Details
| Stereochemistry | ACHIRAL |
| Molecular Formula | C12H24O6 |
| Molecular Weight | 264.3154 |
| Optical Activity | NONE |
| Defined Stereocenters | 0 / 0 |
| E/Z Centers | 0 |
| Charge | 0 |
SHOW SMILES / InChI
SMILES
C1COCCOCCOCCOCCOCCO1
InChI
InChIKey=XEZNGIUYQVAUSS-UHFFFAOYSA-N
InChI=1S/C12H24O6/c1-2-14-5-6-16-9-10-18-12-11-17-8-7-15-4-3-13-1/h1-12H2
Approval Year
PubMed
| Title | Date | PubMed |
|---|---|---|
| Preparation and structural characterisation of methoxybis(trimethylsilyl)silyl potassium and its condensation product. | 2004-08-07 |
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| The development of a continuous isothermal titration calorimetric method for equilibrium studies. | 2004-08-01 |
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| Possible role of relativistic effects in the plasticity of the coordination geometry of cadmium(II). A voltammetric study of the stability of the complexes of cadmium(II) with 12-crown-4,15-crown-5 and 18-crown-6 in aqueous solution and the structures of [Cd(benzo-18-crown-6)(NCS)(2)] and [K(18-crown-6)][Cd(SCN)(3)]. | 2004-07-12 |
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| Calorimetric vs. van't Hoff binding enthalpies from isothermal titration calorimetry: Ba2+-crown ether complexation. | 2004-07-01 |
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| Synthesis of double-armed lariat ethers with pyrene moieties at each end of two sidearms and their fluorescence properties in the presence of alkali metal and alkaline earth metal cations. | 2004-06-25 |
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| Simultaneous determination of catecholamines and polyamines in PC-12 cell extracts by micellar electrokinetic capillary chromatography with ultraviolet absorbance detection. | 2004-06-15 |
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| Distorted equatorial coordination environments and weakening of U=O bonds in uranyl complexes containing NCN and NPN ligands. | 2004-05-17 |
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| Spacer length effect of a chiral stationary phase based on (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid. | 2004-05-15 |
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| Crystallographic distinction between "contact" and "separated" ion pairs: structural effects on electronic/ESR spectra of alkali-metal nitrobenzenides. | 2004-04-14 |
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| Chiral discrimination studies of (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid by high-performance liquid chromatography and NMR spectroscopy. | 2004-04 |
|
| Two complexes of Sm(II) with crown ethers-electrochemical synthesis, structure and spectroscopy. | 2004-03-07 |
|
| Protonated nucleobase ligands: synthesis, structure and characterization of 9-methyladeninium hexachloroplatinate and pentachloro(9-methyladeninium)platinum(IV). | 2004-03 |
|
| Nucleophilic displacement on 4-nitrophenyl dimethyl phosphinate by ethoxide ion: alkali metal ion catalysis and mechanism. | 2004-02-21 |
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| Ion chromatographic separation of hydrogen ion and other common mono- and divalent cations. | 2004-01-16 |
|
| Biological activity of bacterial lectins and their molecular complexes with heterocyclic bis-adducts. | 2004-01-16 |
|
| Ethylenediamine as a liquid chemical reagent to probe hydrogen bonding and host-guest interactions with crown ethers in an ion trap tandem mass spectrometer. | 2004 |
|
| Crystal and molecular structures of ionophore-siderophore host-guest supramolecular assemblies relevant to molecular recognition. | 2003-12-03 |
|
| CE/electrospray ionization-MS analysis of underivatized d/l-amino acids and several small neurotransmitters at attomole levels through the use of 18-crown-6-tetracarboxylic acid as a complexation reagent/background electrolyte. | 2003-11-15 |
|
| Isolation, characterization, and reaction of activated iodosylbenzene monomer hydroxy(phenyl)iodonium ion with hypervalent bonding: supramolecular complex PhI+OH.18-crown-6 with secondary I...O interactions. | 2003-10-29 |
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| Use of mobile phase 18-crown-6 to improve peak resolution between mono- and divalent metal and amine cations in ion chromatography. | 2003-10-24 |
|
| H+, Na+ and K+ modulated lanthanide luminescent switching of Tb(III) based cyclen aromatic diaza-crown ether conjugates in water. | 2003-10-07 |
|
| Computational assessment of the electronic structure of 1-azacyclohexa-2,3,5-triene (3 delta 2-1H-pyridine) and its benzo derivative (3 delta 2-1H-quinoline) as well as generation and interception of 1-methyl-3 delta 2-1H-quinoline. | 2003-10-06 |
|
