detour method to synthesize bicyclo[2.2.2]octenones from 2-methoxyphenols.
2002 Sep 6
Proton transfer reaction ion trap mass spectrometer.
2003
Double bonds in motion: bis(oxazolinylmethyl)pyrroles and their metal-induced planarization to a new class of rigid chiral C2-symmetric complexes.
2003 Apr 14
Description and characterization of an on-line system for long-term measurements of isoprene, methyl vinyl ketone, and methacrolein in ambient air.
2003 May 2
Direct enantioselective Michael addition of aldehydes to vinyl ketones catalyzed by chiral amines.
2003 May 30
Differentiation of isobaric compounds using chemical ionization reaction mass spectrometry.
2005
Mechanism of scandium ion catalyzed Diels-Alder reaction of anthracenes with methyl vinyl ketone.
2005 Apr 14
A theoretical study of the mechanism of phosphine-catalyzed hydroalkoxylation of methyl vinyl ketone.
2005 Dec 1
Regioselective silylphosphination of methyl vinyl ketone with complexes containing cyclic and linear iron-silicon-phosphorus reacting sites.
2005 Feb 21
A succinct method for preparing the Stork-Jung vinylsilane robinson annulation reagent.
2005 Jan 21
A DFT study of Diels-Alder reactions of o-quinone methides and various substituted ethenes: selectivity and reaction mechanism.
2005 Jun 24
Catalytic, asymmetric aza-Baylis-Hillman reaction of N-sulfonated imines with activated olefins by quinidine-derived chiral amines.
2005 Mar 4
Tetrahydropyran rings from a Mukaiyama-Michael cascade reaction.
2005 Nov 23
Adducts of oxylipin electrophiles to glutathione reflect a 13 specificity of the downstream lipoxygenase pathway in the tobacco hypersensitive response.
2006 Apr
Cobalt-catalyzed reductive coupling of saturated alkyl halides with activated alkenes.
2006 Jan 20
Stereoselectivity in Diels-Alder reactions of diene-substituted N-alkoxycarbonyl-1,2-dihydropyridines.
2007 Apr 27
Overall rate constant measurements of the reaction of hydroxy- and chloroalkylperoxy radicals derived from methacrolein and methyl vinyl ketone with nitric oxide.
2007 Feb 1
[Extraction and determination of essential oils in Indocalamus latifolius leaves and Indocalamus tessellatus leaves].
2007 Jan
Structure-toxicity analysis of type-2 alkenes: in vitro neurotoxicity.
2007 Jan
Rhodium-catalyzed reductive mannich coupling of vinyl ketones to N-sulfonylimines mediated by hydrogen.
2007 Jul 20
Organocatalytic sequential one-pot double cascade asymmetric synthesis of Wieland-Miescher ketone analogues from a Knoevenagel/hydrogenation/Robinson annulation sequence: scope and applications of organocatalytic biomimetic reductions.
2007 Jul 6
Photolysis of 4-oxo-2-pentenal in the 190-460 nm region.
2007 Sep 20
Synthesis and anti-breast cancer activities of substituted quinolines.
2008 Jun 1
Palladium-catalyzed cyclization/Heck- and cyclization/conjugate-addition-type sequences in the preparation of polysubstituted furans.
2008 May 2
One-pot multi-component asymmetric cascade reactions catalyzed by soluble star polymers with highly branched non-interpenetrating catalytic cores.
2008 May 21
Noncovalent cell surface engineering: incorporation of bioactive synthetic glycopolymers into cellular membranes.
2008 May 7
Patents

Patents

Name Type Language
METHYL VINYL KETONE
MI  
Systematic Name English
3-OXO-1-BUTENE
Systematic Name English
.DELTA.3-2-BUTENONE
Common Name English
3-BUTEN-2-ONE
Systematic Name English
UN1251
Code English
ACETYL ETHYLENE
Systematic Name English
2-BUTENONE
Common Name English
METHYLENE ACETONE
Systematic Name English
UN-1251
Code English
3-OXOBUTENE
Systematic Name English
METHYL VINYL KETONE [MI]
Common Name English
1-BUTEN-3-ONE
Systematic Name English
.DELTA.-OXO-.ALPHA.-BUTYLENE
Common Name English
NSC-4853
Code English
VINYL METHYL KETONE
Systematic Name English
Code System Code Type Description
PUBCHEM
6570
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
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NSC
4853
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
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EPA CompTox
DTXSID3025671
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
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CAS
78-94-4
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
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FDA UNII
AR7642I1MP
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
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CHEBI
48058
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
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HSDB
716
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
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MERCK INDEX
m7480
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
PRIMARY Merck Index
MESH
C057920
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
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WIKIPEDIA
METHYL VINYL KETONE
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
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ECHA (EC/EINECS)
201-160-6
Created by admin on Sat Dec 16 02:15:42 GMT 2023 , Edited by admin on Sat Dec 16 02:15:42 GMT 2023
PRIMARY