| The isothiocyanate complex of triphenylborane forms an unusual coordination polymer with [K(18-crown-6)](+), both in the solid state and in solution. | 2003-10 |
|
| Chemical activation of cytochrome c proteins via crown ether complexation: cold-active synzymes for enantiomer-selective sulfoxide oxidation in methanol. | 2003-09-24 |
|
| Sonogashira coupling using bulky palladium-phenanthryl imidazolium carbene catalysis. | 2003-09-04 |
|
| From 1D strands to extended molecular assemblies in the binary compounds of dithiooxamide and dithiobiurea with crown ethers. | 2003-08-21 |
|
| Enantiomeric separation of TAPP, H-Tyr-(D)Ala-Phe-Phe-NH(2), by capillary electrophoresis using 18-crown-6-tetracarboxylic acid as a chiral selector. | 2003-08-15 |
|
| Synthesis of a new potential tridentate anthracene ligand bearing deprotectable methoxymethoxy (OMOM) group at 1,8-positions: attempt to synthesize anionic hypervalent carbon compounds. | 2003-08-04 |
|
| Photonic crystal optrode sensor for detection of Pb2+ in high ionic strength environments. | 2003-08-01 |
|
| Potassium dicyanoargentate(I) 1,4,7,10,13,16-hexaoxacyclooctadecane. | 2003-08 |
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| Controlling the conformation and interplay of p-sulfonatocalix[6]arene as lanthanide crown ether complexes. | 2003-06-16 |
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| High-speed simultaneous ion-exclusion/cation-exchange chromatography of anions and cations on a weakly acidic cation-exchange resin column. | 2003-05-16 |
|
| Synthesis, characterization, and reaction of ethynyl(phenyl)-lambda3-iodane complex with [18]crown-6. | 2003-05-16 |
|
| A theoretical study of the large Hg-Hg spin-spin coupling constants in Hg(2)(2+), Hg(3)(2+), and Hg(2)(2+)-crown ether complexes. | 2003-04-23 |
|
| Single complexation force of 18-crown-6 with ammonium ion evaluated by atomic force microscopy. | 2003-04-16 |
|
| Electron transfer between two silyl-substituted phenylene rings: EPR/ENDOR spectra, DFT calculations, and crystal structure of the one-electron reduction compound of a di(m-silylphenylenedisiloxane). | 2003-04-16 |
|
| An equilibrium partitioning model for predicting response to host-guest complexation in electrospray ionization mass spectrometry. | 2003-04-15 |
|
| Evaluation of diabetic ketoacidosis-related ionic metabolites in human blood serum by capillary electrophoresis. | 2003-04 |
|
| Threshold dissociation energies of protonated amine/polyether complexes in a quadrupole ion trap. | 2003-04 |
|
| Near infrared spectral investigations of hydration of 18-crown-6 in HDO-D2O solutions at different temperatures. | 2003-04 |
|
| Secondary hypervalent I(III)...O interactions: synthesis and structure of hypervalent complexes of diphenyl-lambda3-iodanes with 18-crown-6. | 2003-01-22 |
|
| Preparation and application of a new modified liquid chromatographic chiral stationary phase based on (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid. | 2003-01-17 |
|
| Enantioselective ion-exclusion chromatography on teicoplanin aglycone and (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid stationary phases. | 2003-01-03 |
|
| Crown ethers as ancillary ligands in the assembly of silver(i) aggregates containing embedded acetylenediide. | 2003-01-03 |
|
| Probing the discriminating power of chiral crown hosts by CD spectroscopy. | 2003 |
|
| Effect of acidity on the enantiomeric resolution of thyroxine and tocainide by HPLC on a (+)-(18-crown-6)-2,3,11,12-tetracarboxylic acid column. | 2002-12-31 |
|
| From one-dimensional chain to pentanuclear molecule. Magnetism of cyano-bridged Fe(III)-Ni(II) complexes. | 2002-12-16 |
|
| Structural and vibrational study of the Ci(1) conformation of 18-crown-6. | 2002-11 |
|
| Simultaneous determination of inorganic and organic anions, alkali, alkaline earth and transition metal cations by capillary electrophoresis with contactless conductometric detection. | 2002-11 |
|
| A unique spherical molecular host with D2d symmetry. A novel intramolecular kinetic equilibrium in metal ion complexation between two crown ethers. | 2002-10-31 |
Patents
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32397
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C015762
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DTXSID7058626
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63J177NC5B
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241-473-5
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17455-13-9
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159836
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28557
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18-CROWN-6
Created by
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SUBSTANCE RECORD
